Straightforward formation of dianionic acetonylate: self-assembly of mercury() with pyridyl donor ligands in acetone
Self-assembly of Hg(ClO 4 ) 2 with a new bidentate ligand (L) in acetone at room temperature produces single crystals consisting of unusual discrete tetranuclear complexes [Hg 4 (ClO 4 ) 4 (CH 2 COCH 2 ) 2 L 2 ]·CH 3 COCH 3 via straightforward formation of dianionic acetonylate − CH 2 COCH 2 − in a...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2021-10, Vol.5 (41), p.14547-1455 |
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| container_issue | 41 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 5 |
| creator | Hong, Kangsan Lim, Sangwoo Moon, Heehun Kim, Dongwon Kim, Dongwook Jung, Ok-Sang |
| description | Self-assembly of Hg(ClO
4
)
2
with a new bidentate ligand (L) in acetone at room temperature produces single crystals consisting of unusual discrete tetranuclear complexes [Hg
4
(ClO
4
)
4
(CH
2
COCH
2
)
2
L
2
]·CH
3
COCH
3
via
straightforward formation of dianionic acetonylate
−
CH
2
COCH
2
−
in a quantitative yield.
Self-assembly of Hg(ClO
4
)
2
with a horse-shoe type ligand in acetone at room temperature produces single crystals consisting of [Hg
4
(ClO
4
)
4
(CH
2
COCH
2
)
2
L
2
]·CH
3
COCH
3
via
straightforward formation of dianionic acetonylate
−
CH
2
COCH
2
−
in high yields. |
| doi_str_mv | 10.1039/d1dt03115e |
| format | Article |
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4
)
2
with a new bidentate ligand (L) in acetone at room temperature produces single crystals consisting of unusual discrete tetranuclear complexes [Hg
4
(ClO
4
)
4
(CH
2
COCH
2
)
2
L
2
]·CH
3
COCH
3
via
straightforward formation of dianionic acetonylate
−
CH
2
COCH
2
−
in a quantitative yield.
Self-assembly of Hg(ClO
4
)
2
with a horse-shoe type ligand in acetone at room temperature produces single crystals consisting of [Hg
4
(ClO
4
)
4
(CH
2
COCH
2
)
2
L
2
]·CH
3
COCH
3
via
straightforward formation of dianionic acetonylate
−
CH
2
COCH
2
−
in high yields.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d1dt03115e</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Acetone ; Crystals ; Ligands ; Mercury compounds ; Room temperature ; Self-assembly ; Single crystals</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2021-10, Vol.5 (41), p.14547-1455</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c314t-ea498a13fbd77d8fa26b2a7b680b228bbb5b762071a0fb0db5f9d678ab7e208d3</citedby><cites>FETCH-LOGICAL-c314t-ea498a13fbd77d8fa26b2a7b680b228bbb5b762071a0fb0db5f9d678ab7e208d3</cites><orcidid>0000-0003-4432-371X ; 0000-0002-7218-457X ; 0000-0002-7950-5487</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Hong, Kangsan</creatorcontrib><creatorcontrib>Lim, Sangwoo</creatorcontrib><creatorcontrib>Moon, Heehun</creatorcontrib><creatorcontrib>Kim, Dongwon</creatorcontrib><creatorcontrib>Kim, Dongwook</creatorcontrib><creatorcontrib>Jung, Ok-Sang</creatorcontrib><title>Straightforward formation of dianionic acetonylate: self-assembly of mercury() with pyridyl donor ligands in acetone</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>Self-assembly of Hg(ClO
4
)
2
with a new bidentate ligand (L) in acetone at room temperature produces single crystals consisting of unusual discrete tetranuclear complexes [Hg
4
(ClO
4
)
4
(CH
2
COCH
2
)
2
L
2
]·CH
3
COCH
3
via
straightforward formation of dianionic acetonylate
−
CH
2
COCH
2
−
in a quantitative yield.
Self-assembly of Hg(ClO
4
)
2
with a horse-shoe type ligand in acetone at room temperature produces single crystals consisting of [Hg
4
(ClO
4
)
4
(CH
2
COCH
2
)
2
L
2
]·CH
3
COCH
3
via
straightforward formation of dianionic acetonylate
−
CH
2
COCH
2
−
in high yields.</description><subject>Acetone</subject><subject>Crystals</subject><subject>Ligands</subject><subject>Mercury compounds</subject><subject>Room temperature</subject><subject>Self-assembly</subject><subject>Single crystals</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpd0c9LwzAUB_AiCs7pxbsQ8DKFan60TetNtvkDBh6c5_LSJFtG28wkY_S_t3Njgqf3Dh--78E3iq4JfiCYFY-SyIAZIak6iQYk4TwuKEtOjzvNzqML71cYU4pTOojCZ3BgFsugrduCk6ifDQRjW2Q1kgbafjUVgkoF23Y1BPWEvKp1DN6rRtTdzjXKVRvXje7Q1oQlWnfOyK5G0rbWodosoJUemfaQoi6jMw21V1eHOYy-Xqbz8Vs8-3h9Hz_P4oqRJMQKkiIHwrSQnMtcA80EBS6yHAtKcyFEKnhGMSeAtcBSpLqQGc9BcEVxLtkwGu1z185-b5QPZWN8peoaWmU3vqRpzpKEFUnW09t_dGU3ru2_26k0x6Q_1Kv7vaqc9d4pXa6dacB1JcHlroByQibz3wKmPb7ZY-ero_sriP0Awx6EQQ</recordid><startdate>20211026</startdate><enddate>20211026</enddate><creator>Hong, Kangsan</creator><creator>Lim, Sangwoo</creator><creator>Moon, Heehun</creator><creator>Kim, Dongwon</creator><creator>Kim, Dongwook</creator><creator>Jung, Ok-Sang</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-4432-371X</orcidid><orcidid>https://orcid.org/0000-0002-7218-457X</orcidid><orcidid>https://orcid.org/0000-0002-7950-5487</orcidid></search><sort><creationdate>20211026</creationdate><title>Straightforward formation of dianionic acetonylate: self-assembly of mercury() with pyridyl donor ligands in acetone</title><author>Hong, Kangsan ; Lim, Sangwoo ; Moon, Heehun ; Kim, Dongwon ; Kim, Dongwook ; Jung, Ok-Sang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c314t-ea498a13fbd77d8fa26b2a7b680b228bbb5b762071a0fb0db5f9d678ab7e208d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acetone</topic><topic>Crystals</topic><topic>Ligands</topic><topic>Mercury compounds</topic><topic>Room temperature</topic><topic>Self-assembly</topic><topic>Single crystals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hong, Kangsan</creatorcontrib><creatorcontrib>Lim, Sangwoo</creatorcontrib><creatorcontrib>Moon, Heehun</creatorcontrib><creatorcontrib>Kim, Dongwon</creatorcontrib><creatorcontrib>Kim, Dongwook</creatorcontrib><creatorcontrib>Jung, Ok-Sang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hong, Kangsan</au><au>Lim, Sangwoo</au><au>Moon, Heehun</au><au>Kim, Dongwon</au><au>Kim, Dongwook</au><au>Jung, Ok-Sang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Straightforward formation of dianionic acetonylate: self-assembly of mercury() with pyridyl donor ligands in acetone</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2021-10-26</date><risdate>2021</risdate><volume>5</volume><issue>41</issue><spage>14547</spage><epage>1455</epage><pages>14547-1455</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Self-assembly of Hg(ClO
4
)
2
with a new bidentate ligand (L) in acetone at room temperature produces single crystals consisting of unusual discrete tetranuclear complexes [Hg
4
(ClO
4
)
4
(CH
2
COCH
2
)
2
L
2
]·CH
3
COCH
3
via
straightforward formation of dianionic acetonylate
−
CH
2
COCH
2
−
in a quantitative yield.
Self-assembly of Hg(ClO
4
)
2
with a horse-shoe type ligand in acetone at room temperature produces single crystals consisting of [Hg
4
(ClO
4
)
4
(CH
2
COCH
2
)
2
L
2
]·CH
3
COCH
3
via
straightforward formation of dianionic acetonylate
−
CH
2
COCH
2
−
in high yields.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1dt03115e</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-4432-371X</orcidid><orcidid>https://orcid.org/0000-0002-7218-457X</orcidid><orcidid>https://orcid.org/0000-0002-7950-5487</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2021-10, Vol.5 (41), p.14547-1455 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_journals_2585801620 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Acetone Crystals Ligands Mercury compounds Room temperature Self-assembly Single crystals |
| title | Straightforward formation of dianionic acetonylate: self-assembly of mercury() with pyridyl donor ligands in acetone |
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