Novel zinc-polymer complex with antioxidant activity for industrial lubricating oil
[Display omitted] •Innovated zinc complex polymer as antioxidant for lube oil.•Fully characterization of the prepared zinc complex polymer using FTIR, SEM, XRD, PSD and BET have been carried out.•Measuring the oxidation stability for the prepared zinc complex polymer.•Certain properties were determi...
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| Veröffentlicht in: | Fuel (Guildford) 2021-12, Vol.305, p.121536, Article 121536 |
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| container_title | Fuel (Guildford) |
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| creator | Salah, Hesham Elkatory, Marwa R. Abdel Fattah, Marwa |
| description | [Display omitted]
•Innovated zinc complex polymer as antioxidant for lube oil.•Fully characterization of the prepared zinc complex polymer using FTIR, SEM, XRD, PSD and BET have been carried out.•Measuring the oxidation stability for the prepared zinc complex polymer.•Certain properties were determined density, total amount of acid, viscosity and carbon residue.•Zinc complex polymer, is effective as a lube oil additive act as antioxidant.
The development of lubricants requires antioxidants, which enhance their efficiency by minimizing waste products derived from oxidation processes. The present study aimed to synthesize (Zn-Complex) Zinc (N-Salicylidene Poly Methyl Acrylic Acid Hydrazide). These obtained polymeric derivatives were characterized by FTIR, XRD, SEM, BET and PSD. The antioxidant behavior was investigated by density, total amount of acid, viscosity and carbon residue. This investigation successfully managed to prepared new additive to the lubricant that does not contain Sulphur and Phosphorus with better lubricant antioxidant properties also has greater efficiency than traditional antioxidant (p-Cresol). This new synthetic antioxidant could be used by industrialists to replace the multipurpose lubricant additive, ZDDP and ZDDC which contain Sulphur and Phosphorus that produces and deposit ashes in the car exhaust pipe. |
| doi_str_mv | 10.1016/j.fuel.2021.121536 |
| format | Article |
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•Innovated zinc complex polymer as antioxidant for lube oil.•Fully characterization of the prepared zinc complex polymer using FTIR, SEM, XRD, PSD and BET have been carried out.•Measuring the oxidation stability for the prepared zinc complex polymer.•Certain properties were determined density, total amount of acid, viscosity and carbon residue.•Zinc complex polymer, is effective as a lube oil additive act as antioxidant.
The development of lubricants requires antioxidants, which enhance their efficiency by minimizing waste products derived from oxidation processes. The present study aimed to synthesize (Zn-Complex) Zinc (N-Salicylidene Poly Methyl Acrylic Acid Hydrazide). These obtained polymeric derivatives were characterized by FTIR, XRD, SEM, BET and PSD. The antioxidant behavior was investigated by density, total amount of acid, viscosity and carbon residue. This investigation successfully managed to prepared new additive to the lubricant that does not contain Sulphur and Phosphorus with better lubricant antioxidant properties also has greater efficiency than traditional antioxidant (p-Cresol). This new synthetic antioxidant could be used by industrialists to replace the multipurpose lubricant additive, ZDDP and ZDDC which contain Sulphur and Phosphorus that produces and deposit ashes in the car exhaust pipe.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2021.121536</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Acrylic acid ; Antioxidants ; Ashes ; Cresol ; Exhaust pipes ; Lube oil ; Lubricants ; Lubricants & lubrication ; Lubricating oils ; N-Salicylidene Poly Methyl Acrylic Acid Hydrazide ; Oxidation ; p-Cresol ; Phosphorus ; Polymers ; Sulfur ; Vehicle emissions ; ZDDC ; ZDDP ; Zinc ; Zn-complex</subject><ispartof>Fuel (Guildford), 2021-12, Vol.305, p.121536, Article 121536</ispartof><rights>2021 Elsevier Ltd</rights><rights>Copyright Elsevier BV Dec 1, 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c328t-d1e6f7fa544423a30f4f7898f4597ba04ec08ea8726a3cc9d52d00709de856d3</citedby><cites>FETCH-LOGICAL-c328t-d1e6f7fa544423a30f4f7898f4597ba04ec08ea8726a3cc9d52d00709de856d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.fuel.2021.121536$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Salah, Hesham</creatorcontrib><creatorcontrib>Elkatory, Marwa R.</creatorcontrib><creatorcontrib>Abdel Fattah, Marwa</creatorcontrib><title>Novel zinc-polymer complex with antioxidant activity for industrial lubricating oil</title><title>Fuel (Guildford)</title><description>[Display omitted]
•Innovated zinc complex polymer as antioxidant for lube oil.•Fully characterization of the prepared zinc complex polymer using FTIR, SEM, XRD, PSD and BET have been carried out.•Measuring the oxidation stability for the prepared zinc complex polymer.•Certain properties were determined density, total amount of acid, viscosity and carbon residue.•Zinc complex polymer, is effective as a lube oil additive act as antioxidant.
The development of lubricants requires antioxidants, which enhance their efficiency by minimizing waste products derived from oxidation processes. The present study aimed to synthesize (Zn-Complex) Zinc (N-Salicylidene Poly Methyl Acrylic Acid Hydrazide). These obtained polymeric derivatives were characterized by FTIR, XRD, SEM, BET and PSD. The antioxidant behavior was investigated by density, total amount of acid, viscosity and carbon residue. This investigation successfully managed to prepared new additive to the lubricant that does not contain Sulphur and Phosphorus with better lubricant antioxidant properties also has greater efficiency than traditional antioxidant (p-Cresol). This new synthetic antioxidant could be used by industrialists to replace the multipurpose lubricant additive, ZDDP and ZDDC which contain Sulphur and Phosphorus that produces and deposit ashes in the car exhaust pipe.</description><subject>Acrylic acid</subject><subject>Antioxidants</subject><subject>Ashes</subject><subject>Cresol</subject><subject>Exhaust pipes</subject><subject>Lube oil</subject><subject>Lubricants</subject><subject>Lubricants & lubrication</subject><subject>Lubricating oils</subject><subject>N-Salicylidene Poly Methyl Acrylic Acid Hydrazide</subject><subject>Oxidation</subject><subject>p-Cresol</subject><subject>Phosphorus</subject><subject>Polymers</subject><subject>Sulfur</subject><subject>Vehicle emissions</subject><subject>ZDDC</subject><subject>ZDDP</subject><subject>Zinc</subject><subject>Zn-complex</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhYMoWKt_wFXA9dQ85pEBN1J8QdGF3Yc0D82QTsYkU1t_vSnj2tXhwjnnHj4ArjFaYITr225hRu0WBBG8wARXtD4BM8waWjT5OAUzlF0FoTU-BxcxdgihhlXlDLy_-p128Mf2shi8O2x1gNJvB6f38NumTyj6ZP3eqqxQyGR3Nh2g8QHaXo0xBSscdOMmWCmS7T-gt-4SnBnhor760zlYPz6sl8_F6u3pZXm_KiQlLBUK69o0RlRlWRIqKDKlaVjLTFm1zUagUkvEtGANqQWVslUVUXk2apVmVa3oHNxMtUPwX6OOiXd-DH3-yEnFMKtb2rLsIpNLBh9j0IYPwW5FOHCM-JEd7_iRHT-y4xO7HLqbQjrP31kdeJRW91IrG7RMXHn7X_wXO1V4xQ</recordid><startdate>20211201</startdate><enddate>20211201</enddate><creator>Salah, Hesham</creator><creator>Elkatory, Marwa R.</creator><creator>Abdel Fattah, Marwa</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>20211201</creationdate><title>Novel zinc-polymer complex with antioxidant activity for industrial lubricating oil</title><author>Salah, Hesham ; Elkatory, Marwa R. ; Abdel Fattah, Marwa</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-d1e6f7fa544423a30f4f7898f4597ba04ec08ea8726a3cc9d52d00709de856d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acrylic acid</topic><topic>Antioxidants</topic><topic>Ashes</topic><topic>Cresol</topic><topic>Exhaust pipes</topic><topic>Lube oil</topic><topic>Lubricants</topic><topic>Lubricants & lubrication</topic><topic>Lubricating oils</topic><topic>N-Salicylidene Poly Methyl Acrylic Acid Hydrazide</topic><topic>Oxidation</topic><topic>p-Cresol</topic><topic>Phosphorus</topic><topic>Polymers</topic><topic>Sulfur</topic><topic>Vehicle emissions</topic><topic>ZDDC</topic><topic>ZDDP</topic><topic>Zinc</topic><topic>Zn-complex</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Salah, Hesham</creatorcontrib><creatorcontrib>Elkatory, Marwa R.</creatorcontrib><creatorcontrib>Abdel Fattah, Marwa</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Salah, Hesham</au><au>Elkatory, Marwa R.</au><au>Abdel Fattah, Marwa</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel zinc-polymer complex with antioxidant activity for industrial lubricating oil</atitle><jtitle>Fuel (Guildford)</jtitle><date>2021-12-01</date><risdate>2021</risdate><volume>305</volume><spage>121536</spage><pages>121536-</pages><artnum>121536</artnum><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>[Display omitted]
•Innovated zinc complex polymer as antioxidant for lube oil.•Fully characterization of the prepared zinc complex polymer using FTIR, SEM, XRD, PSD and BET have been carried out.•Measuring the oxidation stability for the prepared zinc complex polymer.•Certain properties were determined density, total amount of acid, viscosity and carbon residue.•Zinc complex polymer, is effective as a lube oil additive act as antioxidant.
The development of lubricants requires antioxidants, which enhance their efficiency by minimizing waste products derived from oxidation processes. The present study aimed to synthesize (Zn-Complex) Zinc (N-Salicylidene Poly Methyl Acrylic Acid Hydrazide). These obtained polymeric derivatives were characterized by FTIR, XRD, SEM, BET and PSD. The antioxidant behavior was investigated by density, total amount of acid, viscosity and carbon residue. This investigation successfully managed to prepared new additive to the lubricant that does not contain Sulphur and Phosphorus with better lubricant antioxidant properties also has greater efficiency than traditional antioxidant (p-Cresol). This new synthetic antioxidant could be used by industrialists to replace the multipurpose lubricant additive, ZDDP and ZDDC which contain Sulphur and Phosphorus that produces and deposit ashes in the car exhaust pipe.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.fuel.2021.121536</doi></addata></record> |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Acrylic acid Antioxidants Ashes Cresol Exhaust pipes Lube oil Lubricants Lubricants & lubrication Lubricating oils N-Salicylidene Poly Methyl Acrylic Acid Hydrazide Oxidation p-Cresol Phosphorus Polymers Sulfur Vehicle emissions ZDDC ZDDP Zinc Zn-complex |
| title | Novel zinc-polymer complex with antioxidant activity for industrial lubricating oil |
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