Layer structural MoO2/carbon hybrid composites as anode materials for lithium-ion batteries
Layer structural MoO 2 /carbon hybrid composites (LMC) were prepared via simply two-step method by using organic–inorganic MoO 3 /(dodecyl amine, DDA) as precursor followed with annealing at 600 °C under reducing atmosphere. As an anode material, the hybrid composites deliver a good capacity of 675...
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| Veröffentlicht in: | Ionics 2021-11, Vol.27 (11), p.4713-4720 |
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| container_title | Ionics |
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| creator | Wu, Di Ge, Fei Xing, Shijun Ji, Wenxu Peng, Luming |
| description | Layer structural MoO
2
/carbon hybrid composites (LMC) were prepared via simply two-step method by using organic–inorganic MoO
3
/(dodecyl amine, DDA) as precursor followed with annealing at 600 °C under reducing atmosphere. As an anode material, the hybrid composites deliver a good capacity of 675 mAh/g after 60 cycles and show a much better performance in cycling and rate capability than that of bare MoO
2
. The significant improvement may be partially ascribed to the layered structure of the composites, which is beneficial for diffusion of Li
+
by decreasing the diffusion path lengths. In addition, combining carbon with MoO
2
improves the electronic conductivity of composites and maintains the mechanical integrity of electrode, thus decreases the mechanical degradation and pulverization. The presented work provides a strategy to design and prepare electrode carbon-containing electrode materials for better energy storage properties. |
| doi_str_mv | 10.1007/s11581-021-04238-z |
| format | Article |
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2
/carbon hybrid composites (LMC) were prepared via simply two-step method by using organic–inorganic MoO
3
/(dodecyl amine, DDA) as precursor followed with annealing at 600 °C under reducing atmosphere. As an anode material, the hybrid composites deliver a good capacity of 675 mAh/g after 60 cycles and show a much better performance in cycling and rate capability than that of bare MoO
2
. The significant improvement may be partially ascribed to the layered structure of the composites, which is beneficial for diffusion of Li
+
by decreasing the diffusion path lengths. In addition, combining carbon with MoO
2
improves the electronic conductivity of composites and maintains the mechanical integrity of electrode, thus decreases the mechanical degradation and pulverization. The presented work provides a strategy to design and prepare electrode carbon-containing electrode materials for better energy storage properties.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-021-04238-z</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Anodes ; Carbon ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Diffusion layers ; Electrochemistry ; Electrode materials ; Electrodes ; Energy Storage ; Hybrid composites ; Lithium ; Lithium-ion batteries ; Molybdenum oxides ; Optical and Electronic Materials ; Original Paper ; Rechargeable batteries ; Renewable and Green Energy</subject><ispartof>Ionics, 2021-11, Vol.27 (11), p.4713-4720</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-ad3b66802559a76a5f8ff3b334eef0e95ecf94bf05d2bab541a3966ad0bc6f823</citedby><cites>FETCH-LOGICAL-c319t-ad3b66802559a76a5f8ff3b334eef0e95ecf94bf05d2bab541a3966ad0bc6f823</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-021-04238-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-021-04238-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Wu, Di</creatorcontrib><creatorcontrib>Ge, Fei</creatorcontrib><creatorcontrib>Xing, Shijun</creatorcontrib><creatorcontrib>Ji, Wenxu</creatorcontrib><creatorcontrib>Peng, Luming</creatorcontrib><title>Layer structural MoO2/carbon hybrid composites as anode materials for lithium-ion batteries</title><title>Ionics</title><addtitle>Ionics</addtitle><description>Layer structural MoO
2
/carbon hybrid composites (LMC) were prepared via simply two-step method by using organic–inorganic MoO
3
/(dodecyl amine, DDA) as precursor followed with annealing at 600 °C under reducing atmosphere. As an anode material, the hybrid composites deliver a good capacity of 675 mAh/g after 60 cycles and show a much better performance in cycling and rate capability than that of bare MoO
2
. The significant improvement may be partially ascribed to the layered structure of the composites, which is beneficial for diffusion of Li
+
by decreasing the diffusion path lengths. In addition, combining carbon with MoO
2
improves the electronic conductivity of composites and maintains the mechanical integrity of electrode, thus decreases the mechanical degradation and pulverization. The presented work provides a strategy to design and prepare electrode carbon-containing electrode materials for better energy storage properties.</description><subject>Anodes</subject><subject>Carbon</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Diffusion layers</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Energy Storage</subject><subject>Hybrid composites</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Molybdenum oxides</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Rechargeable batteries</subject><subject>Renewable and Green Energy</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhYMoWKt_wFXAdWzemVlK8QWVbnTlIiQziZ3SmdQks6i_3tQR3Annchf3nHPhA-Ca4FuCsVokQkRFEKZlOGUV-joBM1JJirCS-BTMcM0VUpirc3CR0hZjKQlVM_C-MgcXYcpxbPIYzQ6-hDVdNCbaMMDNwcauhU3o9yF12SVoiobQOtib7GJndgn6EOGuy5tu7FFXQtbk48mlS3Dmi8Fd_e45eHu4f10-odX68Xl5t0INI3VGpmVWygpTIWqjpBG-8p5ZxrhzHrtauMbX3HosWmqNFZwYVktpWmwb6SvK5uBm6t3H8Dm6lPU2jHEoLzUVVRHnShUXnVxNDClF5_U-dr2JB02wPkLUE0RdIOofiPqrhNgUSsU8fLj4V_1P6htD_3bo</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Wu, Di</creator><creator>Ge, Fei</creator><creator>Xing, Shijun</creator><creator>Ji, Wenxu</creator><creator>Peng, Luming</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20211101</creationdate><title>Layer structural MoO2/carbon hybrid composites as anode materials for lithium-ion batteries</title><author>Wu, Di ; Ge, Fei ; Xing, Shijun ; Ji, Wenxu ; Peng, Luming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-ad3b66802559a76a5f8ff3b334eef0e95ecf94bf05d2bab541a3966ad0bc6f823</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Anodes</topic><topic>Carbon</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Diffusion layers</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Energy Storage</topic><topic>Hybrid composites</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Molybdenum oxides</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Rechargeable batteries</topic><topic>Renewable and Green Energy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Di</creatorcontrib><creatorcontrib>Ge, Fei</creatorcontrib><creatorcontrib>Xing, Shijun</creatorcontrib><creatorcontrib>Ji, Wenxu</creatorcontrib><creatorcontrib>Peng, Luming</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Di</au><au>Ge, Fei</au><au>Xing, Shijun</au><au>Ji, Wenxu</au><au>Peng, Luming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Layer structural MoO2/carbon hybrid composites as anode materials for lithium-ion batteries</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2021-11-01</date><risdate>2021</risdate><volume>27</volume><issue>11</issue><spage>4713</spage><epage>4720</epage><pages>4713-4720</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>Layer structural MoO
2
/carbon hybrid composites (LMC) were prepared via simply two-step method by using organic–inorganic MoO
3
/(dodecyl amine, DDA) as precursor followed with annealing at 600 °C under reducing atmosphere. As an anode material, the hybrid composites deliver a good capacity of 675 mAh/g after 60 cycles and show a much better performance in cycling and rate capability than that of bare MoO
2
. The significant improvement may be partially ascribed to the layered structure of the composites, which is beneficial for diffusion of Li
+
by decreasing the diffusion path lengths. In addition, combining carbon with MoO
2
improves the electronic conductivity of composites and maintains the mechanical integrity of electrode, thus decreases the mechanical degradation and pulverization. The presented work provides a strategy to design and prepare electrode carbon-containing electrode materials for better energy storage properties.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-021-04238-z</doi><tpages>8</tpages></addata></record> |
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| language | eng |
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| subjects | Anodes Carbon Chemistry Chemistry and Materials Science Condensed Matter Physics Diffusion layers Electrochemistry Electrode materials Electrodes Energy Storage Hybrid composites Lithium Lithium-ion batteries Molybdenum oxides Optical and Electronic Materials Original Paper Rechargeable batteries Renewable and Green Energy |
| title | Layer structural MoO2/carbon hybrid composites as anode materials for lithium-ion batteries |
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