Cellulose Schiff base-supported Pd(II): An efficient heterogeneous catalyst for Suzuki Miyaura cross-coupling

Cellulose Schiff base-supported Pd(II): An efficient heterogeneous catalyst for Suzuki Miyaura cross-coupling

Cellulose-supported Schiff base Pd(II) complex [(Cell-Sc-Pd(II))] has been designed and synthesized by multistep approach. (Cell-Sc-Pd(II)) was characterized by techniques, viz . FT-IR, XRD, XPS, EDS, FE-SEM and TGA. Catalytic activity of (Cell-Sc-Pd(II)) is explored for Suzuki Miyaura cross-couplin...

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Veröffentlicht in:Research on chemical intermediates 2021-11, Vol.47 (11), p.4457-4476
Hauptverfasser: Pharande, P. S., Rashinkar, G. S., Pore, D. M.
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Catalysts
Catalytic activity
Cellulose
Chemistry
Chemistry and Materials Science
Cross coupling
Halides
Imines
Inorganic Chemistry
Physical Chemistry
X ray photoelectron spectroscopy
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container_title Research on chemical intermediates
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creator Pharande, P. S.
Rashinkar, G. S.
Pore, D. M.
description Cellulose-supported Schiff base Pd(II) complex [(Cell-Sc-Pd(II))] has been designed and synthesized by multistep approach. (Cell-Sc-Pd(II)) was characterized by techniques, viz . FT-IR, XRD, XPS, EDS, FE-SEM and TGA. Catalytic activity of (Cell-Sc-Pd(II)) is explored for Suzuki Miyaura cross-coupling of phenyl boronic acid and aryl halides. Special features of present method are high TONs and TOFs, low catalyst loading (0.0016 mol %), reusability of the catalyst at least for five times and synthesis of novel biphenyl derivatives of xanthenes. Graphic abstract
doi_str_mv 10.1007/s11164-021-04528-1
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subjects Catalysis
Catalysts
Catalytic activity
Cellulose
Chemistry
Chemistry and Materials Science
Cross coupling
Halides
Imines
Inorganic Chemistry
Physical Chemistry
X ray photoelectron spectroscopy
title Cellulose Schiff base-supported Pd(II): An efficient heterogeneous catalyst for Suzuki Miyaura cross-coupling
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