Thermally‐Induced Spin‐Crossover in Fe1‐xTx(pyrazine)[Fe(CN)5NO] with T=Co, Ni – Effects of Iron Atom Dilution

2D ferrous nitroprusside with the pyrazine molecule as a pillar between adjacent layers shows a thermally induced spin‐crossover behavior. This supposes that the energy gap between the high and low spin states is the order of kT in the temperature region where such a spin transition is observed. If...

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Veröffentlicht in:European journal of inorganic chemistry 2021-10, Vol.2021 (38), p.3969-3980
Hauptverfasser: Avila, Yosuan, Terrero, Ricardo, Crespo, Paula M., Díaz‐Paneque, Luis A., González, Marlene, Ávila, Manuel, Reguera, Edilso
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Sprache:eng
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