Temperature-Dependent Rheological Behaviors of Binary Eutectic Mixtures of Sugar Alcohols for Latent Heat Storage: A Comparative Study with Pure Sugar Alcohols
The temperature-dependent rheological behaviors of five selected binary eutectic mixture sugar alcohols, with great potential for latent heat storage in the range of 353.15 K to 523.15 K, were investigated. It was found that the rheological behaviors of the mixture sugar alcohols depend on those of...
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| Veröffentlicht in: | Journal of thermal science 2021-11, Vol.30 (6), p.2002-2014 |
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| creator | Shao, Xuefeng Yang, Sheng Chen, Chenlin Fan, Liwu Yu, Zitao |
| description | The temperature-dependent rheological behaviors of five selected binary eutectic mixture sugar alcohols, with great potential for latent heat storage in the range of 353.15 K to 523.15 K, were investigated. It was found that the rheological behaviors of the mixture sugar alcohols depend on those of the pure compounds as well as their molar ratios. The two mixtures of xylitol (75 mol%)+erythritol and erythritol (84 mol%)+d-mannitol behave like pseudoplastic fluids with typical non-Newtonian shear-thinning behaviors, as indicated by the power law index of 0.99 ( |
| doi_str_mv | 10.1007/s11630-021-1279-9 |
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It was found that the rheological behaviors of the mixture sugar alcohols depend on those of the pure compounds as well as their molar ratios. The two mixtures of xylitol (75 mol%)+erythritol and erythritol (84 mol%)+d-mannitol behave like pseudoplastic fluids with typical non-Newtonian shear-thinning behaviors, as indicated by the power law index of 0.99 (<1). The mixture of d-mannitol (70 mol%)+d-dulcitol is a nonlinear Bingham fluid, exhibiting a slight yield stress (0.001 Pa to 0.01 Pa) at low shear rates. The rest two mixtures containing the cyclic-structured inositol behave like Herschel-Bulkley fluids. The infinite shear viscosities of the eutectic mixtures over the entire temperature range appear to be higher than those of their respective pure compounds, except for inositol. The mixture of xylitol (75 mol%)+erythritol at its melting point shows higher dynamic viscosity of about 0.546 Pa·s than the values of about 0.396 Pa·s and 0.035 Pa·s for xylitol and erythritol, respectively. In addition, the activation energies of viscous flow of the mixtures, as determined by fitting the dynamic viscosity-temperature curves using the Arrhenius model, also exhibit higher values than those of their pure compounds. The activation energy of viscous flow of the mixture xylitol (75 mol%)+erythritol was determined to be about 92 400 J/mol in the supercooled liquid state, while the supercooled liquid xylitol and erythritol have much lower values of 83 500 J/mol and 51 900 J/mol, respectively. Both the increased dynamic viscosities and activation energies of viscous flow can result in deteriorated crystallization performance during latent heat retrieval.</description><identifier>ISSN: 1003-2169</identifier><identifier>EISSN: 1993-033X</identifier><identifier>DOI: 10.1007/s11630-021-1279-9</identifier><language>eng</language><publisher>Heidelberg: Science Press</publisher><subject>Activation energy ; Alcohol ; Alcohols ; Classical and Continuum Physics ; Comparative studies ; Crystallization ; Curve fitting ; Engineering ; Engineering Fluid Dynamics ; Engineering Thermodynamics ; Engineering, Mechanical ; Erythritol ; Eutectics ; Heat ; Heat and Mass Transfer ; Heat storage ; Latent heat ; Mannitol ; Melting points ; Physical Sciences ; Physics ; Physics and Astronomy ; Polyols ; Pseudoplasticity ; Rheological properties ; Rheology ; Science & Technology ; Shear ; Shear thinning (liquids) ; Technology ; Temperature dependence ; Thermodynamics ; Viscosity ; Viscous flow ; Xylitol ; Yield stress</subject><ispartof>Journal of thermal science, 2021-11, Vol.30 (6), p.2002-2014</ispartof><rights>Science Press, Institute of Engineering Thermophysics, CAS and Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>Science Press, Institute of Engineering Thermophysics, CAS and Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>12</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000609057800001</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c316t-82f3e8fb0ec946543ef692e4c9b74cc79ae289142240ef3e2f8eaef01b134a9b3</citedby><cites>FETCH-LOGICAL-c316t-82f3e8fb0ec946543ef692e4c9b74cc79ae289142240ef3e2f8eaef01b134a9b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11630-021-1279-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11630-021-1279-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27931,27932,39265,41495,42564,51326</link.rule.ids></links><search><creatorcontrib>Shao, Xuefeng</creatorcontrib><creatorcontrib>Yang, Sheng</creatorcontrib><creatorcontrib>Chen, Chenlin</creatorcontrib><creatorcontrib>Fan, Liwu</creatorcontrib><creatorcontrib>Yu, Zitao</creatorcontrib><title>Temperature-Dependent Rheological Behaviors of Binary Eutectic Mixtures of Sugar Alcohols for Latent Heat Storage: A Comparative Study with Pure Sugar Alcohols</title><title>Journal of thermal science</title><addtitle>J. Therm. Sci</addtitle><addtitle>J THERM SCI</addtitle><description>The temperature-dependent rheological behaviors of five selected binary eutectic mixture sugar alcohols, with great potential for latent heat storage in the range of 353.15 K to 523.15 K, were investigated. It was found that the rheological behaviors of the mixture sugar alcohols depend on those of the pure compounds as well as their molar ratios. The two mixtures of xylitol (75 mol%)+erythritol and erythritol (84 mol%)+d-mannitol behave like pseudoplastic fluids with typical non-Newtonian shear-thinning behaviors, as indicated by the power law index of 0.99 (<1). The mixture of d-mannitol (70 mol%)+d-dulcitol is a nonlinear Bingham fluid, exhibiting a slight yield stress (0.001 Pa to 0.01 Pa) at low shear rates. The rest two mixtures containing the cyclic-structured inositol behave like Herschel-Bulkley fluids. The infinite shear viscosities of the eutectic mixtures over the entire temperature range appear to be higher than those of their respective pure compounds, except for inositol. The mixture of xylitol (75 mol%)+erythritol at its melting point shows higher dynamic viscosity of about 0.546 Pa·s than the values of about 0.396 Pa·s and 0.035 Pa·s for xylitol and erythritol, respectively. In addition, the activation energies of viscous flow of the mixtures, as determined by fitting the dynamic viscosity-temperature curves using the Arrhenius model, also exhibit higher values than those of their pure compounds. The activation energy of viscous flow of the mixture xylitol (75 mol%)+erythritol was determined to be about 92 400 J/mol in the supercooled liquid state, while the supercooled liquid xylitol and erythritol have much lower values of 83 500 J/mol and 51 900 J/mol, respectively. Both the increased dynamic viscosities and activation energies of viscous flow can result in deteriorated crystallization performance during latent heat retrieval.</description><subject>Activation energy</subject><subject>Alcohol</subject><subject>Alcohols</subject><subject>Classical and Continuum Physics</subject><subject>Comparative studies</subject><subject>Crystallization</subject><subject>Curve fitting</subject><subject>Engineering</subject><subject>Engineering Fluid Dynamics</subject><subject>Engineering Thermodynamics</subject><subject>Engineering, Mechanical</subject><subject>Erythritol</subject><subject>Eutectics</subject><subject>Heat</subject><subject>Heat and Mass Transfer</subject><subject>Heat storage</subject><subject>Latent heat</subject><subject>Mannitol</subject><subject>Melting points</subject><subject>Physical Sciences</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Polyols</subject><subject>Pseudoplasticity</subject><subject>Rheological properties</subject><subject>Rheology</subject><subject>Science & Technology</subject><subject>Shear</subject><subject>Shear thinning (liquids)</subject><subject>Technology</subject><subject>Temperature dependence</subject><subject>Thermodynamics</subject><subject>Viscosity</subject><subject>Viscous flow</subject><subject>Xylitol</subject><subject>Yield stress</subject><issn>1003-2169</issn><issn>1993-033X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>HGBXW</sourceid><recordid>eNqNkcFu1DAQhqMKpJbCA3Cz1CMyHdvZJOa2DaWttAhEi8TNctzxrqtsHGynpU_TV623qUBCQuLkkf1__4znL4q3DN4zgPo4MlYJoMAZZbyWVO4VB0xKQUGIHy9yDSAoZ5XcL17FeANQ1ZUoD4qHK9yOGHSaAtKPOOJwjUMi3zboe792RvfkBDf61vkQibfkxA063JPTKaFJzpDP7tcOfXq7nNY6kGVv_Mb3kVgfyEqnnd056kQukw96jR_IkrR-O-rc1N1ivp6u78mdSxvyNTv95fK6eGl1H_HN83lYfP90etWe09WXs4t2uaJGsCrRhluBje0AjSyrRSnQVpJjaWRXl8bUUiNvJCs5LwGzlNsGNVpgHROllp04LI5m3zH4nxPGpG78FIbcUvFFJqXgbJFVbFaZ4GMMaNUY3DYvRDFQuxzUnIPKOahdDkpm5t3M3GHnbTQOB4O_OchJgIRF3eQKWFY3_69uXco79EPrpyFllM9ozPJhjeHPF_493SOum64p</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Shao, Xuefeng</creator><creator>Yang, Sheng</creator><creator>Chen, Chenlin</creator><creator>Fan, Liwu</creator><creator>Yu, Zitao</creator><general>Science Press</general><general>Springer Nature</general><general>Springer Nature B.V</general><scope>BLEPL</scope><scope>DTL</scope><scope>HGBXW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20211101</creationdate><title>Temperature-Dependent Rheological Behaviors of Binary Eutectic Mixtures of Sugar Alcohols for Latent Heat Storage: A Comparative Study with Pure Sugar Alcohols</title><author>Shao, Xuefeng ; Yang, Sheng ; Chen, Chenlin ; Fan, Liwu ; Yu, Zitao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-82f3e8fb0ec946543ef692e4c9b74cc79ae289142240ef3e2f8eaef01b134a9b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Activation energy</topic><topic>Alcohol</topic><topic>Alcohols</topic><topic>Classical and Continuum Physics</topic><topic>Comparative studies</topic><topic>Crystallization</topic><topic>Curve fitting</topic><topic>Engineering</topic><topic>Engineering Fluid Dynamics</topic><topic>Engineering Thermodynamics</topic><topic>Engineering, Mechanical</topic><topic>Erythritol</topic><topic>Eutectics</topic><topic>Heat</topic><topic>Heat and Mass Transfer</topic><topic>Heat storage</topic><topic>Latent heat</topic><topic>Mannitol</topic><topic>Melting points</topic><topic>Physical Sciences</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Polyols</topic><topic>Pseudoplasticity</topic><topic>Rheological properties</topic><topic>Rheology</topic><topic>Science & Technology</topic><topic>Shear</topic><topic>Shear thinning (liquids)</topic><topic>Technology</topic><topic>Temperature dependence</topic><topic>Thermodynamics</topic><topic>Viscosity</topic><topic>Viscous flow</topic><topic>Xylitol</topic><topic>Yield stress</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shao, Xuefeng</creatorcontrib><creatorcontrib>Yang, Sheng</creatorcontrib><creatorcontrib>Chen, Chenlin</creatorcontrib><creatorcontrib>Fan, Liwu</creatorcontrib><creatorcontrib>Yu, Zitao</creatorcontrib><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Web of Science - Science Citation Index Expanded - 2021</collection><collection>CrossRef</collection><jtitle>Journal of thermal science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shao, Xuefeng</au><au>Yang, Sheng</au><au>Chen, Chenlin</au><au>Fan, Liwu</au><au>Yu, Zitao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Temperature-Dependent Rheological Behaviors of Binary Eutectic Mixtures of Sugar Alcohols for Latent Heat Storage: A Comparative Study with Pure Sugar Alcohols</atitle><jtitle>Journal of thermal science</jtitle><stitle>J. Therm. Sci</stitle><stitle>J THERM SCI</stitle><date>2021-11-01</date><risdate>2021</risdate><volume>30</volume><issue>6</issue><spage>2002</spage><epage>2014</epage><pages>2002-2014</pages><issn>1003-2169</issn><eissn>1993-033X</eissn><abstract>The temperature-dependent rheological behaviors of five selected binary eutectic mixture sugar alcohols, with great potential for latent heat storage in the range of 353.15 K to 523.15 K, were investigated. It was found that the rheological behaviors of the mixture sugar alcohols depend on those of the pure compounds as well as their molar ratios. The two mixtures of xylitol (75 mol%)+erythritol and erythritol (84 mol%)+d-mannitol behave like pseudoplastic fluids with typical non-Newtonian shear-thinning behaviors, as indicated by the power law index of 0.99 (<1). The mixture of d-mannitol (70 mol%)+d-dulcitol is a nonlinear Bingham fluid, exhibiting a slight yield stress (0.001 Pa to 0.01 Pa) at low shear rates. The rest two mixtures containing the cyclic-structured inositol behave like Herschel-Bulkley fluids. The infinite shear viscosities of the eutectic mixtures over the entire temperature range appear to be higher than those of their respective pure compounds, except for inositol. The mixture of xylitol (75 mol%)+erythritol at its melting point shows higher dynamic viscosity of about 0.546 Pa·s than the values of about 0.396 Pa·s and 0.035 Pa·s for xylitol and erythritol, respectively. In addition, the activation energies of viscous flow of the mixtures, as determined by fitting the dynamic viscosity-temperature curves using the Arrhenius model, also exhibit higher values than those of their pure compounds. The activation energy of viscous flow of the mixture xylitol (75 mol%)+erythritol was determined to be about 92 400 J/mol in the supercooled liquid state, while the supercooled liquid xylitol and erythritol have much lower values of 83 500 J/mol and 51 900 J/mol, respectively. Both the increased dynamic viscosities and activation energies of viscous flow can result in deteriorated crystallization performance during latent heat retrieval.</abstract><cop>Heidelberg</cop><pub>Science Press</pub><doi>10.1007/s11630-021-1279-9</doi><tpages>13</tpages></addata></record> |
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| subjects | Activation energy Alcohol Alcohols Classical and Continuum Physics Comparative studies Crystallization Curve fitting Engineering Engineering Fluid Dynamics Engineering Thermodynamics Engineering, Mechanical Erythritol Eutectics Heat Heat and Mass Transfer Heat storage Latent heat Mannitol Melting points Physical Sciences Physics Physics and Astronomy Polyols Pseudoplasticity Rheological properties Rheology Science & Technology Shear Shear thinning (liquids) Technology Temperature dependence Thermodynamics Viscosity Viscous flow Xylitol Yield stress |
| title | Temperature-Dependent Rheological Behaviors of Binary Eutectic Mixtures of Sugar Alcohols for Latent Heat Storage: A Comparative Study with Pure Sugar Alcohols |
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