Electrochemical Determination of Triclosan Using ZIF-11/Activated Carbon Derived from the Rice Husk Modified Electrode
In the present paper, the composite of zeolite imidazolate framework-11 (ZIF-11) and activated carbon derived from rice husks (RHAC) was synthesized. The obtained materials were characterized by XRD, SEM, EDX-mapping, and nitrogen adsorption/desorption isotherms. The final composite ZIF-11/RHAC exhi...
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| Veröffentlicht in: | Journal of nanomaterials 2021-10, Vol.2021, p.1-14 |
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| container_title | Journal of nanomaterials |
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| creator | Luyen, Nguyen Dinh Toan, Tran Thanh Tam Trang, Ha Thuy Nguyen, Vo Thang Son, Le Van Thanh Thanh, Tran Si Thanh, Nguyen Mau Quy, Phan Tu Khieu, Dinh Quang |
| description | In the present paper, the composite of zeolite imidazolate framework-11 (ZIF-11) and activated carbon derived from rice husks (RHAC) was synthesized. The obtained materials were characterized by XRD, SEM, EDX-mapping, and nitrogen adsorption/desorption isotherms. The final composite ZIF-11/RHAC exhibits an even dispersion of ZIF-11 particles on activated carbon matrix. Herein, an electrochemical sensor based on a ZIF-11/RHAC was developed for a rapid determination of triclosan (TCS). It was found that the oxidation of TCS is irreversible and involves the transfer of one electron. The linear range for TCS detection in the optimized experimental conditions was found to be 0.1-8 μM with the limit of detection of 0.076 μM. Finally, the proposed method was successfully employed to detect TCS in different personal care product samples with high accuracy, which was confirmed by a good agreement between these results and those obtained using high-performance liquid chromatography (HPLC). |
| doi_str_mv | 10.1155/2021/8486962 |
| format | Article |
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The obtained materials were characterized by XRD, SEM, EDX-mapping, and nitrogen adsorption/desorption isotherms. The final composite ZIF-11/RHAC exhibits an even dispersion of ZIF-11 particles on activated carbon matrix. Herein, an electrochemical sensor based on a ZIF-11/RHAC was developed for a rapid determination of triclosan (TCS). It was found that the oxidation of TCS is irreversible and involves the transfer of one electron. The linear range for TCS detection in the optimized experimental conditions was found to be 0.1-8 μM with the limit of detection of 0.076 μM. Finally, the proposed method was successfully employed to detect TCS in different personal care product samples with high accuracy, which was confirmed by a good agreement between these results and those obtained using high-performance liquid chromatography (HPLC).</description><identifier>ISSN: 1687-4110</identifier><identifier>EISSN: 1687-4129</identifier><identifier>DOI: 10.1155/2021/8486962</identifier><language>eng</language><publisher>New York: Hindawi</publisher><subject>Activated carbon ; Charcoal ; Chemical sensors ; Chromatography ; Composite materials ; Cosmetics ; Electrodes ; Gram-positive bacteria ; Graphene ; High performance liquid chromatography ; Mass spectrometry ; Nanomaterials ; Oxidation ; Porous materials ; Scientific imaging ; Sensors ; Voltammetry ; Zeolites ; Zinc</subject><ispartof>Journal of nanomaterials, 2021-10, Vol.2021, p.1-14</ispartof><rights>Copyright © 2021 Nguyen Dinh Luyen et al.</rights><rights>Copyright © 2021 Nguyen Dinh Luyen et al. This is an open access article distributed under the Creative Commons Attribution License (the “License”), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. https://creativecommons.org/licenses/by/4.0</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-a86c3843e6107d884a6887ddadea80eedc811183d5cb3f666a0032c72ff7deac3</citedby><cites>FETCH-LOGICAL-c337t-a86c3843e6107d884a6887ddadea80eedc811183d5cb3f666a0032c72ff7deac3</cites><orcidid>0000-0003-3473-6377</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><contributor>Nguyen, Duy Trinh</contributor><contributor>Duy Trinh Nguyen</contributor><creatorcontrib>Luyen, Nguyen Dinh</creatorcontrib><creatorcontrib>Toan, Tran Thanh Tam</creatorcontrib><creatorcontrib>Trang, Ha Thuy</creatorcontrib><creatorcontrib>Nguyen, Vo Thang</creatorcontrib><creatorcontrib>Son, Le Van Thanh</creatorcontrib><creatorcontrib>Thanh, Tran Si</creatorcontrib><creatorcontrib>Thanh, Nguyen Mau</creatorcontrib><creatorcontrib>Quy, Phan Tu</creatorcontrib><creatorcontrib>Khieu, Dinh Quang</creatorcontrib><title>Electrochemical Determination of Triclosan Using ZIF-11/Activated Carbon Derived from the Rice Husk Modified Electrode</title><title>Journal of nanomaterials</title><description>In the present paper, the composite of zeolite imidazolate framework-11 (ZIF-11) and activated carbon derived from rice husks (RHAC) was synthesized. 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| subjects | Activated carbon Charcoal Chemical sensors Chromatography Composite materials Cosmetics Electrodes Gram-positive bacteria Graphene High performance liquid chromatography Mass spectrometry Nanomaterials Oxidation Porous materials Scientific imaging Sensors Voltammetry Zeolites Zinc |
| title | Electrochemical Determination of Triclosan Using ZIF-11/Activated Carbon Derived from the Rice Husk Modified Electrode |
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