An Investigation on Opto-thermo-mechanical Behaviour of a Borate Family NLO Crystal for Photonic Applications
A borate family crystal, thiourea hydrogen borate, a nonlinear material (NLO), is grown, and its optical and physicochemical properties are investigated. Single-crystal X-ray diffraction study conducted reveals triclinic structure of the crystal. Energy-dispersive X-ray analysis is performed to dete...
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| Veröffentlicht in: | Brazilian journal of physics 2021-12, Vol.51 (6), p.1625-1635 |
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| container_title | Brazilian journal of physics |
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| creator | Divya, M. Malliga, P. Pragasam, A. Joseph Arul |
| description | A borate family crystal, thiourea hydrogen borate, a nonlinear material (NLO), is grown, and its optical and physicochemical properties are investigated. Single-crystal X-ray diffraction study conducted reveals triclinic structure of the crystal. Energy-dispersive X-ray analysis is performed to determine the elemental composition of the material. Fourier transform infrared spectral analysis is done to identify the functional groups. Ultraviolet (UV) characterization is done to figure out the optical properties like the fundamental frequency and optical band gap for nonlinear applications. Second harmonic generation analysis shows the crystal to possess centrosymmetric structure. Third-order analysis is conducted to deduce the third-order susceptibility (
χ
3
). Thermal gravimetric analysis and differential thermal analysis are performed to determine the decomposition temperature and process of decomposition. Mechanical stability is examined by Vickers microhardness test, and the mechanical properties have been inspected for photonic applications. |
| doi_str_mv | 10.1007/s13538-021-00988-3 |
| format | Article |
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χ
3
). Thermal gravimetric analysis and differential thermal analysis are performed to determine the decomposition temperature and process of decomposition. Mechanical stability is examined by Vickers microhardness test, and the mechanical properties have been inspected for photonic applications.</description><identifier>ISSN: 0103-9733</identifier><identifier>EISSN: 1678-4448</identifier><identifier>DOI: 10.1007/s13538-021-00988-3</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Condensed Matter ; Crystal structure ; Crystals ; Decomposition ; Diamond pyramid hardness ; Differential thermal analysis ; Fourier transforms ; Functional groups ; Gravimetric analysis ; Infrared analysis ; Mechanical properties ; Optical properties ; Photonic crystals ; Physics ; Physics and Astronomy ; Resonant frequencies ; Second harmonic generation ; Single crystals ; Spectrum analysis ; X ray analysis</subject><ispartof>Brazilian journal of physics, 2021-12, Vol.51 (6), p.1625-1635</ispartof><rights>Sociedade Brasileira de Física 2021</rights><rights>Sociedade Brasileira de Física 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-8b6f5581a478a7ba0a0edceaa2ecf639def790a52548a6663a8b3862536cad2f3</citedby><cites>FETCH-LOGICAL-c319t-8b6f5581a478a7ba0a0edceaa2ecf639def790a52548a6663a8b3862536cad2f3</cites><orcidid>0000-0003-2887-2487</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13538-021-00988-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13538-021-00988-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Divya, M.</creatorcontrib><creatorcontrib>Malliga, P.</creatorcontrib><creatorcontrib>Pragasam, A. Joseph Arul</creatorcontrib><title>An Investigation on Opto-thermo-mechanical Behaviour of a Borate Family NLO Crystal for Photonic Applications</title><title>Brazilian journal of physics</title><addtitle>Braz J Phys</addtitle><description>A borate family crystal, thiourea hydrogen borate, a nonlinear material (NLO), is grown, and its optical and physicochemical properties are investigated. Single-crystal X-ray diffraction study conducted reveals triclinic structure of the crystal. Energy-dispersive X-ray analysis is performed to determine the elemental composition of the material. Fourier transform infrared spectral analysis is done to identify the functional groups. Ultraviolet (UV) characterization is done to figure out the optical properties like the fundamental frequency and optical band gap for nonlinear applications. Second harmonic generation analysis shows the crystal to possess centrosymmetric structure. Third-order analysis is conducted to deduce the third-order susceptibility (
χ
3
). Thermal gravimetric analysis and differential thermal analysis are performed to determine the decomposition temperature and process of decomposition. Mechanical stability is examined by Vickers microhardness test, and the mechanical properties have been inspected for photonic applications.</description><subject>Condensed Matter</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Decomposition</subject><subject>Diamond pyramid hardness</subject><subject>Differential thermal analysis</subject><subject>Fourier transforms</subject><subject>Functional groups</subject><subject>Gravimetric analysis</subject><subject>Infrared analysis</subject><subject>Mechanical properties</subject><subject>Optical properties</subject><subject>Photonic crystals</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Resonant frequencies</subject><subject>Second harmonic generation</subject><subject>Single crystals</subject><subject>Spectrum analysis</subject><subject>X ray analysis</subject><issn>0103-9733</issn><issn>1678-4448</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kEFLwzAUx4MoOKdfwFPAc_SladL0uA2ng-E86Dm8denasTY16Qb79mZW8CYE3uX_-7-8HyH3HB45QPYUuJBCM0g4A8i1ZuKCjLjKNEvTVF-SEXAQLM-EuCY3IewAEgmpGJFm0tJFe7Shr7fY166l8a263rG-sr5xrLFFhW1d4J5ObYXH2h08dSVFOnUee0vn2NT7E31brujMn0Ifg6Xz9L1yvYscnXTdPuLn7nBLrkrcB3v3O8fkc_78MXtly9XLYjZZskLwvGd6rUopNcc005itERDsprCIiS1KJfKNLbMcUCYy1aiUEqjXQqtEClXgJinFmDwMvZ13X4d4nNnFb7dxpUmkVhK0AoipZEgV3oXgbWk6XzfoT4aDOWs1g1YTtZofrUZESAxQiOF2a_1f9T_UN5yge6Y</recordid><startdate>20211201</startdate><enddate>20211201</enddate><creator>Divya, M.</creator><creator>Malliga, P.</creator><creator>Pragasam, A. Joseph Arul</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2887-2487</orcidid></search><sort><creationdate>20211201</creationdate><title>An Investigation on Opto-thermo-mechanical Behaviour of a Borate Family NLO Crystal for Photonic Applications</title><author>Divya, M. ; Malliga, P. ; Pragasam, A. Joseph Arul</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-8b6f5581a478a7ba0a0edceaa2ecf639def790a52548a6663a8b3862536cad2f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Condensed Matter</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Decomposition</topic><topic>Diamond pyramid hardness</topic><topic>Differential thermal analysis</topic><topic>Fourier transforms</topic><topic>Functional groups</topic><topic>Gravimetric analysis</topic><topic>Infrared analysis</topic><topic>Mechanical properties</topic><topic>Optical properties</topic><topic>Photonic crystals</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Resonant frequencies</topic><topic>Second harmonic generation</topic><topic>Single crystals</topic><topic>Spectrum analysis</topic><topic>X ray analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Divya, M.</creatorcontrib><creatorcontrib>Malliga, P.</creatorcontrib><creatorcontrib>Pragasam, A. Joseph Arul</creatorcontrib><collection>CrossRef</collection><jtitle>Brazilian journal of physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Divya, M.</au><au>Malliga, P.</au><au>Pragasam, A. Joseph Arul</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Investigation on Opto-thermo-mechanical Behaviour of a Borate Family NLO Crystal for Photonic Applications</atitle><jtitle>Brazilian journal of physics</jtitle><stitle>Braz J Phys</stitle><date>2021-12-01</date><risdate>2021</risdate><volume>51</volume><issue>6</issue><spage>1625</spage><epage>1635</epage><pages>1625-1635</pages><issn>0103-9733</issn><eissn>1678-4448</eissn><abstract>A borate family crystal, thiourea hydrogen borate, a nonlinear material (NLO), is grown, and its optical and physicochemical properties are investigated. Single-crystal X-ray diffraction study conducted reveals triclinic structure of the crystal. Energy-dispersive X-ray analysis is performed to determine the elemental composition of the material. Fourier transform infrared spectral analysis is done to identify the functional groups. Ultraviolet (UV) characterization is done to figure out the optical properties like the fundamental frequency and optical band gap for nonlinear applications. Second harmonic generation analysis shows the crystal to possess centrosymmetric structure. Third-order analysis is conducted to deduce the third-order susceptibility (
χ
3
). Thermal gravimetric analysis and differential thermal analysis are performed to determine the decomposition temperature and process of decomposition. Mechanical stability is examined by Vickers microhardness test, and the mechanical properties have been inspected for photonic applications.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s13538-021-00988-3</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0003-2887-2487</orcidid></addata></record> |
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| subjects | Condensed Matter Crystal structure Crystals Decomposition Diamond pyramid hardness Differential thermal analysis Fourier transforms Functional groups Gravimetric analysis Infrared analysis Mechanical properties Optical properties Photonic crystals Physics Physics and Astronomy Resonant frequencies Second harmonic generation Single crystals Spectrum analysis X ray analysis |
| title | An Investigation on Opto-thermo-mechanical Behaviour of a Borate Family NLO Crystal for Photonic Applications |
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