Chemical composition and antioxidant activity of oil obtained from coconut meal by subcritical ethanol extraction

This work aimed to evaluate the efficiency of subcritical ethanol extraction for recovering oil from coconut meal. Dried coconut meal with an oil content of 19.85% (w.b.) was treated with subcritical ethanol at various ethanol concentrations (80, 90, and 100% v/v), solvent to solid ratios (5:1, 8:1,...

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Veröffentlicht in:Journal of food measurement & characterization 2021-10, Vol.15 (5), p.4128-4137
Hauptverfasser: Plangklang, Thussanee, Khuwijitjaru, Pramote, Klinchongkon, Khwanjai, Adachi, Shuji
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container_issue 5
container_start_page 4128
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creator Plangklang, Thussanee
Khuwijitjaru, Pramote
Klinchongkon, Khwanjai
Adachi, Shuji
description This work aimed to evaluate the efficiency of subcritical ethanol extraction for recovering oil from coconut meal. Dried coconut meal with an oil content of 19.85% (w.b.) was treated with subcritical ethanol at various ethanol concentrations (80, 90, and 100% v/v), solvent to solid ratios (5:1, 8:1, 10:1, and 15:1 v/w), temperatures (80, 100, and 120 °C), and holding times (0, 15, 30, and 45 min) in a batch-type vessel. The highest oil recovery (81.49%), which was obtained from the extraction with 100% ethanol and solvent-solid ratio of 8:1 (v/w) at 100 °C for 45 min did not significantly differ from those obtained at 120 °C for 15–45 min. The chemical properties, including free fatty acid content, peroxide value, saponification value, unsaponifiable matter, and fatty acid profile of the oils conformed to the standard values for crude coconut oil. Gas chromatography showed the higher ratios of caprylic and capric acids in the subcritical ethanol-extracted oils than those in hexane extracted oil, approximately 1.05–1.4 times. Additionally, the total phenolic content and 2,2-diphenyl-1-picrylhydrazyl radical-scavenging activity of the oils extracted with the subcritical ethanol extraction were significantly higher (up to 3.5 and 6 times, respectively) than those of the oil Soxhlet-extracted with hexane. The present study showed that subcritical ethanol extraction is an effective method for extracting oil with good qualities and antioxidant properties from coconut meal.
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Dried coconut meal with an oil content of 19.85% (w.b.) was treated with subcritical ethanol at various ethanol concentrations (80, 90, and 100% v/v), solvent to solid ratios (5:1, 8:1, 10:1, and 15:1 v/w), temperatures (80, 100, and 120 °C), and holding times (0, 15, 30, and 45 min) in a batch-type vessel. The highest oil recovery (81.49%), which was obtained from the extraction with 100% ethanol and solvent-solid ratio of 8:1 (v/w) at 100 °C for 45 min did not significantly differ from those obtained at 120 °C for 15–45 min. The chemical properties, including free fatty acid content, peroxide value, saponification value, unsaponifiable matter, and fatty acid profile of the oils conformed to the standard values for crude coconut oil. Gas chromatography showed the higher ratios of caprylic and capric acids in the subcritical ethanol-extracted oils than those in hexane extracted oil, approximately 1.05–1.4 times. Additionally, the total phenolic content and 2,2-diphenyl-1-picrylhydrazyl radical-scavenging activity of the oils extracted with the subcritical ethanol extraction were significantly higher (up to 3.5 and 6 times, respectively) than those of the oil Soxhlet-extracted with hexane. 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Dried coconut meal with an oil content of 19.85% (w.b.) was treated with subcritical ethanol at various ethanol concentrations (80, 90, and 100% v/v), solvent to solid ratios (5:1, 8:1, 10:1, and 15:1 v/w), temperatures (80, 100, and 120 °C), and holding times (0, 15, 30, and 45 min) in a batch-type vessel. The highest oil recovery (81.49%), which was obtained from the extraction with 100% ethanol and solvent-solid ratio of 8:1 (v/w) at 100 °C for 45 min did not significantly differ from those obtained at 120 °C for 15–45 min. The chemical properties, including free fatty acid content, peroxide value, saponification value, unsaponifiable matter, and fatty acid profile of the oils conformed to the standard values for crude coconut oil. Gas chromatography showed the higher ratios of caprylic and capric acids in the subcritical ethanol-extracted oils than those in hexane extracted oil, approximately 1.05–1.4 times. 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subjects Antioxidants
Chemical composition
Chemical properties
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Coconut oil
Engineering
Ethanol
Fatty acids
Food Science
Gas chromatography
Hexanes
Oil recovery
Original Paper
Phenolic compounds
Phenols
Scavenging
Solvents
title Chemical composition and antioxidant activity of oil obtained from coconut meal by subcritical ethanol extraction
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