Synthesis of Porous Confined Ionic Liquid Phosphotungstate Based on MIL-101 and its Solvent-Free Catalytic Oxidation of Cyclohexene to Adipic Acid
A series of porous confined ionic liquid phosphotungstate were synthesized by encapsulated of N-(3-sulfopropyl)morpholinium phosphotungstate ([C 3 SO 3 Hnhm] 3 -PW 12 O 40 ) into MIL-101. Then the aforementioned porous confined ionic liquid phosphotungstate as heterogeneous catalyst will be used tog...
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| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2021-11, Vol.31 (11), p.4195-4208 |
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| creator | Wang, Lulu Zeng, Xiangrui Wang, Haiyan Wang, Yujia |
| description | A series of porous confined ionic liquid phosphotungstate were synthesized by encapsulated of N-(3-sulfopropyl)morpholinium phosphotungstate ([C
3
SO
3
Hnhm]
3
-PW
12
O
40
) into MIL-101. Then the aforementioned porous confined ionic liquid phosphotungstate as heterogeneous catalyst will be used together with H
2
O
2
for the catalytic synthesis of adipic acid from cyclohexene. During the experiment, the effect of weight content of [C
3
SO
3
Hnhm]
3
PW
12
O
40
on the catalytic performance was investigated in detail. And the chemical structure of the catalyst was also characterized by XRD, FT-IR,
1
H-NMR, SEM–EDX and N
2
adsorption–desorption isotherms. Experimental results revealed that the desired products has been successfully prepared, and the best catalytic performance (81.2% yield of the adipic acid) was obtained under the dose of [C
3
SO
3
Hnhm]
3
PW
12
O
40
was 31wt%, which was almost close to the catalytic activity of original [C
3
SO
3
Hnhm]
3
PW
12
O
40
(85.3% yield of the adipic acid), which was also proved the strategy of packaging ionic liquid phosphotungstate with MIL-101 in this research is feasible. Furthermore, recycled catalytic performance of the catalyst under repeat 6 times was evaluated and the result revealed that the yield in adipic acid was still higher than 80.0%, which also proved that the catalytic active component was stable in the catalyst.
Graphic Abstract |
| doi_str_mv | 10.1007/s10904-021-02094-y |
| format | Article |
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3
SO
3
Hnhm]
3
-PW
12
O
40
) into MIL-101. Then the aforementioned porous confined ionic liquid phosphotungstate as heterogeneous catalyst will be used together with H
2
O
2
for the catalytic synthesis of adipic acid from cyclohexene. During the experiment, the effect of weight content of [C
3
SO
3
Hnhm]
3
PW
12
O
40
on the catalytic performance was investigated in detail. And the chemical structure of the catalyst was also characterized by XRD, FT-IR,
1
H-NMR, SEM–EDX and N
2
adsorption–desorption isotherms. Experimental results revealed that the desired products has been successfully prepared, and the best catalytic performance (81.2% yield of the adipic acid) was obtained under the dose of [C
3
SO
3
Hnhm]
3
PW
12
O
40
was 31wt%, which was almost close to the catalytic activity of original [C
3
SO
3
Hnhm]
3
PW
12
O
40
(85.3% yield of the adipic acid), which was also proved the strategy of packaging ionic liquid phosphotungstate with MIL-101 in this research is feasible. Furthermore, recycled catalytic performance of the catalyst under repeat 6 times was evaluated and the result revealed that the yield in adipic acid was still higher than 80.0%, which also proved that the catalytic active component was stable in the catalyst.
Graphic Abstract</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-021-02094-y</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Acids ; Catalysts ; Catalytic activity ; Catalytic oxidation ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Cyclohexene ; Hydrogen peroxide ; Inorganic Chemistry ; Ionic liquids ; Ions ; NMR ; Nuclear magnetic resonance ; Nylon ; Organic Chemistry ; Oxidation ; Polymer Sciences</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2021-11, Vol.31 (11), p.4195-4208</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c363t-ebe1d12763f7872d7c1e0ccfe3d379e390e10291fa348ef044415e5b2d200cf3</citedby><cites>FETCH-LOGICAL-c363t-ebe1d12763f7872d7c1e0ccfe3d379e390e10291fa348ef044415e5b2d200cf3</cites><orcidid>0000-0001-5840-0435</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-021-02094-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-021-02094-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Wang, Lulu</creatorcontrib><creatorcontrib>Zeng, Xiangrui</creatorcontrib><creatorcontrib>Wang, Haiyan</creatorcontrib><creatorcontrib>Wang, Yujia</creatorcontrib><title>Synthesis of Porous Confined Ionic Liquid Phosphotungstate Based on MIL-101 and its Solvent-Free Catalytic Oxidation of Cyclohexene to Adipic Acid</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>A series of porous confined ionic liquid phosphotungstate were synthesized by encapsulated of N-(3-sulfopropyl)morpholinium phosphotungstate ([C
3
SO
3
Hnhm]
3
-PW
12
O
40
) into MIL-101. Then the aforementioned porous confined ionic liquid phosphotungstate as heterogeneous catalyst will be used together with H
2
O
2
for the catalytic synthesis of adipic acid from cyclohexene. During the experiment, the effect of weight content of [C
3
SO
3
Hnhm]
3
PW
12
O
40
on the catalytic performance was investigated in detail. And the chemical structure of the catalyst was also characterized by XRD, FT-IR,
1
H-NMR, SEM–EDX and N
2
adsorption–desorption isotherms. Experimental results revealed that the desired products has been successfully prepared, and the best catalytic performance (81.2% yield of the adipic acid) was obtained under the dose of [C
3
SO
3
Hnhm]
3
PW
12
O
40
was 31wt%, which was almost close to the catalytic activity of original [C
3
SO
3
Hnhm]
3
PW
12
O
40
(85.3% yield of the adipic acid), which was also proved the strategy of packaging ionic liquid phosphotungstate with MIL-101 in this research is feasible. Furthermore, recycled catalytic performance of the catalyst under repeat 6 times was evaluated and the result revealed that the yield in adipic acid was still higher than 80.0%, which also proved that the catalytic active component was stable in the catalyst.
Graphic Abstract</description><subject>Acids</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Catalytic oxidation</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cyclohexene</subject><subject>Hydrogen peroxide</subject><subject>Inorganic Chemistry</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Nylon</subject><subject>Organic Chemistry</subject><subject>Oxidation</subject><subject>Polymer Sciences</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kMFOGzEQhlcVlQq0L9CTpZ6XztjebPaYrgpECgIJ7paxx8QotYPtRexr8MR1mwpuPYxmDt__j_Q1zVeEMwTov2eEAWQLHOvAINv5Q3OMXS9blB0evd1SfGpOcn4EEEvo8Lh5vZ1D2VL2mUXHbmKKU2ZjDM4Hsmwdgzds458mb9nNNub9NpYpPOSiC7EfOlcmBna13rQIyHSwzJfMbuPumUJpzxMRG3XRu7nUnusXb3XxNVBfjbPZxS29UCBWIltZv6_Iynj7ufno9C7Tl3_7tLk7_3k3Xrab64v1uNq0RixEaeme0CLvF8L1y57b3iCBMY6EFf1AYgBC4AM6LeSSHEgpsaPunlsOYJw4bb4davcpPk2Ui3qMUwr1o-LdshtkJ_miUvxAmRRzTuTUPvlfOs0KQf1Rrw7qVVWv_qpXcw2JQyhXODxQeq_-T-o34zGIGg</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Wang, Lulu</creator><creator>Zeng, Xiangrui</creator><creator>Wang, Haiyan</creator><creator>Wang, Yujia</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-5840-0435</orcidid></search><sort><creationdate>20211101</creationdate><title>Synthesis of Porous Confined Ionic Liquid Phosphotungstate Based on MIL-101 and its Solvent-Free Catalytic Oxidation of Cyclohexene to Adipic Acid</title><author>Wang, Lulu ; Zeng, Xiangrui ; Wang, Haiyan ; Wang, Yujia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-ebe1d12763f7872d7c1e0ccfe3d379e390e10291fa348ef044415e5b2d200cf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acids</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Catalytic oxidation</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cyclohexene</topic><topic>Hydrogen peroxide</topic><topic>Inorganic Chemistry</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Nylon</topic><topic>Organic Chemistry</topic><topic>Oxidation</topic><topic>Polymer Sciences</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Lulu</creatorcontrib><creatorcontrib>Zeng, Xiangrui</creatorcontrib><creatorcontrib>Wang, Haiyan</creatorcontrib><creatorcontrib>Wang, Yujia</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Lulu</au><au>Zeng, Xiangrui</au><au>Wang, Haiyan</au><au>Wang, Yujia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Porous Confined Ionic Liquid Phosphotungstate Based on MIL-101 and its Solvent-Free Catalytic Oxidation of Cyclohexene to Adipic Acid</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2021-11-01</date><risdate>2021</risdate><volume>31</volume><issue>11</issue><spage>4195</spage><epage>4208</epage><pages>4195-4208</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>A series of porous confined ionic liquid phosphotungstate were synthesized by encapsulated of N-(3-sulfopropyl)morpholinium phosphotungstate ([C
3
SO
3
Hnhm]
3
-PW
12
O
40
) into MIL-101. Then the aforementioned porous confined ionic liquid phosphotungstate as heterogeneous catalyst will be used together with H
2
O
2
for the catalytic synthesis of adipic acid from cyclohexene. During the experiment, the effect of weight content of [C
3
SO
3
Hnhm]
3
PW
12
O
40
on the catalytic performance was investigated in detail. And the chemical structure of the catalyst was also characterized by XRD, FT-IR,
1
H-NMR, SEM–EDX and N
2
adsorption–desorption isotherms. Experimental results revealed that the desired products has been successfully prepared, and the best catalytic performance (81.2% yield of the adipic acid) was obtained under the dose of [C
3
SO
3
Hnhm]
3
PW
12
O
40
was 31wt%, which was almost close to the catalytic activity of original [C
3
SO
3
Hnhm]
3
PW
12
O
40
(85.3% yield of the adipic acid), which was also proved the strategy of packaging ionic liquid phosphotungstate with MIL-101 in this research is feasible. Furthermore, recycled catalytic performance of the catalyst under repeat 6 times was evaluated and the result revealed that the yield in adipic acid was still higher than 80.0%, which also proved that the catalytic active component was stable in the catalyst.
Graphic Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-021-02094-y</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0001-5840-0435</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Acids Catalysts Catalytic activity Catalytic oxidation Chemical synthesis Chemistry Chemistry and Materials Science Cyclohexene Hydrogen peroxide Inorganic Chemistry Ionic liquids Ions NMR Nuclear magnetic resonance Nylon Organic Chemistry Oxidation Polymer Sciences |
| title | Synthesis of Porous Confined Ionic Liquid Phosphotungstate Based on MIL-101 and its Solvent-Free Catalytic Oxidation of Cyclohexene to Adipic Acid |
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