Hydrogen embrittlement of bulk W-0.5 wt% ZrC alloy induced by annealing in hydrogen atmosphere

Annealing of a tungsten alloy containing 0.5 wt% zirconium carbide (WZC) in hydrogen atmosphere induced hydrogen embrittlement, which was investigated by exploring the evolution of the tungsten grain size and orientation, the second phase particles distribution, and the tensile properties of the hyd...

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Veröffentlicht in:Journal of nuclear materials 2021-12, Vol.556, p.153177, Article 153177
Hauptverfasser: Wang, H., Cheng, X., Zhang, Y.G., Wang, M.M., Zhao, B.L., Xie, Z.M., Zhang, T., Liu, R., Wu, X.B., Wang, X.P., Fang, Q.F., Chen, C.A., Liu, C.S.
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container_issue
container_start_page 153177
container_title Journal of nuclear materials
container_volume 556
creator Wang, H.
Cheng, X.
Zhang, Y.G.
Wang, M.M.
Zhao, B.L.
Xie, Z.M.
Zhang, T.
Liu, R.
Wu, X.B.
Wang, X.P.
Fang, Q.F.
Chen, C.A.
Liu, C.S.
description Annealing of a tungsten alloy containing 0.5 wt% zirconium carbide (WZC) in hydrogen atmosphere induced hydrogen embrittlement, which was investigated by exploring the evolution of the tungsten grain size and orientation, the second phase particles distribution, and the tensile properties of the hydrogen-containing and hydrogen-free WZC samples. Thermal desorption spectroscopy used to determine the hydrogen retention revealed a broad hydrogen desorption peak at 1000 – 1300 K, whose hydrogen origin was attributed to the trapping sites in the non-stoichiometric ZrCx of the WZC samples after annealing in hydrogen atmosphere at 1300 °C. Hydrogen retention resulted in the degradation of mechanical properties including strength and ductility and in the deterioration of the ductile-to-brittle-transition behavior. The results emphasize the importance of the atmosphere choice for annealing tungsten materials to avoid hydrogen embrittlement and to ensure good mechanical properties.
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Thermal desorption spectroscopy used to determine the hydrogen retention revealed a broad hydrogen desorption peak at 1000 – 1300 K, whose hydrogen origin was attributed to the trapping sites in the non-stoichiometric ZrCx of the WZC samples after annealing in hydrogen atmosphere at 1300 °C. Hydrogen retention resulted in the degradation of mechanical properties including strength and ductility and in the deterioration of the ductile-to-brittle-transition behavior. 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subjects Annealing
Atmosphere
Desorption
Ductile-brittle transition
Ductility
Grain size
Hydrogen
Hydrogen embrittlement
Materials Science
Materials Science, Multidisciplinary
Materials selection
Mechanical properties
Nuclear Science & Technology
Retention
Science & Technology
Spectroscopy
Technology
Tensile properties
Thermal desorption spectroscopy
Tungsten
Tungsten base alloys
W-0.5 wt% ZrC
Zirconium
Zirconium carbide
title Hydrogen embrittlement of bulk W-0.5 wt% ZrC alloy induced by annealing in hydrogen atmosphere
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