Magnetic structures and spin reorientation in the B-site disordered perovskite PrFe0.5Cr0.5O3
Through the detailed studies utilizing x-ray and neutron powder diffraction and magnetometry measurements, we report the magnetic phase transitions in the B-site disorder perovskite oxide PrFe0.5Cr0.5O3. The Fe3+/Cr3+ sublattice was observed to form a long-range magnetic order with the GxFz configur...
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| Veröffentlicht in: | Journal of magnetism and magnetic materials 2021-11, Vol.538, p.168273, Article 168273 |
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| container_title | Journal of magnetism and magnetic materials |
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| creator | Wang, Chin-Wei Liang, Yu-Hui Liu, En-Pei Studer, Andrew J. Chen, W.T. Du, Chao-Hung |
| description | Through the detailed studies utilizing x-ray and neutron powder diffraction and magnetometry measurements, we report the magnetic phase transitions in the B-site disorder perovskite oxide PrFe0.5Cr0.5O3. The Fe3+/Cr3+ sublattice was observed to form a long-range magnetic order with the GxFz configuration below TN = 270 K from neutron powder diffraction. It then undergoes the second-order phase transition to FxGz spin configuration below 210 K and the transition ends at ~170 K. On the other hand, long range magnetic ordering with FxCy configuration at Pr3+ sublattice can be identified at base temperature. The magnetic phase diagram is derived with spontaneous spin ordering and reorientation at A- and B-sublattices. |
| doi_str_mv | 10.1016/j.jmmm.2021.168273 |
| format | Article |
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The Fe3+/Cr3+ sublattice was observed to form a long-range magnetic order with the GxFz configuration below TN = 270 K from neutron powder diffraction. It then undergoes the second-order phase transition to FxGz spin configuration below 210 K and the transition ends at ~170 K. On the other hand, long range magnetic ordering with FxCy configuration at Pr3+ sublattice can be identified at base temperature. The magnetic phase diagram is derived with spontaneous spin ordering and reorientation at A- and B-sublattices.</description><identifier>ISSN: 0304-8853</identifier><identifier>EISSN: 1873-4766</identifier><identifier>DOI: 10.1016/j.jmmm.2021.168273</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Configurations ; Magnetic measurement ; Magnetic ordering ; Magnetic phase transition ; Magnetization sign reversal ; Neutron diffraction ; Neutrons ; Perovskites ; Phase diagrams ; Phase transitions ; Spin reorientation</subject><ispartof>Journal of magnetism and magnetic materials, 2021-11, Vol.538, p.168273, Article 168273</ispartof><rights>2021 Elsevier B.V.</rights><rights>Copyright Elsevier BV Nov 15, 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c328t-884e695ce5a43462a385e76d01da9cdd6fa80e0fb9dbe505a92d5654bcb6c07f3</citedby><cites>FETCH-LOGICAL-c328t-884e695ce5a43462a385e76d01da9cdd6fa80e0fb9dbe505a92d5654bcb6c07f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jmmm.2021.168273$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Wang, Chin-Wei</creatorcontrib><creatorcontrib>Liang, Yu-Hui</creatorcontrib><creatorcontrib>Liu, En-Pei</creatorcontrib><creatorcontrib>Studer, Andrew J.</creatorcontrib><creatorcontrib>Chen, W.T.</creatorcontrib><creatorcontrib>Du, Chao-Hung</creatorcontrib><title>Magnetic structures and spin reorientation in the B-site disordered perovskite PrFe0.5Cr0.5O3</title><title>Journal of magnetism and magnetic materials</title><description>Through the detailed studies utilizing x-ray and neutron powder diffraction and magnetometry measurements, we report the magnetic phase transitions in the B-site disorder perovskite oxide PrFe0.5Cr0.5O3. The Fe3+/Cr3+ sublattice was observed to form a long-range magnetic order with the GxFz configuration below TN = 270 K from neutron powder diffraction. It then undergoes the second-order phase transition to FxGz spin configuration below 210 K and the transition ends at ~170 K. On the other hand, long range magnetic ordering with FxCy configuration at Pr3+ sublattice can be identified at base temperature. The magnetic phase diagram is derived with spontaneous spin ordering and reorientation at A- and B-sublattices.</description><subject>Configurations</subject><subject>Magnetic measurement</subject><subject>Magnetic ordering</subject><subject>Magnetic phase transition</subject><subject>Magnetization sign reversal</subject><subject>Neutron diffraction</subject><subject>Neutrons</subject><subject>Perovskites</subject><subject>Phase diagrams</subject><subject>Phase transitions</subject><subject>Spin reorientation</subject><issn>0304-8853</issn><issn>1873-4766</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kEFLxDAQhYMouK7-AU8Bz61J06QpeNHFVUFZD3qUkE2mmuq2dZJd8N_bpZ69zMDjvZnHR8g5ZzlnXF22ebvZbPKCFTznSheVOCAzriuRlZVSh2TGBCszraU4JicxtowxXmo1I29P9r2DFByNCbcubREitZ2ncQgdRegxQJdsCn1HRyF9AL3JYkhAfYg9ekDwdADsd_Fzrz7jElguFziOlTglR439inD2t-fkdXn7srjPHld3D4vrx8yJQqexVwmqlg6kLUWpCiu0hEp5xr2tnfeqsZoBa9a1X4Nk0taFl0qWa7dWjlWNmJOL6e6A_fcWYjJtv8VufGkKWUlW67LWo6uYXA77GBEaM2DYWPwxnJk9RtOaPUazx2gmjGPoagrB2H8XAE10IxIHPiC4ZHwf_ov_ApE-e3c</recordid><startdate>20211115</startdate><enddate>20211115</enddate><creator>Wang, Chin-Wei</creator><creator>Liang, Yu-Hui</creator><creator>Liu, En-Pei</creator><creator>Studer, Andrew J.</creator><creator>Chen, W.T.</creator><creator>Du, Chao-Hung</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20211115</creationdate><title>Magnetic structures and spin reorientation in the B-site disordered perovskite PrFe0.5Cr0.5O3</title><author>Wang, Chin-Wei ; Liang, Yu-Hui ; Liu, En-Pei ; Studer, Andrew J. ; Chen, W.T. ; Du, Chao-Hung</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-884e695ce5a43462a385e76d01da9cdd6fa80e0fb9dbe505a92d5654bcb6c07f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Configurations</topic><topic>Magnetic measurement</topic><topic>Magnetic ordering</topic><topic>Magnetic phase transition</topic><topic>Magnetization sign reversal</topic><topic>Neutron diffraction</topic><topic>Neutrons</topic><topic>Perovskites</topic><topic>Phase diagrams</topic><topic>Phase transitions</topic><topic>Spin reorientation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Chin-Wei</creatorcontrib><creatorcontrib>Liang, Yu-Hui</creatorcontrib><creatorcontrib>Liu, En-Pei</creatorcontrib><creatorcontrib>Studer, Andrew J.</creatorcontrib><creatorcontrib>Chen, W.T.</creatorcontrib><creatorcontrib>Du, Chao-Hung</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of magnetism and magnetic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Chin-Wei</au><au>Liang, Yu-Hui</au><au>Liu, En-Pei</au><au>Studer, Andrew J.</au><au>Chen, W.T.</au><au>Du, Chao-Hung</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Magnetic structures and spin reorientation in the B-site disordered perovskite PrFe0.5Cr0.5O3</atitle><jtitle>Journal of magnetism and magnetic materials</jtitle><date>2021-11-15</date><risdate>2021</risdate><volume>538</volume><spage>168273</spage><pages>168273-</pages><artnum>168273</artnum><issn>0304-8853</issn><eissn>1873-4766</eissn><abstract>Through the detailed studies utilizing x-ray and neutron powder diffraction and magnetometry measurements, we report the magnetic phase transitions in the B-site disorder perovskite oxide PrFe0.5Cr0.5O3. The Fe3+/Cr3+ sublattice was observed to form a long-range magnetic order with the GxFz configuration below TN = 270 K from neutron powder diffraction. It then undergoes the second-order phase transition to FxGz spin configuration below 210 K and the transition ends at ~170 K. On the other hand, long range magnetic ordering with FxCy configuration at Pr3+ sublattice can be identified at base temperature. The magnetic phase diagram is derived with spontaneous spin ordering and reorientation at A- and B-sublattices.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jmmm.2021.168273</doi></addata></record> |
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| subjects | Configurations Magnetic measurement Magnetic ordering Magnetic phase transition Magnetization sign reversal Neutron diffraction Neutrons Perovskites Phase diagrams Phase transitions Spin reorientation |
| title | Magnetic structures and spin reorientation in the B-site disordered perovskite PrFe0.5Cr0.5O3 |
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