Synthesis, Crystal Structure, and Physicochemical Properties of Bi4–xPrxTi3O12 (x = 0.4, 0.8, 1.2, 1.6) Solid Solutions
— Bi 4– x Pr x Ti 3 O 12 ( x = 0.4, 0.8, 1.2, 1.6) solid solutions have been prepared by solid-state reactions, via multistep firing of stoichiometric mixtures of their constituent oxides in air at temperatures from 1003 to 1323 K. Their crystal structure has been determined using X-ray diffraction,...
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| Veröffentlicht in: | Inorganic materials 2021-09, Vol.57 (9), p.919-928 |
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| container_title | Inorganic materials |
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| creator | Denisova, L. T. Molokeev, M. S. Kargin, Yu. F. Gerasimov, V. P. Krylov, A. S. Aleksandrovskii, A. S. Chumilina, L. G. Denisov, V. M. Vasil’ev, G. V. |
| description | —
Bi
4–
x
Pr
x
Ti
3
O
12
(
x
= 0.4, 0.8, 1.2, 1.6) solid solutions have been prepared by solid-state reactions, via multistep firing of stoichiometric mixtures of their constituent oxides in air at temperatures from 1003 to 1323 K. Their crystal structure has been determined using X-ray diffraction, and their luminescence spectra have been measured at room temperature. High-temperature heat capacity of polycrystalline substituted bismuth titanate samples has been determined by differential scanning calorimetry. The
C
p
(
T
) curves of the solid solutions with
x
= 0.4 and 0.8 have extrema related to phase transitions. Experimental data have been used to calculate the main thermodynamic functions of the solid solutions. |
| doi_str_mv | 10.1134/S002016852109003X |
| format | Article |
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Bi
4–
x
Pr
x
Ti
3
O
12
(
x
= 0.4, 0.8, 1.2, 1.6) solid solutions have been prepared by solid-state reactions, via multistep firing of stoichiometric mixtures of their constituent oxides in air at temperatures from 1003 to 1323 K. Their crystal structure has been determined using X-ray diffraction, and their luminescence spectra have been measured at room temperature. High-temperature heat capacity of polycrystalline substituted bismuth titanate samples has been determined by differential scanning calorimetry. The
C
p
(
T
) curves of the solid solutions with
x
= 0.4 and 0.8 have extrema related to phase transitions. Experimental data have been used to calculate the main thermodynamic functions of the solid solutions.</description><identifier>ISSN: 0020-1685</identifier><identifier>EISSN: 1608-3172</identifier><identifier>DOI: 10.1134/S002016852109003X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Bismuth titanate ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; High temperature ; Industrial Chemistry/Chemical Engineering ; Inorganic Chemistry ; Materials Science ; Mathematical analysis ; Phase transitions ; Room temperature ; Solid solutions</subject><ispartof>Inorganic materials, 2021-09, Vol.57 (9), p.919-928</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 0020-1685, Inorganic Materials, 2021, Vol. 57, No. 9, pp. 919–928. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Neorganicheskie Materialy, 2021, Vol. 57, No. 9, pp. 968–977.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c246t-bd0ce0da2da7d3048336cb1b5c09d99c876d4b83c3834a181786607fa351b5a13</citedby><cites>FETCH-LOGICAL-c246t-bd0ce0da2da7d3048336cb1b5c09d99c876d4b83c3834a181786607fa351b5a13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S002016852109003X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S002016852109003X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Denisova, L. T.</creatorcontrib><creatorcontrib>Molokeev, M. S.</creatorcontrib><creatorcontrib>Kargin, Yu. F.</creatorcontrib><creatorcontrib>Gerasimov, V. P.</creatorcontrib><creatorcontrib>Krylov, A. S.</creatorcontrib><creatorcontrib>Aleksandrovskii, A. S.</creatorcontrib><creatorcontrib>Chumilina, L. G.</creatorcontrib><creatorcontrib>Denisov, V. M.</creatorcontrib><creatorcontrib>Vasil’ev, G. V.</creatorcontrib><title>Synthesis, Crystal Structure, and Physicochemical Properties of Bi4–xPrxTi3O12 (x = 0.4, 0.8, 1.2, 1.6) Solid Solutions</title><title>Inorganic materials</title><addtitle>Inorg Mater</addtitle><description>—
Bi
4–
x
Pr
x
Ti
3
O
12
(
x
= 0.4, 0.8, 1.2, 1.6) solid solutions have been prepared by solid-state reactions, via multistep firing of stoichiometric mixtures of their constituent oxides in air at temperatures from 1003 to 1323 K. Their crystal structure has been determined using X-ray diffraction, and their luminescence spectra have been measured at room temperature. High-temperature heat capacity of polycrystalline substituted bismuth titanate samples has been determined by differential scanning calorimetry. The
C
p
(
T
) curves of the solid solutions with
x
= 0.4 and 0.8 have extrema related to phase transitions. Experimental data have been used to calculate the main thermodynamic functions of the solid solutions.</description><subject>Bismuth titanate</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>High temperature</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Mathematical analysis</subject><subject>Phase transitions</subject><subject>Room temperature</subject><subject>Solid solutions</subject><issn>0020-1685</issn><issn>1608-3172</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kM1Kw0AUhQdRsFYfwN2AG4Wk3vlJMlm40OIfFFpIBXdhMjO1U9qkziTQ7HwH39AnMaGCC3Fz7uJ851w4CJ0TGBHC-HUGQIHEIqIEUgD2eoAGJAYRMpLQQzTo7bD3j9GJ9ysA4JFIB6jN2rJeGm99gMeu9bVc46x2jaobZwIsS41ny9ZbVaml2VjV2TNXbY2rrfG4WuA7y78-Pnczt5tbNiUUX-7wDYYRDzoRASYj2kt8hbNqbXWvTW2r0p-io4Vce3P2c4fo5eF-Pn4KJ9PH5_HtJFSUx3VYaFAGtKRaJpoBF4zFqiBFpCDVaapEEmteCKaYYFwSQRIRx5AsJIs6SBI2RBf73q2r3hvj63xVNa7sXuY0SlJCecSijiJ7SrnKe2cW-dbZjXRtTiDvF87_LNxl6D7jO7Z8M-63-f_QN98Kef0</recordid><startdate>20210901</startdate><enddate>20210901</enddate><creator>Denisova, L. T.</creator><creator>Molokeev, M. S.</creator><creator>Kargin, Yu. F.</creator><creator>Gerasimov, V. P.</creator><creator>Krylov, A. S.</creator><creator>Aleksandrovskii, A. S.</creator><creator>Chumilina, L. G.</creator><creator>Denisov, V. M.</creator><creator>Vasil’ev, G. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210901</creationdate><title>Synthesis, Crystal Structure, and Physicochemical Properties of Bi4–xPrxTi3O12 (x = 0.4, 0.8, 1.2, 1.6) Solid Solutions</title><author>Denisova, L. T. ; Molokeev, M. S. ; Kargin, Yu. F. ; Gerasimov, V. P. ; Krylov, A. S. ; Aleksandrovskii, A. S. ; Chumilina, L. G. ; Denisov, V. M. ; Vasil’ev, G. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c246t-bd0ce0da2da7d3048336cb1b5c09d99c876d4b83c3834a181786607fa351b5a13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Bismuth titanate</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>High temperature</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><topic>Mathematical analysis</topic><topic>Phase transitions</topic><topic>Room temperature</topic><topic>Solid solutions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Denisova, L. T.</creatorcontrib><creatorcontrib>Molokeev, M. S.</creatorcontrib><creatorcontrib>Kargin, Yu. F.</creatorcontrib><creatorcontrib>Gerasimov, V. P.</creatorcontrib><creatorcontrib>Krylov, A. S.</creatorcontrib><creatorcontrib>Aleksandrovskii, A. S.</creatorcontrib><creatorcontrib>Chumilina, L. G.</creatorcontrib><creatorcontrib>Denisov, V. M.</creatorcontrib><creatorcontrib>Vasil’ev, G. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Inorganic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Denisova, L. T.</au><au>Molokeev, M. S.</au><au>Kargin, Yu. F.</au><au>Gerasimov, V. P.</au><au>Krylov, A. S.</au><au>Aleksandrovskii, A. S.</au><au>Chumilina, L. G.</au><au>Denisov, V. M.</au><au>Vasil’ev, G. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Crystal Structure, and Physicochemical Properties of Bi4–xPrxTi3O12 (x = 0.4, 0.8, 1.2, 1.6) Solid Solutions</atitle><jtitle>Inorganic materials</jtitle><stitle>Inorg Mater</stitle><date>2021-09-01</date><risdate>2021</risdate><volume>57</volume><issue>9</issue><spage>919</spage><epage>928</epage><pages>919-928</pages><issn>0020-1685</issn><eissn>1608-3172</eissn><abstract>—
Bi
4–
x
Pr
x
Ti
3
O
12
(
x
= 0.4, 0.8, 1.2, 1.6) solid solutions have been prepared by solid-state reactions, via multistep firing of stoichiometric mixtures of their constituent oxides in air at temperatures from 1003 to 1323 K. Their crystal structure has been determined using X-ray diffraction, and their luminescence spectra have been measured at room temperature. High-temperature heat capacity of polycrystalline substituted bismuth titanate samples has been determined by differential scanning calorimetry. The
C
p
(
T
) curves of the solid solutions with
x
= 0.4 and 0.8 have extrema related to phase transitions. Experimental data have been used to calculate the main thermodynamic functions of the solid solutions.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S002016852109003X</doi><tpages>10</tpages></addata></record> |
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| ispartof | Inorganic materials, 2021-09, Vol.57 (9), p.919-928 |
| issn | 0020-1685 1608-3172 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Bismuth titanate Chemistry Chemistry and Materials Science Crystal structure High temperature Industrial Chemistry/Chemical Engineering Inorganic Chemistry Materials Science Mathematical analysis Phase transitions Room temperature Solid solutions |
| title | Synthesis, Crystal Structure, and Physicochemical Properties of Bi4–xPrxTi3O12 (x = 0.4, 0.8, 1.2, 1.6) Solid Solutions |
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