High Temperature Mass Spectrometric Study of the TiO2–Al2O3 System
The results of studying the evaporation and thermodynamic properties of the TiO 2 –Al 2 O 3 system in the temperature range 2250–2710 K by high-temperature mass spectrometry are presented. The composition of the vapor is identified, the partial pressures of the TiO 2 , TiO, and Al vapor species over...
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| Veröffentlicht in: | Russian journal of general chemistry 2021-10, Vol.91 (10), p.1999-2007 |
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| container_end_page | 2007 |
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| container_issue | 10 |
| container_start_page | 1999 |
| container_title | Russian journal of general chemistry |
| container_volume | 91 |
| creator | Stolyarova, V. L. Vorozhtcov, V. A. Shemchuk, D. V. Lopatin, S. I. Bogdanov, O. A. |
| description | The results of studying the evaporation and thermodynamic properties of the TiO
2
–Al
2
O
3
system in the temperature range 2250–2710 K by high-temperature mass spectrometry are presented. The composition of the vapor is identified, the partial pressures of the TiO
2
, TiO, and Al vapor species over the studied samples in the indicated temperature range are determined. The determined activities of the components and the excess Gibbs energy in the melt of the TiO
2
–Al
2
O
3
system at 2345 K point to insignificant deviations from ideality. |
| doi_str_mv | 10.1134/S107036322110011X |
| format | Article |
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2
–Al
2
O
3
system in the temperature range 2250–2710 K by high-temperature mass spectrometry are presented. The composition of the vapor is identified, the partial pressures of the TiO
2
, TiO, and Al vapor species over the studied samples in the indicated temperature range are determined. The determined activities of the components and the excess Gibbs energy in the melt of the TiO
2
–Al
2
O
3
system at 2345 K point to insignificant deviations from ideality.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S107036322110011X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aluminum oxide ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; High temperature ; Mass spectrometry ; Thermodynamic properties ; Titanium dioxide</subject><ispartof>Russian journal of general chemistry, 2021-10, Vol.91 (10), p.1999-2007</ispartof><rights>Pleiades Publishing, Ltd. 2021</rights><rights>Pleiades Publishing, Ltd. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-39a3d96e66be3bc1ff1b9fa5f6f54e13295df89b0d1cd6cff5cc1f47bf33166c3</citedby><cites>FETCH-LOGICAL-c316t-39a3d96e66be3bc1ff1b9fa5f6f54e13295df89b0d1cd6cff5cc1f47bf33166c3</cites><orcidid>0000-0002-6931-1865 ; 0000-0002-5288-865X ; 0000-0003-0209-4023 ; 0000-0002-6060-5349 ; 0000-0001-7798-4405</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S107036322110011X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S107036322110011X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27907,27908,41471,42540,51302</link.rule.ids></links><search><creatorcontrib>Stolyarova, V. L.</creatorcontrib><creatorcontrib>Vorozhtcov, V. A.</creatorcontrib><creatorcontrib>Shemchuk, D. V.</creatorcontrib><creatorcontrib>Lopatin, S. I.</creatorcontrib><creatorcontrib>Bogdanov, O. A.</creatorcontrib><title>High Temperature Mass Spectrometric Study of the TiO2–Al2O3 System</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>The results of studying the evaporation and thermodynamic properties of the TiO
2
–Al
2
O
3
system in the temperature range 2250–2710 K by high-temperature mass spectrometry are presented. The composition of the vapor is identified, the partial pressures of the TiO
2
, TiO, and Al vapor species over the studied samples in the indicated temperature range are determined. The determined activities of the components and the excess Gibbs energy in the melt of the TiO
2
–Al
2
O
3
system at 2345 K point to insignificant deviations from ideality.</description><subject>Aluminum oxide</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>High temperature</subject><subject>Mass spectrometry</subject><subject>Thermodynamic properties</subject><subject>Titanium dioxide</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kM9Kw0AQhxdRsFYfwNuC5-jOTrNtjqX-qVDJIRW8hWQz26Y0TdzdHHrzHXxDn8QtFTyIpxmY7_sN_Bi7BnELgKO7DMRYoEIpAYQAeDthA1BiEiHG4jTs4Rwd7ufswrlNQIRQcsDu5_VqzZfUdGQL31viL4VzPOtIe9s25G2teeb7as9bw_2a-LJO5dfH53QrU-TZ3nlqLtmZKbaOrn7mkL0-Pixn82iRPj3PpotIIygfYVJglShSqiQsNRgDZWKK2CgTjwhQJnFlJkkpKtCV0sbEOkCjcWkw-ErjkN0cczvbvvfkfL5pe7sLL3MZJzHgGEAFCo6Utq1zlkze2bop7D4HkR_Kyv-UFRx5dFxgdyuyv8n_S9_0eGuH</recordid><startdate>20211001</startdate><enddate>20211001</enddate><creator>Stolyarova, V. L.</creator><creator>Vorozhtcov, V. A.</creator><creator>Shemchuk, D. V.</creator><creator>Lopatin, S. I.</creator><creator>Bogdanov, O. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-6931-1865</orcidid><orcidid>https://orcid.org/0000-0002-5288-865X</orcidid><orcidid>https://orcid.org/0000-0003-0209-4023</orcidid><orcidid>https://orcid.org/0000-0002-6060-5349</orcidid><orcidid>https://orcid.org/0000-0001-7798-4405</orcidid></search><sort><creationdate>20211001</creationdate><title>High Temperature Mass Spectrometric Study of the TiO2–Al2O3 System</title><author>Stolyarova, V. L. ; Vorozhtcov, V. A. ; Shemchuk, D. V. ; Lopatin, S. I. ; Bogdanov, O. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-39a3d96e66be3bc1ff1b9fa5f6f54e13295df89b0d1cd6cff5cc1f47bf33166c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aluminum oxide</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>High temperature</topic><topic>Mass spectrometry</topic><topic>Thermodynamic properties</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stolyarova, V. L.</creatorcontrib><creatorcontrib>Vorozhtcov, V. A.</creatorcontrib><creatorcontrib>Shemchuk, D. V.</creatorcontrib><creatorcontrib>Lopatin, S. I.</creatorcontrib><creatorcontrib>Bogdanov, O. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stolyarova, V. L.</au><au>Vorozhtcov, V. A.</au><au>Shemchuk, D. V.</au><au>Lopatin, S. I.</au><au>Bogdanov, O. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High Temperature Mass Spectrometric Study of the TiO2–Al2O3 System</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2021-10-01</date><risdate>2021</risdate><volume>91</volume><issue>10</issue><spage>1999</spage><epage>2007</epage><pages>1999-2007</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>The results of studying the evaporation and thermodynamic properties of the TiO
2
–Al
2
O
3
system in the temperature range 2250–2710 K by high-temperature mass spectrometry are presented. The composition of the vapor is identified, the partial pressures of the TiO
2
, TiO, and Al vapor species over the studied samples in the indicated temperature range are determined. The determined activities of the components and the excess Gibbs energy in the melt of the TiO
2
–Al
2
O
3
system at 2345 K point to insignificant deviations from ideality.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S107036322110011X</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-6931-1865</orcidid><orcidid>https://orcid.org/0000-0002-5288-865X</orcidid><orcidid>https://orcid.org/0000-0003-0209-4023</orcidid><orcidid>https://orcid.org/0000-0002-6060-5349</orcidid><orcidid>https://orcid.org/0000-0001-7798-4405</orcidid></addata></record> |
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| ispartof | Russian journal of general chemistry, 2021-10, Vol.91 (10), p.1999-2007 |
| issn | 1070-3632 1608-3350 |
| language | eng |
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| source | SpringerLink Journals |
| subjects | Aluminum oxide Chemistry Chemistry and Materials Science Chemistry/Food Science High temperature Mass spectrometry Thermodynamic properties Titanium dioxide |
| title | High Temperature Mass Spectrometric Study of the TiO2–Al2O3 System |
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