Spectral and optical properties of Ruddlesden-Popper-type Ba3Zr2O7 phosphors doped with Eu3+ ion

This paper reports the spectroscopic investigation of Ba 3 Zr 2 O 7 phosphors. A series of Ba 3 Zr 2 O 7 : Eu 3+ with the different molar concentrations (0–4 mol.%) of europium (Eu 3+ ) ion is synthesized by the solution combustion method. The synthesized powders are characterized systematically usi...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2021-11, Vol.127 (11), Article 807
Hauptverfasser: Khajuria, Pooja, Mahajan, Rubby, Prakash, Ram, Choudhary, R. J., Phase, D. M.
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container_issue 11
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container_title Applied physics. A, Materials science & processing
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creator Khajuria, Pooja
Mahajan, Rubby
Prakash, Ram
Choudhary, R. J.
Phase, D. M.
description This paper reports the spectroscopic investigation of Ba 3 Zr 2 O 7 phosphors. A series of Ba 3 Zr 2 O 7 : Eu 3+ with the different molar concentrations (0–4 mol.%) of europium (Eu 3+ ) ion is synthesized by the solution combustion method. The synthesized powders are characterized systematically using X-ray diffraction, X-ray photoelectron spectroscopy, photoluminescence spectroscopy, and ultraviolet–visible spectroscopy. X-ray diffraction results indicate that the synthesized powder has a tetragonal crystal structure. X-ray photoelectron spectroscopy is used to study the elemental composition of the synthesized phosphor. Field emission scanning electron microscopy result reveals that non-uniform morphology is formed. Photoluminescence spectroscopy result shows several emission peaks due to electronic transitions of Eu 3+ ion, and the dominant peak is observed at 613 nm due to electric dipole transition 5 D 0  →  7 F 2 . CIE coordinates of Eu 3+ -activated Ba 3 Zr 2 O 7 phosphor is found to be ( x  = 0.64, y  = 0.36) which gives bright red emission. The optical band gap of the phosphors is obtained from the diffuse reflectance spectrum and found in the range of 4.62–4.83 eV.
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Photoluminescence spectroscopy result shows several emission peaks due to electronic transitions of Eu 3+ ion, and the dominant peak is observed at 613 nm due to electric dipole transition 5 D 0  →  7 F 2 . CIE coordinates of Eu 3+ -activated Ba 3 Zr 2 O 7 phosphor is found to be ( x  = 0.64, y  = 0.36) which gives bright red emission. 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Field emission scanning electron microscopy result reveals that non-uniform morphology is formed. Photoluminescence spectroscopy result shows several emission peaks due to electronic transitions of Eu 3+ ion, and the dominant peak is observed at 613 nm due to electric dipole transition 5 D 0  →  7 F 2 . CIE coordinates of Eu 3+ -activated Ba 3 Zr 2 O 7 phosphor is found to be ( x  = 0.64, y  = 0.36) which gives bright red emission. 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J.</creatorcontrib><creatorcontrib>Phase, D. M.</creatorcontrib><collection>CrossRef</collection><jtitle>Applied physics. A, Materials science &amp; processing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khajuria, Pooja</au><au>Mahajan, Rubby</au><au>Prakash, Ram</au><au>Choudhary, R. J.</au><au>Phase, D. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Spectral and optical properties of Ruddlesden-Popper-type Ba3Zr2O7 phosphors doped with Eu3+ ion</atitle><jtitle>Applied physics. A, Materials science &amp; processing</jtitle><stitle>Appl. Phys. A</stitle><date>2021-11-01</date><risdate>2021</risdate><volume>127</volume><issue>11</issue><artnum>807</artnum><issn>0947-8396</issn><eissn>1432-0630</eissn><abstract>This paper reports the spectroscopic investigation of Ba 3 Zr 2 O 7 phosphors. A series of Ba 3 Zr 2 O 7 : Eu 3+ with the different molar concentrations (0–4 mol.%) of europium (Eu 3+ ) ion is synthesized by the solution combustion method. The synthesized powders are characterized systematically using X-ray diffraction, X-ray photoelectron spectroscopy, photoluminescence spectroscopy, and ultraviolet–visible spectroscopy. X-ray diffraction results indicate that the synthesized powder has a tetragonal crystal structure. X-ray photoelectron spectroscopy is used to study the elemental composition of the synthesized phosphor. Field emission scanning electron microscopy result reveals that non-uniform morphology is formed. Photoluminescence spectroscopy result shows several emission peaks due to electronic transitions of Eu 3+ ion, and the dominant peak is observed at 613 nm due to electric dipole transition 5 D 0  →  7 F 2 . CIE coordinates of Eu 3+ -activated Ba 3 Zr 2 O 7 phosphor is found to be ( x  = 0.64, y  = 0.36) which gives bright red emission. 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subjects Applied physics
Characterization and Evaluation of Materials
Chemical synthesis
Condensed Matter Physics
Crystal structure
Electric dipoles
Electron transitions
Emission analysis
Europium
Field emission microscopy
Machines
Manufacturing
Materials science
Morphology
Nanotechnology
Optical and Electronic Materials
Optical properties
Phosphors
Photoelectron spectroscopy
Photoelectrons
Photoluminescence
Physics
Physics and Astronomy
Processes
Spectrum analysis
Surfaces and Interfaces
Thin Films
X ray photoelectron spectroscopy
X-ray diffraction
title Spectral and optical properties of Ruddlesden-Popper-type Ba3Zr2O7 phosphors doped with Eu3+ ion
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