Hydrogen isotope exchange and H(D) atom addition reaction of solid formaldehyde on amorphous solid water at low temperatures

Reaction routes when H2CO and D2CO were exposed to the D and H atoms on amorphous solid water (ASW) at 10–20 K, respectively, were studied experimentally by IR spectroscopy. For D + H2CO on ASW, H2CO was converted to HDCO and D2CO by the H-D substitution reactions. Although CD3OD was slightly observ...

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Veröffentlicht in:	Journal of physics. Conference series 2009-11, Vol.194 (13)
Hauptverfasser:	Hidaka, Hiroshi, Watanabe, Motohiro, Kouchi, Akira, Watanabe, Naoki
Format:	Artikel
Sprache:	eng
Schlagworte:	Deuteration Hydrogen isotopes Infrared spectroscopy Low temperature Methanol Physics Substitution reactions
Online-Zugang:	Volltext
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