Modification of the mechanism of proton conductivity of the perfluorinated membrane copolymer by nanodiamonds
Proton conducting membranes based on a perfluorinated copolymer with short side chains (of the Aquivion® type) are promising for the use in hydrogen fuel cells and overcome in characteristics traditionally used long-chain membranes of the Nation® type. To improve the characteristics of Aquivion® mem...
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Veröffentlicht in: | Russian chemical bulletin 2021-09, Vol.70 (9), p.1713-1717 |
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creator | Kulvelis, Yu. V. Primachenko, O. N. Gofman, I. V. Odinokov, A. S. Shvidchenko, A. V. Yudina, E. B. Marinenko, E. A. Lebedev, V. T. Vul, A. Ya |
description | Proton conducting membranes based on a perfluorinated copolymer with short side chains (of the Aquivion® type) are promising for the use in hydrogen fuel cells and overcome in characteristics traditionally used long-chain membranes of the Nation® type. To improve the characteristics of Aquivion® membranes, we used modifying additives in the form of functionalized nanodiamonds. The mechanism of proton conductivity of composite membranes with nanodiamonds is modified by introducing additional ionogenic groups into the structure on the surface of nanodiamonds. The dependences of the conductivity and mechanical properties of the prepared composite membranes on the sign of the surface charge of the introduced nanodiamonds are examined. |
doi_str_mv | 10.1007/s11172-021-3274-4 |
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The dependences of the conductivity and mechanical properties of the prepared composite membranes on the sign of the surface charge of the introduced nanodiamonds are examined.</description><identifier>ISSN: 1066-5285</identifier><identifier>EISSN: 1573-9171</identifier><identifier>DOI: 10.1007/s11172-021-3274-4</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Additives ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Copolymers ; Diamonds ; Fuel cells ; Full Articles ; Hydrogen fuels ; Inorganic Chemistry ; Mechanical properties ; Membranes ; Nanostructure ; Organic Chemistry ; Protons ; Surface charge</subject><ispartof>Russian chemical bulletin, 2021-09, Vol.70 (9), p.1713-1717</ispartof><rights>Springer Science+Business Media LLC 2021</rights><rights>Springer Science+Business Media LLC 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-95ee06e8f29dd2151c781963a8be266d8f6564b542259e611a426b8009fb47783</citedby><cites>FETCH-LOGICAL-c316t-95ee06e8f29dd2151c781963a8be266d8f6564b542259e611a426b8009fb47783</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11172-021-3274-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11172-021-3274-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Kulvelis, Yu. 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The mechanism of proton conductivity of composite membranes with nanodiamonds is modified by introducing additional ionogenic groups into the structure on the surface of nanodiamonds. The dependences of the conductivity and mechanical properties of the prepared composite membranes on the sign of the surface charge of the introduced nanodiamonds are examined.</description><subject>Additives</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Copolymers</subject><subject>Diamonds</subject><subject>Fuel cells</subject><subject>Full Articles</subject><subject>Hydrogen fuels</subject><subject>Inorganic Chemistry</subject><subject>Mechanical properties</subject><subject>Membranes</subject><subject>Nanostructure</subject><subject>Organic Chemistry</subject><subject>Protons</subject><subject>Surface charge</subject><issn>1066-5285</issn><issn>1573-9171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAQhoMouK7-AG8Fz9VMmq8eZfELFC96DmmbuFm2SU1aof_eLFU8ecqQeZ6Z4UXoEvA1YCxuEgAIUmICZUUELekRWgETVVmDgONcY85LRiQ7RWcp7TDGREq5Qv1L6Jx1rR5d8EWwxbg1RW_arfYu9YePIYYxt9rgu6kd3Zcb519uMNHupxCd16PpstY3UXuT2SHs597EopkLr31eofvsp3N0YvU-mYufd43e7-_eNo_l8-vD0-b2uWwr4GNZM2MwN9KSuusIMGiFhJpXWjaGcN5JyxmnDaOEsNpwAE0JbyTGtW2oELJao6tlbj7-czJpVLswRZ9XKsIkZxioFJmChWpjSCkaq4boeh1nBVgdUlVLqiqnqg6pKpodsjgps_7DxL_J_0vfVF97Mw</recordid><startdate>20210901</startdate><enddate>20210901</enddate><creator>Kulvelis, Yu. 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subjects | Additives Chemistry Chemistry and Materials Science Chemistry/Food Science Copolymers Diamonds Fuel cells Full Articles Hydrogen fuels Inorganic Chemistry Mechanical properties Membranes Nanostructure Organic Chemistry Protons Surface charge |
title | Modification of the mechanism of proton conductivity of the perfluorinated membrane copolymer by nanodiamonds |
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