Modification of the mechanism of proton conductivity of the perfluorinated membrane copolymer by nanodiamonds

Proton conducting membranes based on a perfluorinated copolymer with short side chains (of the Aquivion® type) are promising for the use in hydrogen fuel cells and overcome in characteristics traditionally used long-chain membranes of the Nation® type. To improve the characteristics of Aquivion® mem...

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Veröffentlicht in:Russian chemical bulletin 2021-09, Vol.70 (9), p.1713-1717
Hauptverfasser: Kulvelis, Yu. V., Primachenko, O. N., Gofman, I. V., Odinokov, A. S., Shvidchenko, A. V., Yudina, E. B., Marinenko, E. A., Lebedev, V. T., Vul, A. Ya
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container_end_page 1717
container_issue 9
container_start_page 1713
container_title Russian chemical bulletin
container_volume 70
creator Kulvelis, Yu. V.
Primachenko, O. N.
Gofman, I. V.
Odinokov, A. S.
Shvidchenko, A. V.
Yudina, E. B.
Marinenko, E. A.
Lebedev, V. T.
Vul, A. Ya
description Proton conducting membranes based on a perfluorinated copolymer with short side chains (of the Aquivion® type) are promising for the use in hydrogen fuel cells and overcome in characteristics traditionally used long-chain membranes of the Nation® type. To improve the characteristics of Aquivion® membranes, we used modifying additives in the form of functionalized nanodiamonds. The mechanism of proton conductivity of composite membranes with nanodiamonds is modified by introducing additional ionogenic groups into the structure on the surface of nanodiamonds. The dependences of the conductivity and mechanical properties of the prepared composite membranes on the sign of the surface charge of the introduced nanodiamonds are examined.
doi_str_mv 10.1007/s11172-021-3274-4
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subjects Additives
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Copolymers
Diamonds
Fuel cells
Full Articles
Hydrogen fuels
Inorganic Chemistry
Mechanical properties
Membranes
Nanostructure
Organic Chemistry
Protons
Surface charge
title Modification of the mechanism of proton conductivity of the perfluorinated membrane copolymer by nanodiamonds
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