Characterisation of contact twinning for cerussite, PbCO3, by single-crystal NMR spectroscopy
Cerussite, PbCO 3 , like all members of the aragonite group, shows a tendency to form twins, due to high pseudo-symmetry within the crystal structure. We here demonstrate that the twin law of a cerussite contact twin may be established using only 207 Pb-NMR spectroscopy. This is achieved by a global...
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| container_title | Physics and chemistry of minerals |
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| creator | Zeman, Otto E. O. Steinadler, Jennifer Hochleitner, Rupert Bräuniger, Thomas |
| description | Cerussite,
PbCO
3
, like all members of the aragonite group, shows a tendency to form twins, due to high pseudo-symmetry within the crystal structure. We here demonstrate that the twin law of a cerussite contact twin may be established using only
207
Pb-NMR spectroscopy. This is achieved by a global fit of several sets of orientation-dependent spectra acquired from the twin specimen, allowing to determine the relative orientation of the twin domains. Also, the full
207
Pb chemical shift tensor in cerussite at room temperature is determined from these data, with the eigenvalues being
δ
11
=
(
-
2315
±
1
)
ppm,
δ
22
=
(
-
2492
±
3
)
ppm, and
δ
33
=
(
-
3071
±
3
)
ppm. |
| doi_str_mv | 10.1007/s00269-021-01162-6 |
| format | Article |
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PbCO
3
, like all members of the aragonite group, shows a tendency to form twins, due to high pseudo-symmetry within the crystal structure. We here demonstrate that the twin law of a cerussite contact twin may be established using only
207
Pb-NMR spectroscopy. This is achieved by a global fit of several sets of orientation-dependent spectra acquired from the twin specimen, allowing to determine the relative orientation of the twin domains. Also, the full
207
Pb chemical shift tensor in cerussite at room temperature is determined from these data, with the eigenvalues being
δ
11
=
(
-
2315
±
1
)
ppm,
δ
22
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3
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PbCO
3
, like all members of the aragonite group, shows a tendency to form twins, due to high pseudo-symmetry within the crystal structure. We here demonstrate that the twin law of a cerussite contact twin may be established using only
207
Pb-NMR spectroscopy. This is achieved by a global fit of several sets of orientation-dependent spectra acquired from the twin specimen, allowing to determine the relative orientation of the twin domains. Also, the full
207
Pb chemical shift tensor in cerussite at room temperature is determined from these data, with the eigenvalues being
δ
11
=
(
-
2315
±
1
)
ppm,
δ
22
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-
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δ
33
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O.</creatorcontrib><creatorcontrib>Steinadler, Jennifer</creatorcontrib><creatorcontrib>Hochleitner, Rupert</creatorcontrib><creatorcontrib>Bräuniger, Thomas</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Physics and chemistry of minerals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zeman, Otto E. 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PbCO
3
, like all members of the aragonite group, shows a tendency to form twins, due to high pseudo-symmetry within the crystal structure. We here demonstrate that the twin law of a cerussite contact twin may be established using only
207
Pb-NMR spectroscopy. This is achieved by a global fit of several sets of orientation-dependent spectra acquired from the twin specimen, allowing to determine the relative orientation of the twin domains. Also, the full
207
Pb chemical shift tensor in cerussite at room temperature is determined from these data, with the eigenvalues being
δ
11
=
(
-
2315
±
1
)
ppm,
δ
22
=
(
-
2492
±
3
)
ppm, and
δ
33
=
(
-
3071
±
3
)
ppm.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00269-021-01162-6</doi><orcidid>https://orcid.org/0000-0001-7321-880X</orcidid><oa>free_for_read</oa></addata></record> |
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| language | eng |
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| subjects | Aragonite Chemical equilibrium Crystal structure Crystallography and Scattering Methods Crystals Earth and Environmental Science Earth Sciences Eigenvalues Geochemistry Lead isotopes Mineral Resources Mineralogy NMR spectroscopy Original Paper Room temperature Single crystals Spectroscopy Spectrum analysis Tensors Twinning |
| title | Characterisation of contact twinning for cerussite, PbCO3, by single-crystal NMR spectroscopy |
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