Bimetallic oriented catalytic fast pyrolysis of lignin research based on PY-GC/MS
In this work, catalytic pyrolysis of alkaline lignin over mono- (Fe-Al 2 O 3 -SiO 2 and Mo-Al 2 O 3 -SiO 2 ) and due-metal (Fe-Mo-Al 2 O 3 -SiO 2 ) was studied. All experiments, with or without catalyst, were carried out under different pyrolysis temperatures (300–700 °C) and time (0.1, 0.2, and 0.5...
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| Veröffentlicht in: | Biomass conversion and biorefinery 2020-12, Vol.10 (4), p.1315-1325 |
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| container_title | Biomass conversion and biorefinery |
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| creator | Chen, Fuxin Yan, Beibei Liu, Na Zhang, Junxing Zhu, Junfeng Zhang, Huikuan Gong, Pin Zhao, Weiqin Zhou, Anning |
| description | In this work, catalytic pyrolysis of alkaline lignin over mono- (Fe-Al
2
O
3
-SiO
2
and Mo-Al
2
O
3
-SiO
2
) and due-metal (Fe-Mo-Al
2
O
3
-SiO
2
) was studied. All experiments, with or without catalyst, were carried out under different pyrolysis temperatures (300–700 °C) and time (0.1, 0.2, and 0.5 min) using pyrolysis gas chromatography-mass spectrometry (Py-GC/MS). Verification of the MS data with principal component analysis (PCA) revealed that the co-operation effect of bimetallic is obvious. Due-metal catalytic pyrolysis treatments clearly differ from the non-catalytic treatment of lignin, while mono-metal catalyst (both Fe and Mo) had a little effect on product distribution. However, at lower pyrolysis temperature (300 and 400 °C), Fe-Mo-Al
2
O
3
-SiO
2
also has good catalytic activity compared with mono-catalysts. Loading plots showed several pyrolysis products with great differences. Which compounds undergo more thermal decomposition reactions, for example, 2,3-dihydrobenzofuran, 2-methoxy-phenol, and 2,6-dimethoxy-phenol, were influenced by due catalyst greatly. Based on the results, Py-GC/MS combined with PCA proved to be a promising method for testing the behavior of different catalysts. |
| doi_str_mv | 10.1007/s13399-019-00464-8 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2583988441</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2583988441</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-5e7aeb5dcec7fdff73201ef79e40a339e24393a02bc9e16f90fe5f31699ab6f63</originalsourceid><addsrcrecordid>eNp9kDFPwzAQhS0EElXpH2CyxBx6thMnHqGCggQCBAxMluOei6s0KXY65N9jCIKN4XSnp_fd6R4hpwzOGUA5j0wIpTJgqSCXeVYdkAlnCjJZcXH4O7PimMxi3AAAF6WoBEzI06XfYm-axlvaBY9tjytqTVKGPknOxJ7uhtA1Q_SRdo42ft36lgaMaIJ9p7WJieha-viWLRfz--cTcuRME3H206fk9frqZXGT3T0sbxcXd5kVheyzAkuDdbGyaEu3cq4UHBi6UmEOJv2DPBdKGOC1VcikU-CwcIJJpUwtnRRTcjbu3YXuY4-x15tuH9p0UvOiEqqq8pwlFx9dNnQxBnR6F_zWhEEz0F_p6TE9ndLT3-npKkFihGIyt2sMf6v_oT4BrV1yNA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2583988441</pqid></control><display><type>article</type><title>Bimetallic oriented catalytic fast pyrolysis of lignin research based on PY-GC/MS</title><source>Springer Nature - Complete Springer Journals</source><creator>Chen, Fuxin ; Yan, Beibei ; Liu, Na ; Zhang, Junxing ; Zhu, Junfeng ; Zhang, Huikuan ; Gong, Pin ; Zhao, Weiqin ; Zhou, Anning</creator><creatorcontrib>Chen, Fuxin ; Yan, Beibei ; Liu, Na ; Zhang, Junxing ; Zhu, Junfeng ; Zhang, Huikuan ; Gong, Pin ; Zhao, Weiqin ; Zhou, Anning</creatorcontrib><description>In this work, catalytic pyrolysis of alkaline lignin over mono- (Fe-Al
2
O
3
-SiO
2
and Mo-Al
2
O
3
-SiO
2
) and due-metal (Fe-Mo-Al
2
O
3
-SiO
2
) was studied. All experiments, with or without catalyst, were carried out under different pyrolysis temperatures (300–700 °C) and time (0.1, 0.2, and 0.5 min) using pyrolysis gas chromatography-mass spectrometry (Py-GC/MS). Verification of the MS data with principal component analysis (PCA) revealed that the co-operation effect of bimetallic is obvious. Due-metal catalytic pyrolysis treatments clearly differ from the non-catalytic treatment of lignin, while mono-metal catalyst (both Fe and Mo) had a little effect on product distribution. However, at lower pyrolysis temperature (300 and 400 °C), Fe-Mo-Al
2
O
3
-SiO
2
also has good catalytic activity compared with mono-catalysts. Loading plots showed several pyrolysis products with great differences. Which compounds undergo more thermal decomposition reactions, for example, 2,3-dihydrobenzofuran, 2-methoxy-phenol, and 2,6-dimethoxy-phenol, were influenced by due catalyst greatly. Based on the results, Py-GC/MS combined with PCA proved to be a promising method for testing the behavior of different catalysts.</description><identifier>ISSN: 2190-6815</identifier><identifier>EISSN: 2190-6823</identifier><identifier>DOI: 10.1007/s13399-019-00464-8</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aluminum oxide ; Bimetals ; Biotechnology ; Catalysts ; Catalytic activity ; Decomposition reactions ; Energy ; Gas chromatography ; Iron ; Lignin ; Mass spectrometry ; Molybdenum ; Phenols ; Principal components analysis ; Pyrolysis ; Renewable and Green Energy ; Review Article ; Silicon dioxide ; Thermal decomposition</subject><ispartof>Biomass conversion and biorefinery, 2020-12, Vol.10 (4), p.1315-1325</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2019</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2019.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-5e7aeb5dcec7fdff73201ef79e40a339e24393a02bc9e16f90fe5f31699ab6f63</citedby><cites>FETCH-LOGICAL-c356t-5e7aeb5dcec7fdff73201ef79e40a339e24393a02bc9e16f90fe5f31699ab6f63</cites><orcidid>0000-0002-5384-7825</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13399-019-00464-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13399-019-00464-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Chen, Fuxin</creatorcontrib><creatorcontrib>Yan, Beibei</creatorcontrib><creatorcontrib>Liu, Na</creatorcontrib><creatorcontrib>Zhang, Junxing</creatorcontrib><creatorcontrib>Zhu, Junfeng</creatorcontrib><creatorcontrib>Zhang, Huikuan</creatorcontrib><creatorcontrib>Gong, Pin</creatorcontrib><creatorcontrib>Zhao, Weiqin</creatorcontrib><creatorcontrib>Zhou, Anning</creatorcontrib><title>Bimetallic oriented catalytic fast pyrolysis of lignin research based on PY-GC/MS</title><title>Biomass conversion and biorefinery</title><addtitle>Biomass Conv. Bioref</addtitle><description>In this work, catalytic pyrolysis of alkaline lignin over mono- (Fe-Al
2
O
3
-SiO
2
and Mo-Al
2
O
3
-SiO
2
) and due-metal (Fe-Mo-Al
2
O
3
-SiO
2
) was studied. All experiments, with or without catalyst, were carried out under different pyrolysis temperatures (300–700 °C) and time (0.1, 0.2, and 0.5 min) using pyrolysis gas chromatography-mass spectrometry (Py-GC/MS). Verification of the MS data with principal component analysis (PCA) revealed that the co-operation effect of bimetallic is obvious. Due-metal catalytic pyrolysis treatments clearly differ from the non-catalytic treatment of lignin, while mono-metal catalyst (both Fe and Mo) had a little effect on product distribution. However, at lower pyrolysis temperature (300 and 400 °C), Fe-Mo-Al
2
O
3
-SiO
2
also has good catalytic activity compared with mono-catalysts. Loading plots showed several pyrolysis products with great differences. Which compounds undergo more thermal decomposition reactions, for example, 2,3-dihydrobenzofuran, 2-methoxy-phenol, and 2,6-dimethoxy-phenol, were influenced by due catalyst greatly. Based on the results, Py-GC/MS combined with PCA proved to be a promising method for testing the behavior of different catalysts.</description><subject>Aluminum oxide</subject><subject>Bimetals</subject><subject>Biotechnology</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Decomposition reactions</subject><subject>Energy</subject><subject>Gas chromatography</subject><subject>Iron</subject><subject>Lignin</subject><subject>Mass spectrometry</subject><subject>Molybdenum</subject><subject>Phenols</subject><subject>Principal components analysis</subject><subject>Pyrolysis</subject><subject>Renewable and Green Energy</subject><subject>Review Article</subject><subject>Silicon dioxide</subject><subject>Thermal decomposition</subject><issn>2190-6815</issn><issn>2190-6823</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kDFPwzAQhS0EElXpH2CyxBx6thMnHqGCggQCBAxMluOei6s0KXY65N9jCIKN4XSnp_fd6R4hpwzOGUA5j0wIpTJgqSCXeVYdkAlnCjJZcXH4O7PimMxi3AAAF6WoBEzI06XfYm-axlvaBY9tjytqTVKGPknOxJ7uhtA1Q_SRdo42ft36lgaMaIJ9p7WJieha-viWLRfz--cTcuRME3H206fk9frqZXGT3T0sbxcXd5kVheyzAkuDdbGyaEu3cq4UHBi6UmEOJv2DPBdKGOC1VcikU-CwcIJJpUwtnRRTcjbu3YXuY4-x15tuH9p0UvOiEqqq8pwlFx9dNnQxBnR6F_zWhEEz0F_p6TE9ndLT3-npKkFihGIyt2sMf6v_oT4BrV1yNA</recordid><startdate>20201201</startdate><enddate>20201201</enddate><creator>Chen, Fuxin</creator><creator>Yan, Beibei</creator><creator>Liu, Na</creator><creator>Zhang, Junxing</creator><creator>Zhu, Junfeng</creator><creator>Zhang, Huikuan</creator><creator>Gong, Pin</creator><creator>Zhao, Weiqin</creator><creator>Zhou, Anning</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-5384-7825</orcidid></search><sort><creationdate>20201201</creationdate><title>Bimetallic oriented catalytic fast pyrolysis of lignin research based on PY-GC/MS</title><author>Chen, Fuxin ; Yan, Beibei ; Liu, Na ; Zhang, Junxing ; Zhu, Junfeng ; Zhang, Huikuan ; Gong, Pin ; Zhao, Weiqin ; Zhou, Anning</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-5e7aeb5dcec7fdff73201ef79e40a339e24393a02bc9e16f90fe5f31699ab6f63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aluminum oxide</topic><topic>Bimetals</topic><topic>Biotechnology</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Decomposition reactions</topic><topic>Energy</topic><topic>Gas chromatography</topic><topic>Iron</topic><topic>Lignin</topic><topic>Mass spectrometry</topic><topic>Molybdenum</topic><topic>Phenols</topic><topic>Principal components analysis</topic><topic>Pyrolysis</topic><topic>Renewable and Green Energy</topic><topic>Review Article</topic><topic>Silicon dioxide</topic><topic>Thermal decomposition</topic><toplevel>online_resources</toplevel><creatorcontrib>Chen, Fuxin</creatorcontrib><creatorcontrib>Yan, Beibei</creatorcontrib><creatorcontrib>Liu, Na</creatorcontrib><creatorcontrib>Zhang, Junxing</creatorcontrib><creatorcontrib>Zhu, Junfeng</creatorcontrib><creatorcontrib>Zhang, Huikuan</creatorcontrib><creatorcontrib>Gong, Pin</creatorcontrib><creatorcontrib>Zhao, Weiqin</creatorcontrib><creatorcontrib>Zhou, Anning</creatorcontrib><collection>CrossRef</collection><jtitle>Biomass conversion and biorefinery</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Fuxin</au><au>Yan, Beibei</au><au>Liu, Na</au><au>Zhang, Junxing</au><au>Zhu, Junfeng</au><au>Zhang, Huikuan</au><au>Gong, Pin</au><au>Zhao, Weiqin</au><au>Zhou, Anning</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bimetallic oriented catalytic fast pyrolysis of lignin research based on PY-GC/MS</atitle><jtitle>Biomass conversion and biorefinery</jtitle><stitle>Biomass Conv. Bioref</stitle><date>2020-12-01</date><risdate>2020</risdate><volume>10</volume><issue>4</issue><spage>1315</spage><epage>1325</epage><pages>1315-1325</pages><issn>2190-6815</issn><eissn>2190-6823</eissn><abstract>In this work, catalytic pyrolysis of alkaline lignin over mono- (Fe-Al
2
O
3
-SiO
2
and Mo-Al
2
O
3
-SiO
2
) and due-metal (Fe-Mo-Al
2
O
3
-SiO
2
) was studied. All experiments, with or without catalyst, were carried out under different pyrolysis temperatures (300–700 °C) and time (0.1, 0.2, and 0.5 min) using pyrolysis gas chromatography-mass spectrometry (Py-GC/MS). Verification of the MS data with principal component analysis (PCA) revealed that the co-operation effect of bimetallic is obvious. Due-metal catalytic pyrolysis treatments clearly differ from the non-catalytic treatment of lignin, while mono-metal catalyst (both Fe and Mo) had a little effect on product distribution. However, at lower pyrolysis temperature (300 and 400 °C), Fe-Mo-Al
2
O
3
-SiO
2
also has good catalytic activity compared with mono-catalysts. Loading plots showed several pyrolysis products with great differences. Which compounds undergo more thermal decomposition reactions, for example, 2,3-dihydrobenzofuran, 2-methoxy-phenol, and 2,6-dimethoxy-phenol, were influenced by due catalyst greatly. Based on the results, Py-GC/MS combined with PCA proved to be a promising method for testing the behavior of different catalysts.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13399-019-00464-8</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-5384-7825</orcidid></addata></record> |
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| subjects | Aluminum oxide Bimetals Biotechnology Catalysts Catalytic activity Decomposition reactions Energy Gas chromatography Iron Lignin Mass spectrometry Molybdenum Phenols Principal components analysis Pyrolysis Renewable and Green Energy Review Article Silicon dioxide Thermal decomposition |
| title | Bimetallic oriented catalytic fast pyrolysis of lignin research based on PY-GC/MS |
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