Trimetallic coordination cage formation for nitrate encapsulation: transformation of kinetic products into thermodynamic products
A procedure for the formation of a nitrate-encapsulating tripalladium( ii ) cage via self-assembly of Pd(NO 3 ) 2 with 1,3-bis(dimethyl(pyridin-4-yl)silyl)propane (L) was developed. The self-assembly reaction initially produces spiro-type macrocycles, PdL 2 , and finally results in transformation in...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2021-10, Vol.5 (4), p.1432-14324 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Lim, Sang Woo Moon, Heehun Kim, Dongwon Jung, Ok-Sang |
| description | A procedure for the formation of a nitrate-encapsulating tripalladium(
ii
) cage
via
self-assembly of Pd(NO
3
)
2
with 1,3-bis(dimethyl(pyridin-4-yl)silyl)propane (L) was developed. The self-assembly reaction initially produces spiro-type macrocycles, PdL
2
, and finally results in transformation into a nitrate-encapsulated cage, [(NO
3
)@Pd
3
L
6
], in the mother liquor. The reaction of PdX
2
(X
−
= BF
4
−
, ClO
4
−
, PF
6
−
, and CF
3
SO
3
−
instead of NO
3
−
) with L gives rise to a spiro species, PdL
2
, as the final product, and anion exchange of the spiro products, [PdL
2
](X)
2
, with NO
3
−
produces the tripalladium cage [(NO
3
)@Pd
3
L
6
].
The self-assembly of Pd(NO
3
)
2
with 1,3-bis(dimethyl(pyridin-4-yl)silyl)propane (L) initially produces the nitrate-encapsulated cage [(NO
3
)@Pd
3
L
6
]
via
the spiro-type macrocyclic kinetic product. |
| doi_str_mv | 10.1039/d1dt02691g |
| format | Article |
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ii
) cage
via
self-assembly of Pd(NO
3
)
2
with 1,3-bis(dimethyl(pyridin-4-yl)silyl)propane (L) was developed. The self-assembly reaction initially produces spiro-type macrocycles, PdL
2
, and finally results in transformation into a nitrate-encapsulated cage, [(NO
3
)@Pd
3
L
6
], in the mother liquor. The reaction of PdX
2
(X
−
= BF
4
−
, ClO
4
−
, PF
6
−
, and CF
3
SO
3
−
instead of NO
3
−
) with L gives rise to a spiro species, PdL
2
, as the final product, and anion exchange of the spiro products, [PdL
2
](X)
2
, with NO
3
−
produces the tripalladium cage [(NO
3
)@Pd
3
L
6
].
The self-assembly of Pd(NO
3
)
2
with 1,3-bis(dimethyl(pyridin-4-yl)silyl)propane (L) initially produces the nitrate-encapsulated cage [(NO
3
)@Pd
3
L
6
]
via
the spiro-type macrocyclic kinetic product.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d1dt02691g</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Anion exchanging ; Cages ; Encapsulation ; Nitrates ; Self-assembly</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2021-10, Vol.5 (4), p.1432-14324</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c314t-db5ab4d56ea6ed66f3b0760df520d07f3180d45fe2dc06a0fe8b83b9da722b463</citedby><cites>FETCH-LOGICAL-c314t-db5ab4d56ea6ed66f3b0760df520d07f3180d45fe2dc06a0fe8b83b9da722b463</cites><orcidid>0000-0002-7218-457X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Lim, Sang Woo</creatorcontrib><creatorcontrib>Moon, Heehun</creatorcontrib><creatorcontrib>Kim, Dongwon</creatorcontrib><creatorcontrib>Jung, Ok-Sang</creatorcontrib><title>Trimetallic coordination cage formation for nitrate encapsulation: transformation of kinetic products into thermodynamic products</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>A procedure for the formation of a nitrate-encapsulating tripalladium(
ii
) cage
via
self-assembly of Pd(NO
3
)
2
with 1,3-bis(dimethyl(pyridin-4-yl)silyl)propane (L) was developed. The self-assembly reaction initially produces spiro-type macrocycles, PdL
2
, and finally results in transformation into a nitrate-encapsulated cage, [(NO
3
)@Pd
3
L
6
], in the mother liquor. The reaction of PdX
2
(X
−
= BF
4
−
, ClO
4
−
, PF
6
−
, and CF
3
SO
3
−
instead of NO
3
−
) with L gives rise to a spiro species, PdL
2
, as the final product, and anion exchange of the spiro products, [PdL
2
](X)
2
, with NO
3
−
produces the tripalladium cage [(NO
3
)@Pd
3
L
6
].
The self-assembly of Pd(NO
3
)
2
with 1,3-bis(dimethyl(pyridin-4-yl)silyl)propane (L) initially produces the nitrate-encapsulated cage [(NO
3
)@Pd
3
L
6
]
via
the spiro-type macrocyclic kinetic product.</description><subject>Anion exchanging</subject><subject>Cages</subject><subject>Encapsulation</subject><subject>Nitrates</subject><subject>Self-assembly</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpd0U1LwzAYB_AiCs7pxbsQ8CJCNS9N2nqTTacw8DLPJc3LzGyTmaSHHf3mxk2ceMqTPD-ehPyz7BzBGwRJfSuRjBCzGi0PshEqyjKvMSkOf2vMjrOTEFYQYgwpHmWfC296FXnXGQGEc14ay6NxFgi-VEA73--2qQLWRM-jAsoKvg5Dt-3cgXRow146Dd6NVTENXHsnBxEDMDY6EN-U753cWN7_6Z1mR5p3QZ39rOPs9fFhMXnK5y-z58n9PBcEFTGXLeVtISlTnCnJmCYtLBmUmmIoYakJqqAsqFZYCsg41KpqK9LWkpcYtwUj4-xqNzdd_DGoEJveBKG6jlvlhtBgWjJGUc3qRC__0ZUbvE2vS6rCdcUQhUld75TwLgSvdLNOf8n9pkGw-U6jmaLpYpvGLOGLHfZB_Lp9WuQLiEiKyg</recordid><startdate>20211019</startdate><enddate>20211019</enddate><creator>Lim, Sang Woo</creator><creator>Moon, Heehun</creator><creator>Kim, Dongwon</creator><creator>Jung, Ok-Sang</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-7218-457X</orcidid></search><sort><creationdate>20211019</creationdate><title>Trimetallic coordination cage formation for nitrate encapsulation: transformation of kinetic products into thermodynamic products</title><author>Lim, Sang Woo ; Moon, Heehun ; Kim, Dongwon ; Jung, Ok-Sang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c314t-db5ab4d56ea6ed66f3b0760df520d07f3180d45fe2dc06a0fe8b83b9da722b463</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Anion exchanging</topic><topic>Cages</topic><topic>Encapsulation</topic><topic>Nitrates</topic><topic>Self-assembly</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lim, Sang Woo</creatorcontrib><creatorcontrib>Moon, Heehun</creatorcontrib><creatorcontrib>Kim, Dongwon</creatorcontrib><creatorcontrib>Jung, Ok-Sang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lim, Sang Woo</au><au>Moon, Heehun</au><au>Kim, Dongwon</au><au>Jung, Ok-Sang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Trimetallic coordination cage formation for nitrate encapsulation: transformation of kinetic products into thermodynamic products</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2021-10-19</date><risdate>2021</risdate><volume>5</volume><issue>4</issue><spage>1432</spage><epage>14324</epage><pages>1432-14324</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A procedure for the formation of a nitrate-encapsulating tripalladium(
ii
) cage
via
self-assembly of Pd(NO
3
)
2
with 1,3-bis(dimethyl(pyridin-4-yl)silyl)propane (L) was developed. The self-assembly reaction initially produces spiro-type macrocycles, PdL
2
, and finally results in transformation into a nitrate-encapsulated cage, [(NO
3
)@Pd
3
L
6
], in the mother liquor. The reaction of PdX
2
(X
−
= BF
4
−
, ClO
4
−
, PF
6
−
, and CF
3
SO
3
−
instead of NO
3
−
) with L gives rise to a spiro species, PdL
2
, as the final product, and anion exchange of the spiro products, [PdL
2
](X)
2
, with NO
3
−
produces the tripalladium cage [(NO
3
)@Pd
3
L
6
].
The self-assembly of Pd(NO
3
)
2
with 1,3-bis(dimethyl(pyridin-4-yl)silyl)propane (L) initially produces the nitrate-encapsulated cage [(NO
3
)@Pd
3
L
6
]
via
the spiro-type macrocyclic kinetic product.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1dt02691g</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-7218-457X</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2021-10, Vol.5 (4), p.1432-14324 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_journals_2582986150 |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Anion exchanging Cages Encapsulation Nitrates Self-assembly |
| title | Trimetallic coordination cage formation for nitrate encapsulation: transformation of kinetic products into thermodynamic products |
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