Cellulose Schiff base-supported Pd(II): An efficient heterogeneous catalyst for Suzuki Miyaura cross-coupling
Cellulose-supported Schiff base Pd(II) complex [(Cell-Sc-Pd(II))] has been designed and synthesized by multistep approach. (Cell-Sc-Pd(II)) was characterized by techniques, viz . FT-IR, XRD, XPS, EDS, FE-SEM and TGA. Catalytic activity of (Cell-Sc-Pd(II)) is explored for Suzuki Miyaura cross-couplin...
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Veröffentlicht in: | Research on chemical intermediates 2021-11, Vol.47 (11), p.4457-4476 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | Cellulose-supported Schiff base Pd(II) complex [(Cell-Sc-Pd(II))] has been designed and synthesized by multistep approach. (Cell-Sc-Pd(II)) was characterized by techniques, viz
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FT-IR, XRD, XPS, EDS, FE-SEM and TGA. Catalytic activity of (Cell-Sc-Pd(II)) is explored for Suzuki Miyaura cross-coupling of phenyl boronic acid and aryl halides. Special features of present method are high TONs and TOFs, low catalyst loading (0.0016 mol %), reusability of the catalyst at least for five times and synthesis of novel biphenyl derivatives of xanthenes.
Graphic abstract |
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ISSN: | 0922-6168 1568-5675 |
DOI: | 10.1007/s11164-021-04528-1 |