Vibrational Fano resonances in the photodetachment of dipole-bound anions
A simple model for the photodetachment of dipole-bound anions is proposed where non-adiabatic coupling of vibrational states leads to a Fano resonance in the spectrum. It is found that the shape of the photodetachment spectrum depends significantly on the parameter representing molecular polarizabil...
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| Veröffentlicht in: | Journal of physics. Conference series 2012-11, Vol.388 (2), p.22014 |
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| container_issue | 2 |
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| container_title | Journal of physics. Conference series |
| container_volume | 388 |
| creator | Edwards, Stephen T Tully, John C Johnson, Mark A |
| description | A simple model for the photodetachment of dipole-bound anions is proposed where non-adiabatic coupling of vibrational states leads to a Fano resonance in the spectrum. It is found that the shape of the photodetachment spectrum depends significantly on the parameter representing molecular polarizability. The model is also applied to a Fano profile observed in the photodetachment of small water cluster anions. |
| doi_str_mv | 10.1088/1742-6596/388/2/022014 |
| format | Article |
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| ispartof | Journal of physics. Conference series, 2012-11, Vol.388 (2), p.22014 |
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| subjects | Anions Coupling (molecular) Dipoles Fano resonance Photodetachment Physics Vibrational states |
| title | Vibrational Fano resonances in the photodetachment of dipole-bound anions |
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