Synthesis of indium tin oxide films from ethyl acetoacetonato complexes at low temperatures
A novel recycling system for indium in indium tin oxide (ITO), which comprises the dissolution of indium oxide (In 2 O 3 ), chlorination, chelation, and steaming treatment, was established. Indium trichloride (InCl 3 ) was quantitatively synthesized by the reaction of In 2 O 3 with hydrochloric acid...
Gespeichert in:
| Veröffentlicht in: | Journal of sol-gel science and technology 2021-10, Vol.100 (1), p.68-73 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 73 |
|---|---|
| container_issue | 1 |
| container_start_page | 68 |
| container_title | Journal of sol-gel science and technology |
| container_volume | 100 |
| creator | Gunji, Takahiro Nakamura, Kotoe Hayami, Ryohei Aimi, Akihisa Fujimoto, Kenjiro Yamamoto, Kazuki |
| description | A novel recycling system for indium in indium tin oxide (ITO), which comprises the dissolution of indium oxide (In
2
O
3
), chlorination, chelation, and steaming treatment, was established. Indium trichloride (InCl
3
) was quantitatively synthesized by the reaction of In
2
O
3
with hydrochloric acid (HCl) and furnished tris(ethyl acetoacetato)indium (In(etac)
3
) in a high yield by a subsequent reaction with ethyl acetoacetate (Hetac). In(etac)
3
was mixed with bis(acetylacetonato)tin dichloride (Sn(acac)
2
Cl
2
) and spin coated on a glass plate, followed by steaming and heating to obtain ITO films containing 10 wt% tin oxide. In
2
O
3
was crystallized in c-, rh-, and o-In
2
O
3
. This film showed a resistivity of 9.7 Ωcm and a transparency of 86%.
Highlights
ITO films were prepared from In(etac)
3
and Sn(acac)
2
Cl
2
.
Steaming and heating treatments were performed to remove organic ligands.
In
2
O
3
was recycled by chlorination, chelation, and heating. |
| doi_str_mv | 10.1007/s10971-021-05618-7 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2575651785</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2575651785</sourcerecordid><originalsourceid>FETCH-LOGICAL-c385t-2fb95280f4374814e4067c3ac02329380d9881976de9576e69acb386bd4a4e933</originalsourceid><addsrcrecordid>eNp9kMtKw0AUhgdRsFZfwNWA6-jcL0sp3qDgQl25GKbJiU1JMnVmgu3bGxvBnYtzzub7_wMfQpeUXFNC9E2ixGpaEDaOVNQU-gjNqNS8EEaoYzQjlpmCaKJP0VlKG0KIFFTP0PvLvs9rSE3CocZNXzVDh3PT47BrKsB103YJ1zF0GPJ632JfQg6H1fsccBm6bQs7SNhn3IYvnKHbQvR5iJDO0Unt2wQXv3eO3u7vXhePxfL54WlxuyxKbmQuWL2ykhlSC66FoQIEUbrkviSMM8sNqawx1GpVgZVagbK-XHGjVpXwAiznc3Q19W5j-BwgZbcJQ-zHl45JLZWk2siRYhNVxpBShNptY9P5uHeUuB-JbpLoRonuINHpMcSnUBrh_gPiX_U_qW8uNXT1</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2575651785</pqid></control><display><type>article</type><title>Synthesis of indium tin oxide films from ethyl acetoacetonato complexes at low temperatures</title><source>SpringerLink (Online service)</source><creator>Gunji, Takahiro ; Nakamura, Kotoe ; Hayami, Ryohei ; Aimi, Akihisa ; Fujimoto, Kenjiro ; Yamamoto, Kazuki</creator><creatorcontrib>Gunji, Takahiro ; Nakamura, Kotoe ; Hayami, Ryohei ; Aimi, Akihisa ; Fujimoto, Kenjiro ; Yamamoto, Kazuki</creatorcontrib><description>A novel recycling system for indium in indium tin oxide (ITO), which comprises the dissolution of indium oxide (In
2
O
3
), chlorination, chelation, and steaming treatment, was established. Indium trichloride (InCl
3
) was quantitatively synthesized by the reaction of In
2
O
3
with hydrochloric acid (HCl) and furnished tris(ethyl acetoacetato)indium (In(etac)
3
) in a high yield by a subsequent reaction with ethyl acetoacetate (Hetac). In(etac)
3
was mixed with bis(acetylacetonato)tin dichloride (Sn(acac)
2
Cl
2
) and spin coated on a glass plate, followed by steaming and heating to obtain ITO films containing 10 wt% tin oxide. In
2
O
3
was crystallized in c-, rh-, and o-In
2
O
3
. This film showed a resistivity of 9.7 Ωcm and a transparency of 86%.
Highlights
ITO films were prepared from In(etac)
3
and Sn(acac)
2
Cl
2
.
Steaming and heating treatments were performed to remove organic ligands.
In
2
O
3
was recycled by chlorination, chelation, and heating.</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-021-05618-7</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Ceramics ; Chelation ; Chemical synthesis ; Chemistry and Materials Science ; Chlorides ; Chlorination ; Composites ; Crystallization ; Dichlorides ; Glass ; Glass plates ; Heating ; Hydrochloric acid ; Indium oxides ; Indium tin oxides ; Inorganic Chemistry ; Low temperature ; Materials Science ; Nanotechnology ; Natural Materials ; Optical and Electronic Materials ; Original Paper: Fundamentals of sol-gel and hybrid materials processing ; Oxide coatings ; Steaming ; Tin</subject><ispartof>Journal of sol-gel science and technology, 2021-10, Vol.100 (1), p.68-73</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c385t-2fb95280f4374814e4067c3ac02329380d9881976de9576e69acb386bd4a4e933</citedby><cites>FETCH-LOGICAL-c385t-2fb95280f4374814e4067c3ac02329380d9881976de9576e69acb386bd4a4e933</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10971-021-05618-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10971-021-05618-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Gunji, Takahiro</creatorcontrib><creatorcontrib>Nakamura, Kotoe</creatorcontrib><creatorcontrib>Hayami, Ryohei</creatorcontrib><creatorcontrib>Aimi, Akihisa</creatorcontrib><creatorcontrib>Fujimoto, Kenjiro</creatorcontrib><creatorcontrib>Yamamoto, Kazuki</creatorcontrib><title>Synthesis of indium tin oxide films from ethyl acetoacetonato complexes at low temperatures</title><title>Journal of sol-gel science and technology</title><addtitle>J Sol-Gel Sci Technol</addtitle><description>A novel recycling system for indium in indium tin oxide (ITO), which comprises the dissolution of indium oxide (In
2
O
3
), chlorination, chelation, and steaming treatment, was established. Indium trichloride (InCl
3
) was quantitatively synthesized by the reaction of In
2
O
3
with hydrochloric acid (HCl) and furnished tris(ethyl acetoacetato)indium (In(etac)
3
) in a high yield by a subsequent reaction with ethyl acetoacetate (Hetac). In(etac)
3
was mixed with bis(acetylacetonato)tin dichloride (Sn(acac)
2
Cl
2
) and spin coated on a glass plate, followed by steaming and heating to obtain ITO films containing 10 wt% tin oxide. In
2
O
3
was crystallized in c-, rh-, and o-In
2
O
3
. This film showed a resistivity of 9.7 Ωcm and a transparency of 86%.
Highlights
ITO films were prepared from In(etac)
3
and Sn(acac)
2
Cl
2
.
Steaming and heating treatments were performed to remove organic ligands.
In
2
O
3
was recycled by chlorination, chelation, and heating.</description><subject>Ceramics</subject><subject>Chelation</subject><subject>Chemical synthesis</subject><subject>Chemistry and Materials Science</subject><subject>Chlorides</subject><subject>Chlorination</subject><subject>Composites</subject><subject>Crystallization</subject><subject>Dichlorides</subject><subject>Glass</subject><subject>Glass plates</subject><subject>Heating</subject><subject>Hydrochloric acid</subject><subject>Indium oxides</subject><subject>Indium tin oxides</subject><subject>Inorganic Chemistry</subject><subject>Low temperature</subject><subject>Materials Science</subject><subject>Nanotechnology</subject><subject>Natural Materials</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper: Fundamentals of sol-gel and hybrid materials processing</subject><subject>Oxide coatings</subject><subject>Steaming</subject><subject>Tin</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kMtKw0AUhgdRsFZfwNWA6-jcL0sp3qDgQl25GKbJiU1JMnVmgu3bGxvBnYtzzub7_wMfQpeUXFNC9E2ixGpaEDaOVNQU-gjNqNS8EEaoYzQjlpmCaKJP0VlKG0KIFFTP0PvLvs9rSE3CocZNXzVDh3PT47BrKsB103YJ1zF0GPJ632JfQg6H1fsccBm6bQs7SNhn3IYvnKHbQvR5iJDO0Unt2wQXv3eO3u7vXhePxfL54WlxuyxKbmQuWL2ykhlSC66FoQIEUbrkviSMM8sNqawx1GpVgZVagbK-XHGjVpXwAiznc3Q19W5j-BwgZbcJQ-zHl45JLZWk2siRYhNVxpBShNptY9P5uHeUuB-JbpLoRonuINHpMcSnUBrh_gPiX_U_qW8uNXT1</recordid><startdate>20211001</startdate><enddate>20211001</enddate><creator>Gunji, Takahiro</creator><creator>Nakamura, Kotoe</creator><creator>Hayami, Ryohei</creator><creator>Aimi, Akihisa</creator><creator>Fujimoto, Kenjiro</creator><creator>Yamamoto, Kazuki</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20211001</creationdate><title>Synthesis of indium tin oxide films from ethyl acetoacetonato complexes at low temperatures</title><author>Gunji, Takahiro ; Nakamura, Kotoe ; Hayami, Ryohei ; Aimi, Akihisa ; Fujimoto, Kenjiro ; Yamamoto, Kazuki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c385t-2fb95280f4374814e4067c3ac02329380d9881976de9576e69acb386bd4a4e933</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Ceramics</topic><topic>Chelation</topic><topic>Chemical synthesis</topic><topic>Chemistry and Materials Science</topic><topic>Chlorides</topic><topic>Chlorination</topic><topic>Composites</topic><topic>Crystallization</topic><topic>Dichlorides</topic><topic>Glass</topic><topic>Glass plates</topic><topic>Heating</topic><topic>Hydrochloric acid</topic><topic>Indium oxides</topic><topic>Indium tin oxides</topic><topic>Inorganic Chemistry</topic><topic>Low temperature</topic><topic>Materials Science</topic><topic>Nanotechnology</topic><topic>Natural Materials</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper: Fundamentals of sol-gel and hybrid materials processing</topic><topic>Oxide coatings</topic><topic>Steaming</topic><topic>Tin</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gunji, Takahiro</creatorcontrib><creatorcontrib>Nakamura, Kotoe</creatorcontrib><creatorcontrib>Hayami, Ryohei</creatorcontrib><creatorcontrib>Aimi, Akihisa</creatorcontrib><creatorcontrib>Fujimoto, Kenjiro</creatorcontrib><creatorcontrib>Yamamoto, Kazuki</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>ProQuest Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering collection</collection><jtitle>Journal of sol-gel science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gunji, Takahiro</au><au>Nakamura, Kotoe</au><au>Hayami, Ryohei</au><au>Aimi, Akihisa</au><au>Fujimoto, Kenjiro</au><au>Yamamoto, Kazuki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of indium tin oxide films from ethyl acetoacetonato complexes at low temperatures</atitle><jtitle>Journal of sol-gel science and technology</jtitle><stitle>J Sol-Gel Sci Technol</stitle><date>2021-10-01</date><risdate>2021</risdate><volume>100</volume><issue>1</issue><spage>68</spage><epage>73</epage><pages>68-73</pages><issn>0928-0707</issn><eissn>1573-4846</eissn><abstract>A novel recycling system for indium in indium tin oxide (ITO), which comprises the dissolution of indium oxide (In
2
O
3
), chlorination, chelation, and steaming treatment, was established. Indium trichloride (InCl
3
) was quantitatively synthesized by the reaction of In
2
O
3
with hydrochloric acid (HCl) and furnished tris(ethyl acetoacetato)indium (In(etac)
3
) in a high yield by a subsequent reaction with ethyl acetoacetate (Hetac). In(etac)
3
was mixed with bis(acetylacetonato)tin dichloride (Sn(acac)
2
Cl
2
) and spin coated on a glass plate, followed by steaming and heating to obtain ITO films containing 10 wt% tin oxide. In
2
O
3
was crystallized in c-, rh-, and o-In
2
O
3
. This film showed a resistivity of 9.7 Ωcm and a transparency of 86%.
Highlights
ITO films were prepared from In(etac)
3
and Sn(acac)
2
Cl
2
.
Steaming and heating treatments were performed to remove organic ligands.
In
2
O
3
was recycled by chlorination, chelation, and heating.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10971-021-05618-7</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0928-0707 |
| ispartof | Journal of sol-gel science and technology, 2021-10, Vol.100 (1), p.68-73 |
| issn | 0928-0707 1573-4846 |
| language | eng |
| recordid | cdi_proquest_journals_2575651785 |
| source | SpringerLink (Online service) |
| subjects | Ceramics Chelation Chemical synthesis Chemistry and Materials Science Chlorides Chlorination Composites Crystallization Dichlorides Glass Glass plates Heating Hydrochloric acid Indium oxides Indium tin oxides Inorganic Chemistry Low temperature Materials Science Nanotechnology Natural Materials Optical and Electronic Materials Original Paper: Fundamentals of sol-gel and hybrid materials processing Oxide coatings Steaming Tin |
| title | Synthesis of indium tin oxide films from ethyl acetoacetonato complexes at low temperatures |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-29T07%3A59%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20indium%20tin%20oxide%20films%20from%20ethyl%20acetoacetonato%20complexes%20at%20low%20temperatures&rft.jtitle=Journal%20of%20sol-gel%20science%20and%20technology&rft.au=Gunji,%20Takahiro&rft.date=2021-10-01&rft.volume=100&rft.issue=1&rft.spage=68&rft.epage=73&rft.pages=68-73&rft.issn=0928-0707&rft.eissn=1573-4846&rft_id=info:doi/10.1007/s10971-021-05618-7&rft_dat=%3Cproquest_cross%3E2575651785%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2575651785&rft_id=info:pmid/&rfr_iscdi=true |