The effect of cavity size on ruthenium (II) tris-(2,2-bipyridine) photophysics encapsulated within zirconium based metal organic frameworks

[Display omitted] •Ru(II)(2,2′-bipyridine)3 has been encapsulated in ZrO based metal organic frameworks.•The Uio-66, −67 and −68 of MOFs has been examined due to their variable pore sizes.•The results demonstrate variable effects of pore sine on the Ru complex photophysics.•The smaller pore sizes of...

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Veröffentlicht in:Inorganica Chimica Acta 2021-10, Vol.526, p.120537, Article 120537
Hauptverfasser: Mayers, Jacob M., Larsen, Randy W.
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Sprache:eng
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