Hydrogen-rich syngas production from chemical looping gasification of lignite by using NiFe2O4 and CuFe2O4 as oxygen carriers

•Chemical looping gasification of lignite was promoted by NiFe2O4 and CuFe2O4.•Pure cubic spinel structure is beneficial for the mobility of lattice oxygen.•NiFe2O4 exhibits the highest gas yield of 24.47 mol/kg during lignite gasification.•1.65 times increase of total syngas yield was obtained by a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Fuel (Guildford) 2021-11, Vol.303, p.121269, Article 121269
Hauptverfasser: Zhao, Kun, Fang, Xiaojie, Huang, Zhen, Wei, Guoqiang, Zheng, Anqing, Zhao, Zengli
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue
container_start_page 121269
container_title Fuel (Guildford)
container_volume 303
creator Zhao, Kun
Fang, Xiaojie
Huang, Zhen
Wei, Guoqiang
Zheng, Anqing
Zhao, Zengli
description •Chemical looping gasification of lignite was promoted by NiFe2O4 and CuFe2O4.•Pure cubic spinel structure is beneficial for the mobility of lattice oxygen.•NiFe2O4 exhibits the highest gas yield of 24.47 mol/kg during lignite gasification.•1.65 times increase of total syngas yield was obtained by addition of steam. Chemical looping gasification provides a novel technology to enable clean conversion of coal with inherent CO2 capture. In this study, four types of NiFe2O4 and CuFe2O4 synthesized by sol–gel method and solid-phase method were used as oxygen carriers to promote the H2 production from gasification of lignite. The effects of the types of oxygen carrier and oxygen carrier to coal (O/C) ratio on chemical looping gasification of lignite were first investigated by a thermogravimetric analyzer (TGA) combing with various analytical methods. The results show that, among four types of oxygen carrier, the NiFe2O4 synthesized by sol–gel method exhibits the highest gasification reactivity with lignite char at an O/C ratio of 1, since its highly cubic spinel structure is beneficial to improve the mobility of lattice oxygen. Furthermore, the operating conditions for chemical looping gasification of lignite were optimized and the gasification performance of four types oxygen carriers was compared by using a fixed bed reactor. It is found that NiFe2O4 synthesized by sol–gel method exhibits the highest total gas yield of 24.47 mol/kg and H2/CO ratio of 0.77 during chemical looping gasification of lignite under the optimal operating conditions, ascribed to Fe-Ni synergistic effect which provided higher gasification reactivity with lignite char. The addition of steam drastically improves the total gas yield and H2/CO ratio of syngas from 24.47 mol/kg and 0.77 to 64.98 mol/kg and 2.79, suggesting that the H2/CO ratio of syngas can be flexibly adjusted to meet the need of downstream process via controlling the amount of steam added. These findings provide an efficient method to obtain H2-rich syngas via chemical looping gasification of lignite.
doi_str_mv 10.1016/j.fuel.2021.121269
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2575540067</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0016236121011480</els_id><sourcerecordid>2575540067</sourcerecordid><originalsourceid>FETCH-LOGICAL-c394t-9dd61e4be84987c2b209b727460f39783cace6639d5617ad7cd8430e73d44f763</originalsourceid><addsrcrecordid>eNp9kD9PwzAQxS0EEqXwBZgsMSf4X-xEYkEVUKSKLjBbqX1pXaVxsRNEBr47Lu3MdKfT793dewjdUpJTQuX9Nm8GaHNGGM0po0xWZ2hCS8UzRQt-jiYkURnjkl6iqxi3hBBVFmKCfuajDX4NXRac2eA4dus64n3wdjC98x1ugt9hs4GdM3WLW-_3rlvjBLkmTf4Q3-DWrTvXA16NeIgH4M09A1sKXHcWz4ZTH7H_HtMtbOoQHIR4jS6auo1wc6pT9PH89D6bZ4vly-vscZEZXok-q6yVFMQKSlGVyrAVI9VKMSUkaXilSm5qA1LyyhaSqtoqY0vBCShuhWiU5FN0d9ybjH0OEHu99UPo0knNClUUghCpEsWOlAk-xgCN3ge3q8OoKdGHmPVWH2LWh5j1MeYkejiKIP3_lUzpaBx0BqwLYHptvftP_gupsIZQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2575540067</pqid></control><display><type>article</type><title>Hydrogen-rich syngas production from chemical looping gasification of lignite by using NiFe2O4 and CuFe2O4 as oxygen carriers</title><source>Access via ScienceDirect (Elsevier)</source><creator>Zhao, Kun ; Fang, Xiaojie ; Huang, Zhen ; Wei, Guoqiang ; Zheng, Anqing ; Zhao, Zengli</creator><creatorcontrib>Zhao, Kun ; Fang, Xiaojie ; Huang, Zhen ; Wei, Guoqiang ; Zheng, Anqing ; Zhao, Zengli</creatorcontrib><description>•Chemical looping gasification of lignite was promoted by NiFe2O4 and CuFe2O4.•Pure cubic spinel structure is beneficial for the mobility of lattice oxygen.•NiFe2O4 exhibits the highest gas yield of 24.47 mol/kg during lignite gasification.•1.65 times increase of total syngas yield was obtained by addition of steam. Chemical looping gasification provides a novel technology to enable clean conversion of coal with inherent CO2 capture. In this study, four types of NiFe2O4 and CuFe2O4 synthesized by sol–gel method and solid-phase method were used as oxygen carriers to promote the H2 production from gasification of lignite. The effects of the types of oxygen carrier and oxygen carrier to coal (O/C) ratio on chemical looping gasification of lignite were first investigated by a thermogravimetric analyzer (TGA) combing with various analytical methods. The results show that, among four types of oxygen carrier, the NiFe2O4 synthesized by sol–gel method exhibits the highest gasification reactivity with lignite char at an O/C ratio of 1, since its highly cubic spinel structure is beneficial to improve the mobility of lattice oxygen. Furthermore, the operating conditions for chemical looping gasification of lignite were optimized and the gasification performance of four types oxygen carriers was compared by using a fixed bed reactor. It is found that NiFe2O4 synthesized by sol–gel method exhibits the highest total gas yield of 24.47 mol/kg and H2/CO ratio of 0.77 during chemical looping gasification of lignite under the optimal operating conditions, ascribed to Fe-Ni synergistic effect which provided higher gasification reactivity with lignite char. The addition of steam drastically improves the total gas yield and H2/CO ratio of syngas from 24.47 mol/kg and 0.77 to 64.98 mol/kg and 2.79, suggesting that the H2/CO ratio of syngas can be flexibly adjusted to meet the need of downstream process via controlling the amount of steam added. These findings provide an efficient method to obtain H2-rich syngas via chemical looping gasification of lignite.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2021.121269</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Analytical methods ; Carbon dioxide ; Carbon sequestration ; Chemical looping gasification ; Coal gasification ; Copper ferrite ; Cubic lattice ; Fixed bed reactors ; Fixed beds ; Gasification ; H2-rich syngas ; Hydrogen production ; Lignite ; Nickel ferrite ; Nickel ferrites ; Oxygen ; Sol-gel processes ; Solid phases ; Steam ; Synergistic effect ; Synthesis ; Synthesis gas</subject><ispartof>Fuel (Guildford), 2021-11, Vol.303, p.121269, Article 121269</ispartof><rights>2021 Elsevier Ltd</rights><rights>Copyright Elsevier BV Nov 1, 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c394t-9dd61e4be84987c2b209b727460f39783cace6639d5617ad7cd8430e73d44f763</citedby><cites>FETCH-LOGICAL-c394t-9dd61e4be84987c2b209b727460f39783cace6639d5617ad7cd8430e73d44f763</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.fuel.2021.121269$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Zhao, Kun</creatorcontrib><creatorcontrib>Fang, Xiaojie</creatorcontrib><creatorcontrib>Huang, Zhen</creatorcontrib><creatorcontrib>Wei, Guoqiang</creatorcontrib><creatorcontrib>Zheng, Anqing</creatorcontrib><creatorcontrib>Zhao, Zengli</creatorcontrib><title>Hydrogen-rich syngas production from chemical looping gasification of lignite by using NiFe2O4 and CuFe2O4 as oxygen carriers</title><title>Fuel (Guildford)</title><description>•Chemical looping gasification of lignite was promoted by NiFe2O4 and CuFe2O4.•Pure cubic spinel structure is beneficial for the mobility of lattice oxygen.•NiFe2O4 exhibits the highest gas yield of 24.47 mol/kg during lignite gasification.•1.65 times increase of total syngas yield was obtained by addition of steam. Chemical looping gasification provides a novel technology to enable clean conversion of coal with inherent CO2 capture. In this study, four types of NiFe2O4 and CuFe2O4 synthesized by sol–gel method and solid-phase method were used as oxygen carriers to promote the H2 production from gasification of lignite. The effects of the types of oxygen carrier and oxygen carrier to coal (O/C) ratio on chemical looping gasification of lignite were first investigated by a thermogravimetric analyzer (TGA) combing with various analytical methods. The results show that, among four types of oxygen carrier, the NiFe2O4 synthesized by sol–gel method exhibits the highest gasification reactivity with lignite char at an O/C ratio of 1, since its highly cubic spinel structure is beneficial to improve the mobility of lattice oxygen. Furthermore, the operating conditions for chemical looping gasification of lignite were optimized and the gasification performance of four types oxygen carriers was compared by using a fixed bed reactor. It is found that NiFe2O4 synthesized by sol–gel method exhibits the highest total gas yield of 24.47 mol/kg and H2/CO ratio of 0.77 during chemical looping gasification of lignite under the optimal operating conditions, ascribed to Fe-Ni synergistic effect which provided higher gasification reactivity with lignite char. The addition of steam drastically improves the total gas yield and H2/CO ratio of syngas from 24.47 mol/kg and 0.77 to 64.98 mol/kg and 2.79, suggesting that the H2/CO ratio of syngas can be flexibly adjusted to meet the need of downstream process via controlling the amount of steam added. These findings provide an efficient method to obtain H2-rich syngas via chemical looping gasification of lignite.</description><subject>Analytical methods</subject><subject>Carbon dioxide</subject><subject>Carbon sequestration</subject><subject>Chemical looping gasification</subject><subject>Coal gasification</subject><subject>Copper ferrite</subject><subject>Cubic lattice</subject><subject>Fixed bed reactors</subject><subject>Fixed beds</subject><subject>Gasification</subject><subject>H2-rich syngas</subject><subject>Hydrogen production</subject><subject>Lignite</subject><subject>Nickel ferrite</subject><subject>Nickel ferrites</subject><subject>Oxygen</subject><subject>Sol-gel processes</subject><subject>Solid phases</subject><subject>Steam</subject><subject>Synergistic effect</subject><subject>Synthesis</subject><subject>Synthesis gas</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kD9PwzAQxS0EEqXwBZgsMSf4X-xEYkEVUKSKLjBbqX1pXaVxsRNEBr47Lu3MdKfT793dewjdUpJTQuX9Nm8GaHNGGM0po0xWZ2hCS8UzRQt-jiYkURnjkl6iqxi3hBBVFmKCfuajDX4NXRac2eA4dus64n3wdjC98x1ugt9hs4GdM3WLW-_3rlvjBLkmTf4Q3-DWrTvXA16NeIgH4M09A1sKXHcWz4ZTH7H_HtMtbOoQHIR4jS6auo1wc6pT9PH89D6bZ4vly-vscZEZXok-q6yVFMQKSlGVyrAVI9VKMSUkaXilSm5qA1LyyhaSqtoqY0vBCShuhWiU5FN0d9ybjH0OEHu99UPo0knNClUUghCpEsWOlAk-xgCN3ge3q8OoKdGHmPVWH2LWh5j1MeYkejiKIP3_lUzpaBx0BqwLYHptvftP_gupsIZQ</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Zhao, Kun</creator><creator>Fang, Xiaojie</creator><creator>Huang, Zhen</creator><creator>Wei, Guoqiang</creator><creator>Zheng, Anqing</creator><creator>Zhao, Zengli</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>20211101</creationdate><title>Hydrogen-rich syngas production from chemical looping gasification of lignite by using NiFe2O4 and CuFe2O4 as oxygen carriers</title><author>Zhao, Kun ; Fang, Xiaojie ; Huang, Zhen ; Wei, Guoqiang ; Zheng, Anqing ; Zhao, Zengli</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c394t-9dd61e4be84987c2b209b727460f39783cace6639d5617ad7cd8430e73d44f763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Analytical methods</topic><topic>Carbon dioxide</topic><topic>Carbon sequestration</topic><topic>Chemical looping gasification</topic><topic>Coal gasification</topic><topic>Copper ferrite</topic><topic>Cubic lattice</topic><topic>Fixed bed reactors</topic><topic>Fixed beds</topic><topic>Gasification</topic><topic>H2-rich syngas</topic><topic>Hydrogen production</topic><topic>Lignite</topic><topic>Nickel ferrite</topic><topic>Nickel ferrites</topic><topic>Oxygen</topic><topic>Sol-gel processes</topic><topic>Solid phases</topic><topic>Steam</topic><topic>Synergistic effect</topic><topic>Synthesis</topic><topic>Synthesis gas</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Kun</creatorcontrib><creatorcontrib>Fang, Xiaojie</creatorcontrib><creatorcontrib>Huang, Zhen</creatorcontrib><creatorcontrib>Wei, Guoqiang</creatorcontrib><creatorcontrib>Zheng, Anqing</creatorcontrib><creatorcontrib>Zhao, Zengli</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology &amp; Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts – Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Kun</au><au>Fang, Xiaojie</au><au>Huang, Zhen</au><au>Wei, Guoqiang</au><au>Zheng, Anqing</au><au>Zhao, Zengli</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrogen-rich syngas production from chemical looping gasification of lignite by using NiFe2O4 and CuFe2O4 as oxygen carriers</atitle><jtitle>Fuel (Guildford)</jtitle><date>2021-11-01</date><risdate>2021</risdate><volume>303</volume><spage>121269</spage><pages>121269-</pages><artnum>121269</artnum><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>•Chemical looping gasification of lignite was promoted by NiFe2O4 and CuFe2O4.•Pure cubic spinel structure is beneficial for the mobility of lattice oxygen.•NiFe2O4 exhibits the highest gas yield of 24.47 mol/kg during lignite gasification.•1.65 times increase of total syngas yield was obtained by addition of steam. Chemical looping gasification provides a novel technology to enable clean conversion of coal with inherent CO2 capture. In this study, four types of NiFe2O4 and CuFe2O4 synthesized by sol–gel method and solid-phase method were used as oxygen carriers to promote the H2 production from gasification of lignite. The effects of the types of oxygen carrier and oxygen carrier to coal (O/C) ratio on chemical looping gasification of lignite were first investigated by a thermogravimetric analyzer (TGA) combing with various analytical methods. The results show that, among four types of oxygen carrier, the NiFe2O4 synthesized by sol–gel method exhibits the highest gasification reactivity with lignite char at an O/C ratio of 1, since its highly cubic spinel structure is beneficial to improve the mobility of lattice oxygen. Furthermore, the operating conditions for chemical looping gasification of lignite were optimized and the gasification performance of four types oxygen carriers was compared by using a fixed bed reactor. It is found that NiFe2O4 synthesized by sol–gel method exhibits the highest total gas yield of 24.47 mol/kg and H2/CO ratio of 0.77 during chemical looping gasification of lignite under the optimal operating conditions, ascribed to Fe-Ni synergistic effect which provided higher gasification reactivity with lignite char. The addition of steam drastically improves the total gas yield and H2/CO ratio of syngas from 24.47 mol/kg and 0.77 to 64.98 mol/kg and 2.79, suggesting that the H2/CO ratio of syngas can be flexibly adjusted to meet the need of downstream process via controlling the amount of steam added. These findings provide an efficient method to obtain H2-rich syngas via chemical looping gasification of lignite.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.fuel.2021.121269</doi></addata></record>
fulltext fulltext
identifier ISSN: 0016-2361
ispartof Fuel (Guildford), 2021-11, Vol.303, p.121269, Article 121269
issn 0016-2361
1873-7153
language eng
recordid cdi_proquest_journals_2575540067
source Access via ScienceDirect (Elsevier)
subjects Analytical methods
Carbon dioxide
Carbon sequestration
Chemical looping gasification
Coal gasification
Copper ferrite
Cubic lattice
Fixed bed reactors
Fixed beds
Gasification
H2-rich syngas
Hydrogen production
Lignite
Nickel ferrite
Nickel ferrites
Oxygen
Sol-gel processes
Solid phases
Steam
Synergistic effect
Synthesis
Synthesis gas
title Hydrogen-rich syngas production from chemical looping gasification of lignite by using NiFe2O4 and CuFe2O4 as oxygen carriers
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T03%3A39%3A05IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Hydrogen-rich%20syngas%20production%20from%20chemical%20looping%20gasification%20of%20lignite%20by%20using%20NiFe2O4%20and%20CuFe2O4%20as%20oxygen%20carriers&rft.jtitle=Fuel%20(Guildford)&rft.au=Zhao,%20Kun&rft.date=2021-11-01&rft.volume=303&rft.spage=121269&rft.pages=121269-&rft.artnum=121269&rft.issn=0016-2361&rft.eissn=1873-7153&rft_id=info:doi/10.1016/j.fuel.2021.121269&rft_dat=%3Cproquest_cross%3E2575540067%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2575540067&rft_id=info:pmid/&rft_els_id=S0016236121011480&rfr_iscdi=true