Spectral and optical properties of Ruddlesden-Popper-type Ba3Zr2O7 phosphors doped with Eu3+ ion
This paper reports the spectroscopic investigation of Ba 3 Zr 2 O 7 phosphors. A series of Ba 3 Zr 2 O 7 : Eu 3+ with the different molar concentrations (0–4 mol.%) of europium (Eu 3+ ) ion is synthesized by the solution combustion method. The synthesized powders are characterized systematically usi...
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creator | Khajuria, Pooja Mahajan, Rubby Prakash, Ram Choudhary, R. J. Phase, D. M. |
description | This paper reports the spectroscopic investigation of Ba
3
Zr
2
O
7
phosphors. A series of Ba
3
Zr
2
O
7
: Eu
3+
with the different molar concentrations (0–4 mol.%) of europium (Eu
3+
) ion is synthesized by the solution combustion method. The synthesized powders are characterized systematically using X-ray diffraction, X-ray photoelectron spectroscopy, photoluminescence spectroscopy, and ultraviolet–visible spectroscopy. X-ray diffraction results indicate that the synthesized powder has a tetragonal crystal structure. X-ray photoelectron spectroscopy is used to study the elemental composition of the synthesized phosphor. Field emission scanning electron microscopy result reveals that non-uniform morphology is formed. Photoluminescence spectroscopy result shows several emission peaks due to electronic transitions of Eu
3+
ion, and the dominant peak is observed at 613 nm due to electric dipole transition
5
D
0
→
7
F
2
. CIE coordinates of Eu
3+
-activated Ba
3
Zr
2
O
7
phosphor is found to be (
x
= 0.64,
y
= 0.36) which gives bright red emission. The optical band gap of the phosphors is obtained from the diffuse reflectance spectrum and found in the range of 4.62–4.83 eV. |
doi_str_mv | 10.1007/s00339-021-04956-1 |
format | Article |
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3
Zr
2
O
7
phosphors. A series of Ba
3
Zr
2
O
7
: Eu
3+
with the different molar concentrations (0–4 mol.%) of europium (Eu
3+
) ion is synthesized by the solution combustion method. The synthesized powders are characterized systematically using X-ray diffraction, X-ray photoelectron spectroscopy, photoluminescence spectroscopy, and ultraviolet–visible spectroscopy. X-ray diffraction results indicate that the synthesized powder has a tetragonal crystal structure. X-ray photoelectron spectroscopy is used to study the elemental composition of the synthesized phosphor. Field emission scanning electron microscopy result reveals that non-uniform morphology is formed. Photoluminescence spectroscopy result shows several emission peaks due to electronic transitions of Eu
3+
ion, and the dominant peak is observed at 613 nm due to electric dipole transition
5
D
0
→
7
F
2
. CIE coordinates of Eu
3+
-activated Ba
3
Zr
2
O
7
phosphor is found to be (
x
= 0.64,
y
= 0.36) which gives bright red emission. The optical band gap of the phosphors is obtained from the diffuse reflectance spectrum and found in the range of 4.62–4.83 eV.</description><identifier>ISSN: 0947-8396</identifier><identifier>EISSN: 1432-0630</identifier><identifier>DOI: 10.1007/s00339-021-04956-1</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Applied physics ; Characterization and Evaluation of Materials ; Chemical synthesis ; Condensed Matter Physics ; Crystal structure ; Electric dipoles ; Electron transitions ; Emission analysis ; Europium ; Field emission microscopy ; Machines ; Manufacturing ; Materials science ; Morphology ; Nanotechnology ; Optical and Electronic Materials ; Optical properties ; Phosphors ; Photoelectron spectroscopy ; Photoelectrons ; Photoluminescence ; Physics ; Physics and Astronomy ; Processes ; Spectrum analysis ; Surfaces and Interfaces ; Thin Films ; X ray photoelectron spectroscopy ; X-ray diffraction</subject><ispartof>Applied physics. A, Materials science & processing, 2021-11, Vol.127 (11), Article 807</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-a3aa439d10b23934b389c01a070c382c376f4ad132c8826593b7d33ab390b6b13</citedby><cites>FETCH-LOGICAL-c249t-a3aa439d10b23934b389c01a070c382c376f4ad132c8826593b7d33ab390b6b13</cites><orcidid>0000-0001-8075-1872</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00339-021-04956-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00339-021-04956-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Khajuria, Pooja</creatorcontrib><creatorcontrib>Mahajan, Rubby</creatorcontrib><creatorcontrib>Prakash, Ram</creatorcontrib><creatorcontrib>Choudhary, R. J.</creatorcontrib><creatorcontrib>Phase, D. M.</creatorcontrib><title>Spectral and optical properties of Ruddlesden-Popper-type Ba3Zr2O7 phosphors doped with Eu3+ ion</title><title>Applied physics. A, Materials science & processing</title><addtitle>Appl. Phys. A</addtitle><description>This paper reports the spectroscopic investigation of Ba
3
Zr
2
O
7
phosphors. A series of Ba
3
Zr
2
O
7
: Eu
3+
with the different molar concentrations (0–4 mol.%) of europium (Eu
3+
) ion is synthesized by the solution combustion method. The synthesized powders are characterized systematically using X-ray diffraction, X-ray photoelectron spectroscopy, photoluminescence spectroscopy, and ultraviolet–visible spectroscopy. X-ray diffraction results indicate that the synthesized powder has a tetragonal crystal structure. X-ray photoelectron spectroscopy is used to study the elemental composition of the synthesized phosphor. Field emission scanning electron microscopy result reveals that non-uniform morphology is formed. Photoluminescence spectroscopy result shows several emission peaks due to electronic transitions of Eu
3+
ion, and the dominant peak is observed at 613 nm due to electric dipole transition
5
D
0
→
7
F
2
. CIE coordinates of Eu
3+
-activated Ba
3
Zr
2
O
7
phosphor is found to be (
x
= 0.64,
y
= 0.36) which gives bright red emission. The optical band gap of the phosphors is obtained from the diffuse reflectance spectrum and found in the range of 4.62–4.83 eV.</description><subject>Applied physics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical synthesis</subject><subject>Condensed Matter Physics</subject><subject>Crystal structure</subject><subject>Electric dipoles</subject><subject>Electron transitions</subject><subject>Emission analysis</subject><subject>Europium</subject><subject>Field emission microscopy</subject><subject>Machines</subject><subject>Manufacturing</subject><subject>Materials science</subject><subject>Morphology</subject><subject>Nanotechnology</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Phosphors</subject><subject>Photoelectron spectroscopy</subject><subject>Photoelectrons</subject><subject>Photoluminescence</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Processes</subject><subject>Spectrum analysis</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>X ray photoelectron spectroscopy</subject><subject>X-ray diffraction</subject><issn>0947-8396</issn><issn>1432-0630</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKt_wFPAo0Qnmf3KUUv9gELFj4uXmE2ydkvdXZNdpP_e1BW8OTDMwLzPzPAScsrhggPklwEAUTIQnEEi04zxPTLhCQoGGcI-mYBMclagzA7JUQhriJEIMSFvT50zvdcbqhtL266vTew733bO97ULtK3o42DtxgXrGvbQdnHA-m3n6LXGVy-WOe1WbYjpA7URs_Sr7ld0PuA5rdvmmBxUehPcyW-dkpeb-fPsji2Wt_ezqwUzIpE906h1gtJyKAVKTEospAGuIQeDhTCYZ1WiLUdhikJkqcQyt4i6RAllVnKckrNxb_z9c3ChV-t28E08qUSaF0XKJexUYlQZ34bgXaU6X39ov1Uc1M5JNTqpopPqx0m1g3CEQhQ3787_rf6H-gYI93T3</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Khajuria, Pooja</creator><creator>Mahajan, Rubby</creator><creator>Prakash, Ram</creator><creator>Choudhary, R. J.</creator><creator>Phase, D. M.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-8075-1872</orcidid></search><sort><creationdate>20211101</creationdate><title>Spectral and optical properties of Ruddlesden-Popper-type Ba3Zr2O7 phosphors doped with Eu3+ ion</title><author>Khajuria, Pooja ; Mahajan, Rubby ; Prakash, Ram ; Choudhary, R. J. ; Phase, D. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-a3aa439d10b23934b389c01a070c382c376f4ad132c8826593b7d33ab390b6b13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Applied physics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical synthesis</topic><topic>Condensed Matter Physics</topic><topic>Crystal structure</topic><topic>Electric dipoles</topic><topic>Electron transitions</topic><topic>Emission analysis</topic><topic>Europium</topic><topic>Field emission microscopy</topic><topic>Machines</topic><topic>Manufacturing</topic><topic>Materials science</topic><topic>Morphology</topic><topic>Nanotechnology</topic><topic>Optical and Electronic Materials</topic><topic>Optical properties</topic><topic>Phosphors</topic><topic>Photoelectron spectroscopy</topic><topic>Photoelectrons</topic><topic>Photoluminescence</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Processes</topic><topic>Spectrum analysis</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><topic>X ray photoelectron spectroscopy</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khajuria, Pooja</creatorcontrib><creatorcontrib>Mahajan, Rubby</creatorcontrib><creatorcontrib>Prakash, Ram</creatorcontrib><creatorcontrib>Choudhary, R. J.</creatorcontrib><creatorcontrib>Phase, D. M.</creatorcontrib><collection>CrossRef</collection><jtitle>Applied physics. A, Materials science & processing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khajuria, Pooja</au><au>Mahajan, Rubby</au><au>Prakash, Ram</au><au>Choudhary, R. J.</au><au>Phase, D. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Spectral and optical properties of Ruddlesden-Popper-type Ba3Zr2O7 phosphors doped with Eu3+ ion</atitle><jtitle>Applied physics. A, Materials science & processing</jtitle><stitle>Appl. Phys. A</stitle><date>2021-11-01</date><risdate>2021</risdate><volume>127</volume><issue>11</issue><artnum>807</artnum><issn>0947-8396</issn><eissn>1432-0630</eissn><abstract>This paper reports the spectroscopic investigation of Ba
3
Zr
2
O
7
phosphors. A series of Ba
3
Zr
2
O
7
: Eu
3+
with the different molar concentrations (0–4 mol.%) of europium (Eu
3+
) ion is synthesized by the solution combustion method. The synthesized powders are characterized systematically using X-ray diffraction, X-ray photoelectron spectroscopy, photoluminescence spectroscopy, and ultraviolet–visible spectroscopy. X-ray diffraction results indicate that the synthesized powder has a tetragonal crystal structure. X-ray photoelectron spectroscopy is used to study the elemental composition of the synthesized phosphor. Field emission scanning electron microscopy result reveals that non-uniform morphology is formed. Photoluminescence spectroscopy result shows several emission peaks due to electronic transitions of Eu
3+
ion, and the dominant peak is observed at 613 nm due to electric dipole transition
5
D
0
→
7
F
2
. CIE coordinates of Eu
3+
-activated Ba
3
Zr
2
O
7
phosphor is found to be (
x
= 0.64,
y
= 0.36) which gives bright red emission. The optical band gap of the phosphors is obtained from the diffuse reflectance spectrum and found in the range of 4.62–4.83 eV.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00339-021-04956-1</doi><orcidid>https://orcid.org/0000-0001-8075-1872</orcidid></addata></record> |
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source | SpringerLink Journals - AutoHoldings |
subjects | Applied physics Characterization and Evaluation of Materials Chemical synthesis Condensed Matter Physics Crystal structure Electric dipoles Electron transitions Emission analysis Europium Field emission microscopy Machines Manufacturing Materials science Morphology Nanotechnology Optical and Electronic Materials Optical properties Phosphors Photoelectron spectroscopy Photoelectrons Photoluminescence Physics Physics and Astronomy Processes Spectrum analysis Surfaces and Interfaces Thin Films X ray photoelectron spectroscopy X-ray diffraction |
title | Spectral and optical properties of Ruddlesden-Popper-type Ba3Zr2O7 phosphors doped with Eu3+ ion |
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