Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate

Exploring non π‐conjugated phosphate birefringent crystal with a large birefringence has been a great challenge. Herein, based on the unique two‐dimensional layered structure in KBe2BO3F2 (KBBF), two new compounds, Sn2PO4I and Sn2BO3I, were designed and synthesized successfully, maintaining the laye...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-11, Vol.60 (47), p.24901-24904
Hauptverfasser:	Guo, Jingyu, Tudi, Abudukadi, Han, Shujuan, Yang, Zhihua, Pan, Shilie
Format:	Artikel
Sprache:	eng
Schlagworte:	Anisotropy Birefringence birefringent materials Borates Crystal structure Crystals Inorganic compounds optical anisotropy Phosphates stereochemically active lone pair tin (II)-based materials Titanium dioxide
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