Frontispiece: Large Isotope Effects in Organometallic Chemistry

Frontispiece: Large Isotope Effects in Organometallic Chemistry

Hydrogen atoms sometimes react far faster than deuterium atoms. Reactions can proceed over 100 times faster with hydrogen, or the deuterium reaction may not be observed at all. Examples of large kinetic isotope effects throughout organotransition metal chemistry are reviewed. Possible causes for the...

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Veröffentlicht in:Chemistry : a European journal 2021-10, Vol.27 (60), p.n/a
Hauptverfasser: Truong, Phan T., Miller, Sophia G., McLaughlin Sta. Maria, Emily J., Bowring, Miriam A.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
C−H activation
Deuterium
Hydrogen
Hydrogen atoms
isotope effects
Isotopes
kinetics
Organometallic compounds
protonation
reaction mechanisms
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container_issue 60
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container_title Chemistry : a European journal
container_volume 27
creator Truong, Phan T.
Miller, Sophia G.
McLaughlin Sta. Maria, Emily J.
Bowring, Miriam A.
description Hydrogen atoms sometimes react far faster than deuterium atoms. Reactions can proceed over 100 times faster with hydrogen, or the deuterium reaction may not be observed at all. Examples of large kinetic isotope effects throughout organotransition metal chemistry are reviewed. Possible causes for these observed effects are discussed, including vibrational differences, multistep reactions, and proton tunneling. Artwork depicting a hydrogen cheetah and a deuterium sloth by Caitlyn Y. Tong. Read more in the Minireview by M. A. Bowring et al. on page 14800 ff.
doi_str_mv 10.1002/chem.202186061
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subjects Chemistry
C−H activation
Deuterium
Hydrogen
Hydrogen atoms
isotope effects
Isotopes
kinetics
Organometallic compounds
protonation
reaction mechanisms
title Frontispiece: Large Isotope Effects in Organometallic Chemistry
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