A safe and efficient synthetic method for alkali metal octahydrotriborates, unravelling a general mechanism for constructing the delta B3 unit of polyhedral boranes
A safe and efficient synthetic method for MB 3 H 8 (M = Na, K, Rb and Cs) has been developed with excellent yields by directly reacting the corresponding MBH 4 with the dimethyl sulfide borane complex (DMS·BH 3 ). A general mechanism for constructing B 3 H 8 − , a basic unit for building polyhedral...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2021-10, Vol.5 (39), p.13676-13679 |
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| container_end_page | 13679 |
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| container_issue | 39 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Chen, Xuenian Liu, Xin-Ran Wang, Xinghua Chen, Xi-Meng Jing, Yi Wei, Donghui |
| description | A safe and efficient synthetic method for MB
3
H
8
(M = Na, K, Rb and Cs) has been developed with excellent yields by directly reacting the corresponding MBH
4
with the dimethyl sulfide borane complex (DMS·BH
3
). A general mechanism for constructing B
3
H
8
−
, a basic unit for building polyhedral boranes, has been unravelled.
An efficient synthetic method for KB
3
H
8
has been developed and general mechanisms of formation of the B
3
H
8
−
anion have been elucidated. |
| doi_str_mv | 10.1039/d1dt01892b |
| format | Article |
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3
H
8
(M = Na, K, Rb and Cs) has been developed with excellent yields by directly reacting the corresponding MBH
4
with the dimethyl sulfide borane complex (DMS·BH
3
). A general mechanism for constructing B
3
H
8
−
, a basic unit for building polyhedral boranes, has been unravelled.
An efficient synthetic method for KB
3
H
8
has been developed and general mechanisms of formation of the B
3
H
8
−
anion have been elucidated.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d1dt01892b</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Alkali metals ; Boranes ; Dimethyl sulfide</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2021-10, Vol.5 (39), p.13676-13679</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c314t-8b508addd7418fe95a2a0a9bb928945c1052f0529be7b6e4b97692131c120b9d3</citedby><cites>FETCH-LOGICAL-c314t-8b508addd7418fe95a2a0a9bb928945c1052f0529be7b6e4b97692131c120b9d3</cites><orcidid>0000-0002-9627-0683 ; 0000-0003-2820-282X ; 0000-0001-9029-1777</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Chen, Xuenian</creatorcontrib><creatorcontrib>Liu, Xin-Ran</creatorcontrib><creatorcontrib>Wang, Xinghua</creatorcontrib><creatorcontrib>Chen, Xi-Meng</creatorcontrib><creatorcontrib>Jing, Yi</creatorcontrib><creatorcontrib>Wei, Donghui</creatorcontrib><title>A safe and efficient synthetic method for alkali metal octahydrotriborates, unravelling a general mechanism for constructing the delta B3 unit of polyhedral boranes</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>A safe and efficient synthetic method for MB
3
H
8
(M = Na, K, Rb and Cs) has been developed with excellent yields by directly reacting the corresponding MBH
4
with the dimethyl sulfide borane complex (DMS·BH
3
). A general mechanism for constructing B
3
H
8
−
, a basic unit for building polyhedral boranes, has been unravelled.
An efficient synthetic method for KB
3
H
8
has been developed and general mechanisms of formation of the B
3
H
8
−
anion have been elucidated.</description><subject>Alkali metals</subject><subject>Boranes</subject><subject>Dimethyl sulfide</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdkc9L5TAQx4usoKtevAuBvcji0yRtX5ujvxUEL3ouk2Ri47bJM0kX3v_jH2rqExf2MMwwfOY7M3yL4pDRU0ZLcaaZTpS1gsutYpdVTbMQvKx-fNd8uVP8jPGVUs5pzXeL93MSwSABpwkaY5VFl0hcu9RjsoqMmHqvifGBwPAHBjt3YCBeJejXOvgUrPQBEsYTMrkAf3EYrHshQF7QYcjoiKoHZ-P4qaK8iylMKs1QXkI0DgnIRZmnbSLekJUf1j3qeXRWdhj3i20DQ8SDr7xXPN9cP13eLR4eb-8vzx8WqmRVWrSypi1orZuKtQZFDRwoCCkFb0VVK5Y_NjmExEYusZKiWQrOSqYYp1Locq843uiugn-bMKZutFHlh_IRfoodr5uWVS1jdUZ__Ye--im4fF2mWipoyauZ-r2hVPAxBjTdKtgRwrpjtJsN667Y1dOnYRcZPtrAIapv7p-h5Qffv5TX</recordid><startdate>20211012</startdate><enddate>20211012</enddate><creator>Chen, Xuenian</creator><creator>Liu, Xin-Ran</creator><creator>Wang, Xinghua</creator><creator>Chen, Xi-Meng</creator><creator>Jing, Yi</creator><creator>Wei, Donghui</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-9627-0683</orcidid><orcidid>https://orcid.org/0000-0003-2820-282X</orcidid><orcidid>https://orcid.org/0000-0001-9029-1777</orcidid></search><sort><creationdate>20211012</creationdate><title>A safe and efficient synthetic method for alkali metal octahydrotriborates, unravelling a general mechanism for constructing the delta B3 unit of polyhedral boranes</title><author>Chen, Xuenian ; Liu, Xin-Ran ; Wang, Xinghua ; Chen, Xi-Meng ; Jing, Yi ; Wei, Donghui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c314t-8b508addd7418fe95a2a0a9bb928945c1052f0529be7b6e4b97692131c120b9d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Alkali metals</topic><topic>Boranes</topic><topic>Dimethyl sulfide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Xuenian</creatorcontrib><creatorcontrib>Liu, Xin-Ran</creatorcontrib><creatorcontrib>Wang, Xinghua</creatorcontrib><creatorcontrib>Chen, Xi-Meng</creatorcontrib><creatorcontrib>Jing, Yi</creatorcontrib><creatorcontrib>Wei, Donghui</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Xuenian</au><au>Liu, Xin-Ran</au><au>Wang, Xinghua</au><au>Chen, Xi-Meng</au><au>Jing, Yi</au><au>Wei, Donghui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A safe and efficient synthetic method for alkali metal octahydrotriborates, unravelling a general mechanism for constructing the delta B3 unit of polyhedral boranes</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2021-10-12</date><risdate>2021</risdate><volume>5</volume><issue>39</issue><spage>13676</spage><epage>13679</epage><pages>13676-13679</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A safe and efficient synthetic method for MB
3
H
8
(M = Na, K, Rb and Cs) has been developed with excellent yields by directly reacting the corresponding MBH
4
with the dimethyl sulfide borane complex (DMS·BH
3
). A general mechanism for constructing B
3
H
8
−
, a basic unit for building polyhedral boranes, has been unravelled.
An efficient synthetic method for KB
3
H
8
has been developed and general mechanisms of formation of the B
3
H
8
−
anion have been elucidated.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1dt01892b</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-9627-0683</orcidid><orcidid>https://orcid.org/0000-0003-2820-282X</orcidid><orcidid>https://orcid.org/0000-0001-9029-1777</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2021-10, Vol.5 (39), p.13676-13679 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_journals_2580903245 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alkali metals Boranes Dimethyl sulfide |
| title | A safe and efficient synthetic method for alkali metal octahydrotriborates, unravelling a general mechanism for constructing the delta B3 unit of polyhedral boranes |
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