The Quest for Large Group 13 Metallacalixarenes Based on Benzymidazolyl Ligands and Al and Ga Alkyls

Metallacalix[n]arenes derived from AlMe3 or GaMe3 with either 2‐bromo‐1H‐benzimidazole, 2‐Brbzim, or 2‐ethyl‐1H‐benzimidazole, 2‐Etbzim, were obtained by coordination self‐assembly. SCXRD and 1H and 13C NMR in solution are consistent with the isolation of metallacalix[4]arenes 1 and 2, respectively....

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	European journal of inorganic chemistry 2021-10, Vol.2021 (37), p.3896-3902
Hauptverfasser:	Díaz‐Ramírez, Mariana L., Huggins, Hannah, Donnadieu, Bruno, Lopez, Nazario, Muñoz‐Hernández, Miguel‐Ángel
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum Aluminum and gallium complexes Aromatic compounds Calixarenes Gallium Inorganic chemistry Metallacycles Metallocavitands Molecular structure NMR Nuclear magnetic resonance Self-assembly Supramolecular chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!