Structural, dielectric, electrical and modulus spectroscopic characteristics of CoFeCuO4 spinel ferrite nanoparticles
[Display omitted] •CoFeCuO4 prepared by sol–gel method adopts a cubic symmetry with Fd3-m space group.•The temperature and frequency dependence of dielectric constants was investigated.•Dielectric analysis reveals a single thermally activated conduction mechanism.•Substitution of Fe by Cu increases...
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creator | Nasri, M. Henchiri, C. Dhahri, R. Khelifi, J. Rahmouni, H. Dhahri, E. Omari, L.H. Tozri, A. Berber, Mohamed R. |
description | [Display omitted]
•CoFeCuO4 prepared by sol–gel method adopts a cubic symmetry with Fd3-m space group.•The temperature and frequency dependence of dielectric constants was investigated.•Dielectric analysis reveals a single thermally activated conduction mechanism.•Substitution of Fe by Cu increases ac conductivity and decreases the dielectric loss.•The mechanism responsible of electrical conductivity is related to the relaxation one.
In this work, our focus is upon the synthesis of material having useful and less expensive high frequency applications. For this purpose, we used the sol–gel method to elaborate the Cu-substituted CoFe2O4. The XRD analysis confirmed the single-phase cubic spinel structure with the Fd3-m space group. The grain size distribution was traced through different methods. It confirms the nano-metric size of the compound. To elaborate the electrical and dielectric properties of the prepared sample, impedance spectroscopy was invested. It demonstrated the relaxing nature of our material and indicated that the substitution of Fe by Cu on CoFe2O4 increases the ac conductivity and decreases the dielectric loss especially at higher frequencies; the low loss values indicate the potential of these ferrites for high frequency applications at temperatures close to the room temperature. The activation energy value was estimated based on the relaxation time and the conductance curves analysis, the found value is around 0.33 eV which confirms the semiconductor character of our compound and its capacity to achieve a significant gain in productivity. Moreover, this obtained value indicates the relationship between the electrical conductivity mechanism and the relaxation one. |
doi_str_mv | 10.1016/j.mseb.2021.115331 |
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•CoFeCuO4 prepared by sol–gel method adopts a cubic symmetry with Fd3-m space group.•The temperature and frequency dependence of dielectric constants was investigated.•Dielectric analysis reveals a single thermally activated conduction mechanism.•Substitution of Fe by Cu increases ac conductivity and decreases the dielectric loss.•The mechanism responsible of electrical conductivity is related to the relaxation one.
In this work, our focus is upon the synthesis of material having useful and less expensive high frequency applications. For this purpose, we used the sol–gel method to elaborate the Cu-substituted CoFe2O4. The XRD analysis confirmed the single-phase cubic spinel structure with the Fd3-m space group. The grain size distribution was traced through different methods. It confirms the nano-metric size of the compound. To elaborate the electrical and dielectric properties of the prepared sample, impedance spectroscopy was invested. It demonstrated the relaxing nature of our material and indicated that the substitution of Fe by Cu on CoFe2O4 increases the ac conductivity and decreases the dielectric loss especially at higher frequencies; the low loss values indicate the potential of these ferrites for high frequency applications at temperatures close to the room temperature. The activation energy value was estimated based on the relaxation time and the conductance curves analysis, the found value is around 0.33 eV which confirms the semiconductor character of our compound and its capacity to achieve a significant gain in productivity. Moreover, this obtained value indicates the relationship between the electrical conductivity mechanism and the relaxation one.</description><identifier>ISSN: 0921-5107</identifier><identifier>EISSN: 1873-4944</identifier><identifier>DOI: 10.1016/j.mseb.2021.115331</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>ac Electrical conductivity ; Activation energy ; Cobalt ferrites ; Copper ; Dielectric loss ; Dielectric properties ; Electrical resistivity ; Energy value ; Grain size distribution ; High frequencies ; Impedance spectroscopy ; Nanoparticles ; Phenomenon of relaxation ; Relaxation time ; Room temperature ; Sol-gel processes ; Spinel ; Spinel ferrite</subject><ispartof>Materials science & engineering. B, Solid-state materials for advanced technology, 2021-10, Vol.272, p.115331, Article 115331</ispartof><rights>2021 Elsevier B.V.</rights><rights>Copyright Elsevier BV Oct 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c328t-af5ba715b6aea9c89e9a45078fd3d58ed60f0559f34e7706f47cc92f062c93233</citedby><cites>FETCH-LOGICAL-c328t-af5ba715b6aea9c89e9a45078fd3d58ed60f0559f34e7706f47cc92f062c93233</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.mseb.2021.115331$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,777,781,3537,27905,27906,45976</link.rule.ids></links><search><creatorcontrib>Nasri, M.</creatorcontrib><creatorcontrib>Henchiri, C.</creatorcontrib><creatorcontrib>Dhahri, R.</creatorcontrib><creatorcontrib>Khelifi, J.</creatorcontrib><creatorcontrib>Rahmouni, H.</creatorcontrib><creatorcontrib>Dhahri, E.</creatorcontrib><creatorcontrib>Omari, L.H.</creatorcontrib><creatorcontrib>Tozri, A.</creatorcontrib><creatorcontrib>Berber, Mohamed R.</creatorcontrib><title>Structural, dielectric, electrical and modulus spectroscopic characteristics of CoFeCuO4 spinel ferrite nanoparticles</title><title>Materials science & engineering. B, Solid-state materials for advanced technology</title><description>[Display omitted]
•CoFeCuO4 prepared by sol–gel method adopts a cubic symmetry with Fd3-m space group.•The temperature and frequency dependence of dielectric constants was investigated.•Dielectric analysis reveals a single thermally activated conduction mechanism.•Substitution of Fe by Cu increases ac conductivity and decreases the dielectric loss.•The mechanism responsible of electrical conductivity is related to the relaxation one.
In this work, our focus is upon the synthesis of material having useful and less expensive high frequency applications. For this purpose, we used the sol–gel method to elaborate the Cu-substituted CoFe2O4. The XRD analysis confirmed the single-phase cubic spinel structure with the Fd3-m space group. The grain size distribution was traced through different methods. It confirms the nano-metric size of the compound. To elaborate the electrical and dielectric properties of the prepared sample, impedance spectroscopy was invested. It demonstrated the relaxing nature of our material and indicated that the substitution of Fe by Cu on CoFe2O4 increases the ac conductivity and decreases the dielectric loss especially at higher frequencies; the low loss values indicate the potential of these ferrites for high frequency applications at temperatures close to the room temperature. The activation energy value was estimated based on the relaxation time and the conductance curves analysis, the found value is around 0.33 eV which confirms the semiconductor character of our compound and its capacity to achieve a significant gain in productivity. Moreover, this obtained value indicates the relationship between the electrical conductivity mechanism and the relaxation one.</description><subject>ac Electrical conductivity</subject><subject>Activation energy</subject><subject>Cobalt ferrites</subject><subject>Copper</subject><subject>Dielectric loss</subject><subject>Dielectric properties</subject><subject>Electrical resistivity</subject><subject>Energy value</subject><subject>Grain size distribution</subject><subject>High frequencies</subject><subject>Impedance spectroscopy</subject><subject>Nanoparticles</subject><subject>Phenomenon of relaxation</subject><subject>Relaxation time</subject><subject>Room temperature</subject><subject>Sol-gel processes</subject><subject>Spinel</subject><subject>Spinel ferrite</subject><issn>0921-5107</issn><issn>1873-4944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKxDAUhoMoOI6-gKuAWzvm0rQNuJHiqDAwC3UdMukJpnSamqSCb29Ldesqh_D95_IhdE3JhhJa3LWbY4TDhhFGN5QKzukJWtGq5Fku8_wUrYhkNBOUlOfoIsaWEEIZYys0vqYwmjQG3d3ixkEHJgVnbvFfpTus-wYffTN2Y8RxmL99NH5wBpsPHbRJEFxMzkTsLa79Fupxn0-k66HDFkJwCXCvez_oMGEdxEt0ZnUX4er3XaP37eNb_Zzt9k8v9cMuM5xVKdNWHHRJxaHQoKWpJEidC1JWtuGNqKApiCVCSMtzKEtS2Lw0RjJLCmYkZ5yv0c3Sdwj-c4SYVOvH0E8jFRMVJYXkkk4UWygzHRYDWDUEd9ThW1GiZr2qVbNeNetVi94pdL-EYNr_y0FQ0TjoDTQuTIpU491_8R8IaIVr</recordid><startdate>202110</startdate><enddate>202110</enddate><creator>Nasri, M.</creator><creator>Henchiri, C.</creator><creator>Dhahri, R.</creator><creator>Khelifi, J.</creator><creator>Rahmouni, H.</creator><creator>Dhahri, E.</creator><creator>Omari, L.H.</creator><creator>Tozri, A.</creator><creator>Berber, Mohamed R.</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>202110</creationdate><title>Structural, dielectric, electrical and modulus spectroscopic characteristics of CoFeCuO4 spinel ferrite nanoparticles</title><author>Nasri, M. ; Henchiri, C. ; Dhahri, R. ; Khelifi, J. ; Rahmouni, H. ; Dhahri, E. ; Omari, L.H. ; Tozri, A. ; Berber, Mohamed R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-af5ba715b6aea9c89e9a45078fd3d58ed60f0559f34e7706f47cc92f062c93233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>ac Electrical conductivity</topic><topic>Activation energy</topic><topic>Cobalt ferrites</topic><topic>Copper</topic><topic>Dielectric loss</topic><topic>Dielectric properties</topic><topic>Electrical resistivity</topic><topic>Energy value</topic><topic>Grain size distribution</topic><topic>High frequencies</topic><topic>Impedance spectroscopy</topic><topic>Nanoparticles</topic><topic>Phenomenon of relaxation</topic><topic>Relaxation time</topic><topic>Room temperature</topic><topic>Sol-gel processes</topic><topic>Spinel</topic><topic>Spinel ferrite</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nasri, M.</creatorcontrib><creatorcontrib>Henchiri, C.</creatorcontrib><creatorcontrib>Dhahri, R.</creatorcontrib><creatorcontrib>Khelifi, J.</creatorcontrib><creatorcontrib>Rahmouni, H.</creatorcontrib><creatorcontrib>Dhahri, E.</creatorcontrib><creatorcontrib>Omari, L.H.</creatorcontrib><creatorcontrib>Tozri, A.</creatorcontrib><creatorcontrib>Berber, Mohamed R.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Materials science & engineering. B, Solid-state materials for advanced technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nasri, M.</au><au>Henchiri, C.</au><au>Dhahri, R.</au><au>Khelifi, J.</au><au>Rahmouni, H.</au><au>Dhahri, E.</au><au>Omari, L.H.</au><au>Tozri, A.</au><au>Berber, Mohamed R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural, dielectric, electrical and modulus spectroscopic characteristics of CoFeCuO4 spinel ferrite nanoparticles</atitle><jtitle>Materials science & engineering. B, Solid-state materials for advanced technology</jtitle><date>2021-10</date><risdate>2021</risdate><volume>272</volume><spage>115331</spage><pages>115331-</pages><artnum>115331</artnum><issn>0921-5107</issn><eissn>1873-4944</eissn><abstract>[Display omitted]
•CoFeCuO4 prepared by sol–gel method adopts a cubic symmetry with Fd3-m space group.•The temperature and frequency dependence of dielectric constants was investigated.•Dielectric analysis reveals a single thermally activated conduction mechanism.•Substitution of Fe by Cu increases ac conductivity and decreases the dielectric loss.•The mechanism responsible of electrical conductivity is related to the relaxation one.
In this work, our focus is upon the synthesis of material having useful and less expensive high frequency applications. For this purpose, we used the sol–gel method to elaborate the Cu-substituted CoFe2O4. The XRD analysis confirmed the single-phase cubic spinel structure with the Fd3-m space group. The grain size distribution was traced through different methods. It confirms the nano-metric size of the compound. To elaborate the electrical and dielectric properties of the prepared sample, impedance spectroscopy was invested. It demonstrated the relaxing nature of our material and indicated that the substitution of Fe by Cu on CoFe2O4 increases the ac conductivity and decreases the dielectric loss especially at higher frequencies; the low loss values indicate the potential of these ferrites for high frequency applications at temperatures close to the room temperature. The activation energy value was estimated based on the relaxation time and the conductance curves analysis, the found value is around 0.33 eV which confirms the semiconductor character of our compound and its capacity to achieve a significant gain in productivity. Moreover, this obtained value indicates the relationship between the electrical conductivity mechanism and the relaxation one.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.mseb.2021.115331</doi></addata></record> |
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subjects | ac Electrical conductivity Activation energy Cobalt ferrites Copper Dielectric loss Dielectric properties Electrical resistivity Energy value Grain size distribution High frequencies Impedance spectroscopy Nanoparticles Phenomenon of relaxation Relaxation time Room temperature Sol-gel processes Spinel Spinel ferrite |
title | Structural, dielectric, electrical and modulus spectroscopic characteristics of CoFeCuO4 spinel ferrite nanoparticles |
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