B-N bond formation through palladium-catalyzed, microwave-assisted cross-coupling of nitrogen compounds with iodo-dodecaborate

Substituted undecahydrido- closo -dodecaborates [B 12 H 11 NR 2 ] 2− have potential use in materials and drugs, but have presented a synthetic challenge. Microwave-assisted palladium-catalyzed amination of iodo-dodecaborate [B 12 H 11 I] 2− allows mild and reproducible formation of B-N bonds with ar...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2021-09, Vol.57 (78), p.17-11
Hauptverfasser:	Al-Joumhawy, Mahmoud K, Marei, Tarek, Shmalko, Akim, Cendoya, Paula, La Borde, Jair, Gabel, Detlef
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides Amines Aniline Coupling (molecular) Cross coupling Nitrogen compounds Palladium Substitution reactions
Online-Zugang:	Volltext
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