Influence of monomer structure and dose rate on kinetic elements in electron-beam polymerizations

In electron-beam (EB) polymerizations, altering the dose rate can cause property changes in the cured polymer, such as conversion, glass transition temperature (Tg), and physical or mechanical properties. These dose rate effects (DREs) complicate scale-up of EB polymerizations in industrial processe...

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Veröffentlicht in:	Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2021-12, Vol.189, p.109737, Article 109737
Hauptverfasser:	Thiher, Nicole L.K., Schissel, Sage M., Jessop, Julie L.P.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acrylate Dose rate effect Electron beams Gamma rays Glass transition temperature Hydrogen abstraction Mechanical properties Monomers Polymerization Radiation Radiation chemical yield Radiation dosage Radical concentration Radicals Rate of polymerization Reciprocity
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