Enhanced catalytic activity and stability of bismuth nanosheets decorated by 3-aminopropyltriethoxysilane for efficient electrochemical reduction of CO2
[Display omitted] •High quality Bi nanosheets (NS) are in-situ prepared on carbon paper by electro reduction.•3-Aminopropyltriethoxysilane (APTES)/Bi-NS highly efficient for CO2 conversion to HCOOH.•APTES/Bi-NS beneficial to formation of intermediates *OCHO to formate.•DFT calculation proves the dec...
Gespeichert in:
Veröffentlicht in: | Applied catalysis. B, Environmental Environmental, 2021-12, Vol.298, p.120602, Article 120602 |
---|---|
Hauptverfasser: | , , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | |
---|---|
container_issue | |
container_start_page | 120602 |
container_title | Applied catalysis. B, Environmental |
container_volume | 298 |
creator | Wang, Liwen Liu, Pengfei Xu, Yida Zhao, Yingxuan Xue, Nianhua Guo, Xuefeng Peng, Luming Zhu, Yan Ding, Mengning Wang, Qiang Ding, Weiping |
description | [Display omitted]
•High quality Bi nanosheets (NS) are in-situ prepared on carbon paper by electro reduction.•3-Aminopropyltriethoxysilane (APTES)/Bi-NS highly efficient for CO2 conversion to HCOOH.•APTES/Bi-NS beneficial to formation of intermediates *OCHO to formate.•DFT calculation proves the decrease in energy barrier of OCHO*to HCOOH over APTES/Bi-NS.
Herein, the effects of the introduction of 3-aminopropyltriethoxysilane (APTES) on the intrinsic properties of functionalized Bi nanosheets (Bi-NHS) electrocatalyst and the electrocatalytic performance of CO2 reduction reaction were carefully studied. As a result, high selectivities (> 90 %) to formate in significantly wide potentials of 500 mV and the energy efficiency ΦHCOOH as high as 65.8 % at –0.66 V for the cathodic half reaction can be observed. In addition, the Bi-NHS electrode shows a maximal faradic efficiency of 96.0 % at –0.96 V and a low overpotential around 340 mV, maintains well-preserved catalytic activity, giving formate yield of 8.02 g L−1, in a long term of continuous electrolysis. Based on experiment and density functional theory (DFT) calculations, CO2 reduction to formate on Bi(001)-NHS surface is more energetically favorable than that on bare Bi(001) surface and the APTES is excellent ligands as promoters for stabilized catalytic performance of metallic bismuth. |
doi_str_mv | 10.1016/j.apcatb.2021.120602 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2582221842</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0926337321007281</els_id><sourcerecordid>2582221842</sourcerecordid><originalsourceid>FETCH-LOGICAL-c334t-61fcdbe13b911833c703551b046b1b0851f049ba1123c58e7e225c8ec12ed71d3</originalsourceid><addsrcrecordid>eNp9UctqHDEQFCaBbOz8QQ4Cn2etluahvRjMYicBgy_xWUiaHkbLrLSWtMbzJ_5caxiffemmobqqq4uQ38C2wKC9OWz1yepstpxx2AJnLeMXZAOyE5WQUnwjG7bjbSVEJ36QnykdGGNccLkh7_d-1N5iTwuBnubsLNU2u1eXZ6p9T1PWxk3LFAZqXDqe80i99iGNiDnRHm2IOhcCM1NR6aPz4RTDaZ5ydJjH8DYnN2mPdAiR4jA469BnihPaHIMd8eisnmjE_lx0g1909k_8inwf9JTw12e_JM8P9__3f6vHpz__9nePlRWizlULg-0NgjA7ACmE7ZhoGjCsbk2psoGB1TujAbiwjcQOOW-sRAsc-w56cUmuV95y9MsZU1aHcI6-SCreSM45yJoXVL2ibAwpRRzUKbqjjrMCppYM1EGtGaglA7VmUNZu1zUsDl4dRpUW9-XdLhb7qg_ua4IP_hGUpw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2582221842</pqid></control><display><type>article</type><title>Enhanced catalytic activity and stability of bismuth nanosheets decorated by 3-aminopropyltriethoxysilane for efficient electrochemical reduction of CO2</title><source>Elsevier ScienceDirect Journals</source><creator>Wang, Liwen ; Liu, Pengfei ; Xu, Yida ; Zhao, Yingxuan ; Xue, Nianhua ; Guo, Xuefeng ; Peng, Luming ; Zhu, Yan ; Ding, Mengning ; Wang, Qiang ; Ding, Weiping</creator><creatorcontrib>Wang, Liwen ; Liu, Pengfei ; Xu, Yida ; Zhao, Yingxuan ; Xue, Nianhua ; Guo, Xuefeng ; Peng, Luming ; Zhu, Yan ; Ding, Mengning ; Wang, Qiang ; Ding, Weiping</creatorcontrib><description>[Display omitted]
•High quality Bi nanosheets (NS) are in-situ prepared on carbon paper by electro reduction.•3-Aminopropyltriethoxysilane (APTES)/Bi-NS highly efficient for CO2 conversion to HCOOH.•APTES/Bi-NS beneficial to formation of intermediates *OCHO to formate.•DFT calculation proves the decrease in energy barrier of OCHO*to HCOOH over APTES/Bi-NS.
Herein, the effects of the introduction of 3-aminopropyltriethoxysilane (APTES) on the intrinsic properties of functionalized Bi nanosheets (Bi-NHS) electrocatalyst and the electrocatalytic performance of CO2 reduction reaction were carefully studied. As a result, high selectivities (> 90 %) to formate in significantly wide potentials of 500 mV and the energy efficiency ΦHCOOH as high as 65.8 % at –0.66 V for the cathodic half reaction can be observed. In addition, the Bi-NHS electrode shows a maximal faradic efficiency of 96.0 % at –0.96 V and a low overpotential around 340 mV, maintains well-preserved catalytic activity, giving formate yield of 8.02 g L−1, in a long term of continuous electrolysis. Based on experiment and density functional theory (DFT) calculations, CO2 reduction to formate on Bi(001)-NHS surface is more energetically favorable than that on bare Bi(001) surface and the APTES is excellent ligands as promoters for stabilized catalytic performance of metallic bismuth.</description><identifier>ISSN: 0926-3373</identifier><identifier>EISSN: 1873-3883</identifier><identifier>DOI: 10.1016/j.apcatb.2021.120602</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>3-Aminopropyltriethoxysilane ; Aminopropyltriethoxysilane ; Bismuth ; Bismuth nanosheets ; Carbon dioxide ; Catalytic activity ; Chemical reduction ; Decoration ; Density functional theory ; Electrocatalysts ; Electrochemical CO2 reduction ; Electrochemistry ; Electrolysis ; Energy efficiency ; Formate ; Nanosheets</subject><ispartof>Applied catalysis. B, Environmental, 2021-12, Vol.298, p.120602, Article 120602</ispartof><rights>2021</rights><rights>Copyright Elsevier BV Dec 5, 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c334t-61fcdbe13b911833c703551b046b1b0851f049ba1123c58e7e225c8ec12ed71d3</citedby><cites>FETCH-LOGICAL-c334t-61fcdbe13b911833c703551b046b1b0851f049ba1123c58e7e225c8ec12ed71d3</cites><orcidid>0000-0002-8034-5740</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0926337321007281$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids></links><search><creatorcontrib>Wang, Liwen</creatorcontrib><creatorcontrib>Liu, Pengfei</creatorcontrib><creatorcontrib>Xu, Yida</creatorcontrib><creatorcontrib>Zhao, Yingxuan</creatorcontrib><creatorcontrib>Xue, Nianhua</creatorcontrib><creatorcontrib>Guo, Xuefeng</creatorcontrib><creatorcontrib>Peng, Luming</creatorcontrib><creatorcontrib>Zhu, Yan</creatorcontrib><creatorcontrib>Ding, Mengning</creatorcontrib><creatorcontrib>Wang, Qiang</creatorcontrib><creatorcontrib>Ding, Weiping</creatorcontrib><title>Enhanced catalytic activity and stability of bismuth nanosheets decorated by 3-aminopropyltriethoxysilane for efficient electrochemical reduction of CO2</title><title>Applied catalysis. B, Environmental</title><description>[Display omitted]
•High quality Bi nanosheets (NS) are in-situ prepared on carbon paper by electro reduction.•3-Aminopropyltriethoxysilane (APTES)/Bi-NS highly efficient for CO2 conversion to HCOOH.•APTES/Bi-NS beneficial to formation of intermediates *OCHO to formate.•DFT calculation proves the decrease in energy barrier of OCHO*to HCOOH over APTES/Bi-NS.
Herein, the effects of the introduction of 3-aminopropyltriethoxysilane (APTES) on the intrinsic properties of functionalized Bi nanosheets (Bi-NHS) electrocatalyst and the electrocatalytic performance of CO2 reduction reaction were carefully studied. As a result, high selectivities (> 90 %) to formate in significantly wide potentials of 500 mV and the energy efficiency ΦHCOOH as high as 65.8 % at –0.66 V for the cathodic half reaction can be observed. In addition, the Bi-NHS electrode shows a maximal faradic efficiency of 96.0 % at –0.96 V and a low overpotential around 340 mV, maintains well-preserved catalytic activity, giving formate yield of 8.02 g L−1, in a long term of continuous electrolysis. Based on experiment and density functional theory (DFT) calculations, CO2 reduction to formate on Bi(001)-NHS surface is more energetically favorable than that on bare Bi(001) surface and the APTES is excellent ligands as promoters for stabilized catalytic performance of metallic bismuth.</description><subject>3-Aminopropyltriethoxysilane</subject><subject>Aminopropyltriethoxysilane</subject><subject>Bismuth</subject><subject>Bismuth nanosheets</subject><subject>Carbon dioxide</subject><subject>Catalytic activity</subject><subject>Chemical reduction</subject><subject>Decoration</subject><subject>Density functional theory</subject><subject>Electrocatalysts</subject><subject>Electrochemical CO2 reduction</subject><subject>Electrochemistry</subject><subject>Electrolysis</subject><subject>Energy efficiency</subject><subject>Formate</subject><subject>Nanosheets</subject><issn>0926-3373</issn><issn>1873-3883</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9UctqHDEQFCaBbOz8QQ4Cn2etluahvRjMYicBgy_xWUiaHkbLrLSWtMbzJ_5caxiffemmobqqq4uQ38C2wKC9OWz1yepstpxx2AJnLeMXZAOyE5WQUnwjG7bjbSVEJ36QnykdGGNccLkh7_d-1N5iTwuBnubsLNU2u1eXZ6p9T1PWxk3LFAZqXDqe80i99iGNiDnRHm2IOhcCM1NR6aPz4RTDaZ5ydJjH8DYnN2mPdAiR4jA469BnihPaHIMd8eisnmjE_lx0g1909k_8inwf9JTw12e_JM8P9__3f6vHpz__9nePlRWizlULg-0NgjA7ACmE7ZhoGjCsbk2psoGB1TujAbiwjcQOOW-sRAsc-w56cUmuV95y9MsZU1aHcI6-SCreSM45yJoXVL2ibAwpRRzUKbqjjrMCppYM1EGtGaglA7VmUNZu1zUsDl4dRpUW9-XdLhb7qg_ua4IP_hGUpw</recordid><startdate>20211205</startdate><enddate>20211205</enddate><creator>Wang, Liwen</creator><creator>Liu, Pengfei</creator><creator>Xu, Yida</creator><creator>Zhao, Yingxuan</creator><creator>Xue, Nianhua</creator><creator>Guo, Xuefeng</creator><creator>Peng, Luming</creator><creator>Zhu, Yan</creator><creator>Ding, Mengning</creator><creator>Wang, Qiang</creator><creator>Ding, Weiping</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7ST</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0002-8034-5740</orcidid></search><sort><creationdate>20211205</creationdate><title>Enhanced catalytic activity and stability of bismuth nanosheets decorated by 3-aminopropyltriethoxysilane for efficient electrochemical reduction of CO2</title><author>Wang, Liwen ; Liu, Pengfei ; Xu, Yida ; Zhao, Yingxuan ; Xue, Nianhua ; Guo, Xuefeng ; Peng, Luming ; Zhu, Yan ; Ding, Mengning ; Wang, Qiang ; Ding, Weiping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c334t-61fcdbe13b911833c703551b046b1b0851f049ba1123c58e7e225c8ec12ed71d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>3-Aminopropyltriethoxysilane</topic><topic>Aminopropyltriethoxysilane</topic><topic>Bismuth</topic><topic>Bismuth nanosheets</topic><topic>Carbon dioxide</topic><topic>Catalytic activity</topic><topic>Chemical reduction</topic><topic>Decoration</topic><topic>Density functional theory</topic><topic>Electrocatalysts</topic><topic>Electrochemical CO2 reduction</topic><topic>Electrochemistry</topic><topic>Electrolysis</topic><topic>Energy efficiency</topic><topic>Formate</topic><topic>Nanosheets</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Liwen</creatorcontrib><creatorcontrib>Liu, Pengfei</creatorcontrib><creatorcontrib>Xu, Yida</creatorcontrib><creatorcontrib>Zhao, Yingxuan</creatorcontrib><creatorcontrib>Xue, Nianhua</creatorcontrib><creatorcontrib>Guo, Xuefeng</creatorcontrib><creatorcontrib>Peng, Luming</creatorcontrib><creatorcontrib>Zhu, Yan</creatorcontrib><creatorcontrib>Ding, Mengning</creatorcontrib><creatorcontrib>Wang, Qiang</creatorcontrib><creatorcontrib>Ding, Weiping</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Applied catalysis. B, Environmental</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Liwen</au><au>Liu, Pengfei</au><au>Xu, Yida</au><au>Zhao, Yingxuan</au><au>Xue, Nianhua</au><au>Guo, Xuefeng</au><au>Peng, Luming</au><au>Zhu, Yan</au><au>Ding, Mengning</au><au>Wang, Qiang</au><au>Ding, Weiping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced catalytic activity and stability of bismuth nanosheets decorated by 3-aminopropyltriethoxysilane for efficient electrochemical reduction of CO2</atitle><jtitle>Applied catalysis. B, Environmental</jtitle><date>2021-12-05</date><risdate>2021</risdate><volume>298</volume><spage>120602</spage><pages>120602-</pages><artnum>120602</artnum><issn>0926-3373</issn><eissn>1873-3883</eissn><abstract>[Display omitted]
•High quality Bi nanosheets (NS) are in-situ prepared on carbon paper by electro reduction.•3-Aminopropyltriethoxysilane (APTES)/Bi-NS highly efficient for CO2 conversion to HCOOH.•APTES/Bi-NS beneficial to formation of intermediates *OCHO to formate.•DFT calculation proves the decrease in energy barrier of OCHO*to HCOOH over APTES/Bi-NS.
Herein, the effects of the introduction of 3-aminopropyltriethoxysilane (APTES) on the intrinsic properties of functionalized Bi nanosheets (Bi-NHS) electrocatalyst and the electrocatalytic performance of CO2 reduction reaction were carefully studied. As a result, high selectivities (> 90 %) to formate in significantly wide potentials of 500 mV and the energy efficiency ΦHCOOH as high as 65.8 % at –0.66 V for the cathodic half reaction can be observed. In addition, the Bi-NHS electrode shows a maximal faradic efficiency of 96.0 % at –0.96 V and a low overpotential around 340 mV, maintains well-preserved catalytic activity, giving formate yield of 8.02 g L−1, in a long term of continuous electrolysis. Based on experiment and density functional theory (DFT) calculations, CO2 reduction to formate on Bi(001)-NHS surface is more energetically favorable than that on bare Bi(001) surface and the APTES is excellent ligands as promoters for stabilized catalytic performance of metallic bismuth.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.apcatb.2021.120602</doi><orcidid>https://orcid.org/0000-0002-8034-5740</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0926-3373 |
ispartof | Applied catalysis. B, Environmental, 2021-12, Vol.298, p.120602, Article 120602 |
issn | 0926-3373 1873-3883 |
language | eng |
recordid | cdi_proquest_journals_2582221842 |
source | Elsevier ScienceDirect Journals |
subjects | 3-Aminopropyltriethoxysilane Aminopropyltriethoxysilane Bismuth Bismuth nanosheets Carbon dioxide Catalytic activity Chemical reduction Decoration Density functional theory Electrocatalysts Electrochemical CO2 reduction Electrochemistry Electrolysis Energy efficiency Formate Nanosheets |
title | Enhanced catalytic activity and stability of bismuth nanosheets decorated by 3-aminopropyltriethoxysilane for efficient electrochemical reduction of CO2 |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-25T00%3A58%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Enhanced%20catalytic%20activity%20and%20stability%20of%20bismuth%20nanosheets%20decorated%20by%203-aminopropyltriethoxysilane%20for%20efficient%20electrochemical%20reduction%20of%20CO2&rft.jtitle=Applied%20catalysis.%20B,%20Environmental&rft.au=Wang,%20Liwen&rft.date=2021-12-05&rft.volume=298&rft.spage=120602&rft.pages=120602-&rft.artnum=120602&rft.issn=0926-3373&rft.eissn=1873-3883&rft_id=info:doi/10.1016/j.apcatb.2021.120602&rft_dat=%3Cproquest_cross%3E2582221842%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2582221842&rft_id=info:pmid/&rft_els_id=S0926337321007281&rfr_iscdi=true |