Improved Catalytic Activity of Composite Beads Calcium Alginate@MIL-101@Fe3O4 Towards Reduction Toxic Organic Dyes
The defiance of this study was to explore the potential of alginate/MIL-101 beads containing Fe 3 O 4 nanoparticles as a catalyst for the reduction of dyes. The Fe 3 O 4 @MIL-101 magnetic composite was obtained by the mechanical method and then encapsulated using calcium alginate (CA) as a crosslink...
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| Veröffentlicht in: | Journal of polymers and the environment 2021-12, Vol.29 (12), p.3813-3826 |
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| container_title | Journal of polymers and the environment |
| container_volume | 29 |
| creator | Hachemaoui, Mohammed Mokhtar, Adel Abdelkrim, Soumia Ouargli-Saker, Rachida Zaoui, Farouk Hamacha, Rachida Habib Zahmani, Hadjira Hacini, Salih Bengueddach, Abdelkader Boukoussa, Bouhadjar |
| description | The defiance of this study was to explore the potential of alginate/MIL-101 beads containing Fe
3
O
4
nanoparticles as a catalyst for the reduction of dyes. The Fe
3
O
4
@MIL-101 magnetic composite was obtained by the mechanical method and then encapsulated using calcium alginate (CA) as a crosslinked matrix. The Fe
3
O
4
(X)@MIL-101/CA composites beads at different content (X) of Fe
3
O
4
nanoparticles were evaluated for the catalytic reduction of methylene blue (MB) and orange G (OG). The aerogel beads have completed the MB dye reduction after 7 min with a rate constant of 0.962 min
–1
. This strong activity is assigned to the synergistic effect between Cr containing MIL-101 the Fe
3
O
4
particles and the hydrides formed on the catalyst surface. The obtained optimal conditions of MB dye reduction were used for the reduction of OG dye in simple and binary system.The best catalyst M(1)@MIL-101/CA showed a high affinity via MB dye in a binary system. Then was easily recovered by an external magnetic field and reused for 4 cycles. On the other hand, the time of the catalytic activity clearly increased in its 4th reuse in the reduction of MB dye but did not affect the efficiency of catalytic reduction. |
| doi_str_mv | 10.1007/s10924-021-02177-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2584645709</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2584645709</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-6192c33fb27af5beec29ec85c6d1a7ef6797949e3a0904adc4c75c567a853c953</originalsourceid><addsrcrecordid>eNp9kE1LAzEQhoMoWKt_wNOC52g-N5tb62q1UClIPYc0my1b9qMmWXX_vakrePMwzDA87zvMC8A1RrcYIXHnMZKEQUTwsYSA7ARMMBcEZhLL0-OcppBwRs_Bhfd7hJCMwglwy-bgug9bJLkOuh5CZZK5CdVHFYakK5O8aw6dr4JN7q0ufKRqU_VNMq93VauDnb0sVxAjPFtYumbJpvvULmKvtuijS9fGzVe0XLudbmN_GKy_BGelrr29-u1T8LZ43OTPcLV-WubzFTQUywBTLImhtNwSoUu-tdYQaU3GTVpgLWyZCikkk5ZqJBHThWFGcMNToTNOjeR0Cm5G3_jge299UPuud208qQjPWMq4QDJSZKSM67x3tlQHVzXaDQojdcxWjdmqmKv6yVaxKKKjyEe43Vn3Z_2P6hu9aHvH</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2584645709</pqid></control><display><type>article</type><title>Improved Catalytic Activity of Composite Beads Calcium Alginate@MIL-101@Fe3O4 Towards Reduction Toxic Organic Dyes</title><source>SpringerLink Journals</source><creator>Hachemaoui, Mohammed ; Mokhtar, Adel ; Abdelkrim, Soumia ; Ouargli-Saker, Rachida ; Zaoui, Farouk ; Hamacha, Rachida ; Habib Zahmani, Hadjira ; Hacini, Salih ; Bengueddach, Abdelkader ; Boukoussa, Bouhadjar</creator><creatorcontrib>Hachemaoui, Mohammed ; Mokhtar, Adel ; Abdelkrim, Soumia ; Ouargli-Saker, Rachida ; Zaoui, Farouk ; Hamacha, Rachida ; Habib Zahmani, Hadjira ; Hacini, Salih ; Bengueddach, Abdelkader ; Boukoussa, Bouhadjar</creatorcontrib><description>The defiance of this study was to explore the potential of alginate/MIL-101 beads containing Fe
3
O
4
nanoparticles as a catalyst for the reduction of dyes. The Fe
3
O
4
@MIL-101 magnetic composite was obtained by the mechanical method and then encapsulated using calcium alginate (CA) as a crosslinked matrix. The Fe
3
O
4
(X)@MIL-101/CA composites beads at different content (X) of Fe
3
O
4
nanoparticles were evaluated for the catalytic reduction of methylene blue (MB) and orange G (OG). The aerogel beads have completed the MB dye reduction after 7 min with a rate constant of 0.962 min
–1
. This strong activity is assigned to the synergistic effect between Cr containing MIL-101 the Fe
3
O
4
particles and the hydrides formed on the catalyst surface. The obtained optimal conditions of MB dye reduction were used for the reduction of OG dye in simple and binary system.The best catalyst M(1)@MIL-101/CA showed a high affinity via MB dye in a binary system. Then was easily recovered by an external magnetic field and reused for 4 cycles. On the other hand, the time of the catalytic activity clearly increased in its 4th reuse in the reduction of MB dye but did not affect the efficiency of catalytic reduction.</description><identifier>ISSN: 1566-2543</identifier><identifier>EISSN: 1572-8919</identifier><identifier>DOI: 10.1007/s10924-021-02177-4</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aerogels ; Alginic acid ; Beads ; Binary system ; Calcium ; Calcium alginate ; Catalysts ; Catalytic activity ; Chemical reduction ; Chemistry ; Chemistry and Materials Science ; Dyes ; Environmental Chemistry ; Environmental Engineering/Biotechnology ; Industrial Chemistry/Chemical Engineering ; Iron oxides ; Magnetic fields ; Materials Science ; Methylene blue ; Nanoparticles ; Polymer Sciences ; Review ; Synergistic effect</subject><ispartof>Journal of polymers and the environment, 2021-12, Vol.29 (12), p.3813-3826</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-6192c33fb27af5beec29ec85c6d1a7ef6797949e3a0904adc4c75c567a853c953</citedby><cites>FETCH-LOGICAL-c319t-6192c33fb27af5beec29ec85c6d1a7ef6797949e3a0904adc4c75c567a853c953</cites><orcidid>0000-0001-6008-9826</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10924-021-02177-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10924-021-02177-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Hachemaoui, Mohammed</creatorcontrib><creatorcontrib>Mokhtar, Adel</creatorcontrib><creatorcontrib>Abdelkrim, Soumia</creatorcontrib><creatorcontrib>Ouargli-Saker, Rachida</creatorcontrib><creatorcontrib>Zaoui, Farouk</creatorcontrib><creatorcontrib>Hamacha, Rachida</creatorcontrib><creatorcontrib>Habib Zahmani, Hadjira</creatorcontrib><creatorcontrib>Hacini, Salih</creatorcontrib><creatorcontrib>Bengueddach, Abdelkader</creatorcontrib><creatorcontrib>Boukoussa, Bouhadjar</creatorcontrib><title>Improved Catalytic Activity of Composite Beads Calcium Alginate@MIL-101@Fe3O4 Towards Reduction Toxic Organic Dyes</title><title>Journal of polymers and the environment</title><addtitle>J Polym Environ</addtitle><description>The defiance of this study was to explore the potential of alginate/MIL-101 beads containing Fe
3
O
4
nanoparticles as a catalyst for the reduction of dyes. The Fe
3
O
4
@MIL-101 magnetic composite was obtained by the mechanical method and then encapsulated using calcium alginate (CA) as a crosslinked matrix. The Fe
3
O
4
(X)@MIL-101/CA composites beads at different content (X) of Fe
3
O
4
nanoparticles were evaluated for the catalytic reduction of methylene blue (MB) and orange G (OG). The aerogel beads have completed the MB dye reduction after 7 min with a rate constant of 0.962 min
–1
. This strong activity is assigned to the synergistic effect between Cr containing MIL-101 the Fe
3
O
4
particles and the hydrides formed on the catalyst surface. The obtained optimal conditions of MB dye reduction were used for the reduction of OG dye in simple and binary system.The best catalyst M(1)@MIL-101/CA showed a high affinity via MB dye in a binary system. Then was easily recovered by an external magnetic field and reused for 4 cycles. On the other hand, the time of the catalytic activity clearly increased in its 4th reuse in the reduction of MB dye but did not affect the efficiency of catalytic reduction.</description><subject>Aerogels</subject><subject>Alginic acid</subject><subject>Beads</subject><subject>Binary system</subject><subject>Calcium</subject><subject>Calcium alginate</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemical reduction</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dyes</subject><subject>Environmental Chemistry</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Iron oxides</subject><subject>Magnetic fields</subject><subject>Materials Science</subject><subject>Methylene blue</subject><subject>Nanoparticles</subject><subject>Polymer Sciences</subject><subject>Review</subject><subject>Synergistic effect</subject><issn>1566-2543</issn><issn>1572-8919</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kE1LAzEQhoMoWKt_wNOC52g-N5tb62q1UClIPYc0my1b9qMmWXX_vakrePMwzDA87zvMC8A1RrcYIXHnMZKEQUTwsYSA7ARMMBcEZhLL0-OcppBwRs_Bhfd7hJCMwglwy-bgug9bJLkOuh5CZZK5CdVHFYakK5O8aw6dr4JN7q0ufKRqU_VNMq93VauDnb0sVxAjPFtYumbJpvvULmKvtuijS9fGzVe0XLudbmN_GKy_BGelrr29-u1T8LZ43OTPcLV-WubzFTQUywBTLImhtNwSoUu-tdYQaU3GTVpgLWyZCikkk5ZqJBHThWFGcMNToTNOjeR0Cm5G3_jge299UPuud208qQjPWMq4QDJSZKSM67x3tlQHVzXaDQojdcxWjdmqmKv6yVaxKKKjyEe43Vn3Z_2P6hu9aHvH</recordid><startdate>20211201</startdate><enddate>20211201</enddate><creator>Hachemaoui, Mohammed</creator><creator>Mokhtar, Adel</creator><creator>Abdelkrim, Soumia</creator><creator>Ouargli-Saker, Rachida</creator><creator>Zaoui, Farouk</creator><creator>Hamacha, Rachida</creator><creator>Habib Zahmani, Hadjira</creator><creator>Hacini, Salih</creator><creator>Bengueddach, Abdelkader</creator><creator>Boukoussa, Bouhadjar</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8AO</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><orcidid>https://orcid.org/0000-0001-6008-9826</orcidid></search><sort><creationdate>20211201</creationdate><title>Improved Catalytic Activity of Composite Beads Calcium Alginate@MIL-101@Fe3O4 Towards Reduction Toxic Organic Dyes</title><author>Hachemaoui, Mohammed ; Mokhtar, Adel ; Abdelkrim, Soumia ; Ouargli-Saker, Rachida ; Zaoui, Farouk ; Hamacha, Rachida ; Habib Zahmani, Hadjira ; Hacini, Salih ; Bengueddach, Abdelkader ; Boukoussa, Bouhadjar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-6192c33fb27af5beec29ec85c6d1a7ef6797949e3a0904adc4c75c567a853c953</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aerogels</topic><topic>Alginic acid</topic><topic>Beads</topic><topic>Binary system</topic><topic>Calcium</topic><topic>Calcium alginate</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemical reduction</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dyes</topic><topic>Environmental Chemistry</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Iron oxides</topic><topic>Magnetic fields</topic><topic>Materials Science</topic><topic>Methylene blue</topic><topic>Nanoparticles</topic><topic>Polymer Sciences</topic><topic>Review</topic><topic>Synergistic effect</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hachemaoui, Mohammed</creatorcontrib><creatorcontrib>Mokhtar, Adel</creatorcontrib><creatorcontrib>Abdelkrim, Soumia</creatorcontrib><creatorcontrib>Ouargli-Saker, Rachida</creatorcontrib><creatorcontrib>Zaoui, Farouk</creatorcontrib><creatorcontrib>Hamacha, Rachida</creatorcontrib><creatorcontrib>Habib Zahmani, Hadjira</creatorcontrib><creatorcontrib>Hacini, Salih</creatorcontrib><creatorcontrib>Bengueddach, Abdelkader</creatorcontrib><creatorcontrib>Boukoussa, Bouhadjar</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><jtitle>Journal of polymers and the environment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hachemaoui, Mohammed</au><au>Mokhtar, Adel</au><au>Abdelkrim, Soumia</au><au>Ouargli-Saker, Rachida</au><au>Zaoui, Farouk</au><au>Hamacha, Rachida</au><au>Habib Zahmani, Hadjira</au><au>Hacini, Salih</au><au>Bengueddach, Abdelkader</au><au>Boukoussa, Bouhadjar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Improved Catalytic Activity of Composite Beads Calcium Alginate@MIL-101@Fe3O4 Towards Reduction Toxic Organic Dyes</atitle><jtitle>Journal of polymers and the environment</jtitle><stitle>J Polym Environ</stitle><date>2021-12-01</date><risdate>2021</risdate><volume>29</volume><issue>12</issue><spage>3813</spage><epage>3826</epage><pages>3813-3826</pages><issn>1566-2543</issn><eissn>1572-8919</eissn><abstract>The defiance of this study was to explore the potential of alginate/MIL-101 beads containing Fe
3
O
4
nanoparticles as a catalyst for the reduction of dyes. The Fe
3
O
4
@MIL-101 magnetic composite was obtained by the mechanical method and then encapsulated using calcium alginate (CA) as a crosslinked matrix. The Fe
3
O
4
(X)@MIL-101/CA composites beads at different content (X) of Fe
3
O
4
nanoparticles were evaluated for the catalytic reduction of methylene blue (MB) and orange G (OG). The aerogel beads have completed the MB dye reduction after 7 min with a rate constant of 0.962 min
–1
. This strong activity is assigned to the synergistic effect between Cr containing MIL-101 the Fe
3
O
4
particles and the hydrides formed on the catalyst surface. The obtained optimal conditions of MB dye reduction were used for the reduction of OG dye in simple and binary system.The best catalyst M(1)@MIL-101/CA showed a high affinity via MB dye in a binary system. Then was easily recovered by an external magnetic field and reused for 4 cycles. On the other hand, the time of the catalytic activity clearly increased in its 4th reuse in the reduction of MB dye but did not affect the efficiency of catalytic reduction.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10924-021-02177-4</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0001-6008-9826</orcidid></addata></record> |
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| ispartof | Journal of polymers and the environment, 2021-12, Vol.29 (12), p.3813-3826 |
| issn | 1566-2543 1572-8919 |
| language | eng |
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| source | SpringerLink Journals |
| subjects | Aerogels Alginic acid Beads Binary system Calcium Calcium alginate Catalysts Catalytic activity Chemical reduction Chemistry Chemistry and Materials Science Dyes Environmental Chemistry Environmental Engineering/Biotechnology Industrial Chemistry/Chemical Engineering Iron oxides Magnetic fields Materials Science Methylene blue Nanoparticles Polymer Sciences Review Synergistic effect |
| title | Improved Catalytic Activity of Composite Beads Calcium Alginate@MIL-101@Fe3O4 Towards Reduction Toxic Organic Dyes |
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