Hydroboration of carbonyls and imines by an iminophosphonamido tin() precatalyst

A novel three-coordinated tin( ii ) chloride [Ph 2 P(N t Bu) 2 ]SnCl ( 1 ) supported by an N , N ′-di- tert -butyliminophosphonamide having two phenyl groups on the phosphorus atom was synthesized by the reaction of the starting lithium iminophosphonamide [Ph 2 P(N t Bu) 2 ]Li with SnCl 2 ·(dioxane)...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2021-10, Vol.5 (41), p.1481-14819
Hauptverfasser:	Nakaya, Kazuki, Takahashi, Shintaro, Ishii, Akihiko, Boonpalit, Kajjana, Surawatanawong, Panida, Nakata, Norio
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Carbonyls Chemical synthesis Chlorides Esters Hydrides Hydroboration Imines Ketones Lithium Molecular structure NMR Nuclear magnetic resonance Substrates Toluene
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!