Distribution of Ce in orthophosphate Sr3(PO4)2
•Distribution of Ce in Sr3 (PO4 )2 was studied by the combined XRD and XAFS analysis.•Single-crystal XRD confirms the location of Ce and vacancy or coexisting Li.•Ce K-edge EXAFS analysis supports the residence of Ce3+ at the 3a-site. The distribution of Ce in orthophosphate Sr3(PO4)2 was investigat...
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| Veröffentlicht in: | Journal of crystal growth 2021-10, Vol.571, p.126267, Article 126267 |
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| container_title | Journal of crystal growth |
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| creator | Tokuda, Makoto Kodama, Yui Niiyama, Shintaro Shinoda, Kozo Sugiyama, Kazumasa |
| description | •Distribution of Ce in Sr3 (PO4 )2 was studied by the combined XRD and XAFS analysis.•Single-crystal XRD confirms the location of Ce and vacancy or coexisting Li.•Ce K-edge EXAFS analysis supports the residence of Ce3+ at the 3a-site.
The distribution of Ce in orthophosphate Sr3(PO4)2 was investigated by the combined single-crystal X-ray diffraction (XRD) and extended X-ray absorption fine structure (EXAFS) analyses. Sr3(PO4)2:Ce3+ compounds with two different Sr sites (3a and 6c sites) were synthesized using the solid-state reaction method. Single-crystal XRD analysis confirmed the location of Ce at the 3a site along with the corresponding vacancy or coexisting Li at the 6c site. Additionally, the Ce K-edge EXAFS analysis supported the occupancy of Ce3+ at the 3a site rather than at the 6c site. |
| doi_str_mv | 10.1016/j.jcrysgro.2021.126267 |
| format | Article |
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The distribution of Ce in orthophosphate Sr3(PO4)2 was investigated by the combined single-crystal X-ray diffraction (XRD) and extended X-ray absorption fine structure (EXAFS) analyses. Sr3(PO4)2:Ce3+ compounds with two different Sr sites (3a and 6c sites) were synthesized using the solid-state reaction method. Single-crystal XRD analysis confirmed the location of Ce at the 3a site along with the corresponding vacancy or coexisting Li at the 6c site. Additionally, the Ce K-edge EXAFS analysis supported the occupancy of Ce3+ at the 3a site rather than at the 6c site.</description><identifier>ISSN: 0022-0248</identifier><identifier>EISSN: 1873-5002</identifier><identifier>DOI: 10.1016/j.jcrysgro.2021.126267</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>A1. X-ray diffraction ; B1. Phosphates ; B2. Phosphors ; B3. Scintillators ; Cerium ; Crystal structure ; Crystals ; Fine structure ; Occupancy ; Single crystals ; X ray absorption ; X-ray diffraction</subject><ispartof>Journal of crystal growth, 2021-10, Vol.571, p.126267, Article 126267</ispartof><rights>2021 Elsevier B.V.</rights><rights>Copyright Elsevier BV Oct 1, 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3697-1a4ee8d0cb6b42d4b554ea98ad186a759de46342eaaa0cb1cc8523974a80d5f63</citedby><cites>FETCH-LOGICAL-c3697-1a4ee8d0cb6b42d4b554ea98ad186a759de46342eaaa0cb1cc8523974a80d5f63</cites><orcidid>0000-0001-8221-4923</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jcrysgro.2021.126267$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Tokuda, Makoto</creatorcontrib><creatorcontrib>Kodama, Yui</creatorcontrib><creatorcontrib>Niiyama, Shintaro</creatorcontrib><creatorcontrib>Shinoda, Kozo</creatorcontrib><creatorcontrib>Sugiyama, Kazumasa</creatorcontrib><title>Distribution of Ce in orthophosphate Sr3(PO4)2</title><title>Journal of crystal growth</title><description>•Distribution of Ce in Sr3 (PO4 )2 was studied by the combined XRD and XAFS analysis.•Single-crystal XRD confirms the location of Ce and vacancy or coexisting Li.•Ce K-edge EXAFS analysis supports the residence of Ce3+ at the 3a-site.
The distribution of Ce in orthophosphate Sr3(PO4)2 was investigated by the combined single-crystal X-ray diffraction (XRD) and extended X-ray absorption fine structure (EXAFS) analyses. Sr3(PO4)2:Ce3+ compounds with two different Sr sites (3a and 6c sites) were synthesized using the solid-state reaction method. Single-crystal XRD analysis confirmed the location of Ce at the 3a site along with the corresponding vacancy or coexisting Li at the 6c site. Additionally, the Ce K-edge EXAFS analysis supported the occupancy of Ce3+ at the 3a site rather than at the 6c site.</description><subject>A1. X-ray diffraction</subject><subject>B1. Phosphates</subject><subject>B2. Phosphors</subject><subject>B3. Scintillators</subject><subject>Cerium</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Fine structure</subject><subject>Occupancy</subject><subject>Single crystals</subject><subject>X ray absorption</subject><subject>X-ray diffraction</subject><issn>0022-0248</issn><issn>1873-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkE9LxDAQxYMouK5-BSl40UNrJk3S9Kasf2FhBfUc0nTqpuimJl3Bb2-W6tnLzBzee8P7EXIKtAAK8rIvehu-41vwBaMMCmCSyWqPzEBVZS4oZftklibLKePqkBzF2FOanEBnpLhxcQyu2Y7ObzLfZQvMXDrCuPbD2sdhbUbMnkN5_rTiF-yYHHTmPeLJ756T17vbl8VDvlzdPy6ul7ktZV3lYDiiaqltZMNZyxshOJpamRaUNJWoW-Sy5AyNMUkE1irByrriRtFWdLKck7Mpdwj-c4tx1L3fhk16qZlQIDjUsFPJSWWDjzFgp4fgPkz41kD1jo3u9R8bvWOjJzbJeDUZMXX4chh0tA43FlsX0I669e6_iB81sG6V</recordid><startdate>20211001</startdate><enddate>20211001</enddate><creator>Tokuda, Makoto</creator><creator>Kodama, Yui</creator><creator>Niiyama, Shintaro</creator><creator>Shinoda, Kozo</creator><creator>Sugiyama, Kazumasa</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-8221-4923</orcidid></search><sort><creationdate>20211001</creationdate><title>Distribution of Ce in orthophosphate Sr3(PO4)2</title><author>Tokuda, Makoto ; Kodama, Yui ; Niiyama, Shintaro ; Shinoda, Kozo ; Sugiyama, Kazumasa</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3697-1a4ee8d0cb6b42d4b554ea98ad186a759de46342eaaa0cb1cc8523974a80d5f63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>A1. X-ray diffraction</topic><topic>B1. Phosphates</topic><topic>B2. Phosphors</topic><topic>B3. Scintillators</topic><topic>Cerium</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Fine structure</topic><topic>Occupancy</topic><topic>Single crystals</topic><topic>X ray absorption</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tokuda, Makoto</creatorcontrib><creatorcontrib>Kodama, Yui</creatorcontrib><creatorcontrib>Niiyama, Shintaro</creatorcontrib><creatorcontrib>Shinoda, Kozo</creatorcontrib><creatorcontrib>Sugiyama, Kazumasa</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of crystal growth</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tokuda, Makoto</au><au>Kodama, Yui</au><au>Niiyama, Shintaro</au><au>Shinoda, Kozo</au><au>Sugiyama, Kazumasa</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Distribution of Ce in orthophosphate Sr3(PO4)2</atitle><jtitle>Journal of crystal growth</jtitle><date>2021-10-01</date><risdate>2021</risdate><volume>571</volume><spage>126267</spage><pages>126267-</pages><artnum>126267</artnum><issn>0022-0248</issn><eissn>1873-5002</eissn><abstract>•Distribution of Ce in Sr3 (PO4 )2 was studied by the combined XRD and XAFS analysis.•Single-crystal XRD confirms the location of Ce and vacancy or coexisting Li.•Ce K-edge EXAFS analysis supports the residence of Ce3+ at the 3a-site.
The distribution of Ce in orthophosphate Sr3(PO4)2 was investigated by the combined single-crystal X-ray diffraction (XRD) and extended X-ray absorption fine structure (EXAFS) analyses. Sr3(PO4)2:Ce3+ compounds with two different Sr sites (3a and 6c sites) were synthesized using the solid-state reaction method. Single-crystal XRD analysis confirmed the location of Ce at the 3a site along with the corresponding vacancy or coexisting Li at the 6c site. Additionally, the Ce K-edge EXAFS analysis supported the occupancy of Ce3+ at the 3a site rather than at the 6c site.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jcrysgro.2021.126267</doi><orcidid>https://orcid.org/0000-0001-8221-4923</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | A1. X-ray diffraction B1. Phosphates B2. Phosphors B3. Scintillators Cerium Crystal structure Crystals Fine structure Occupancy Single crystals X ray absorption X-ray diffraction |
| title | Distribution of Ce in orthophosphate Sr3(PO4)2 |
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