Nickel-catalyzed cross-electrophile coupling of aryl bromides and cyclic secondary alkyl bromides with spiro-bidentate-pyox ligands
The cross-electrophile coupling of aryl bromides and cyclic secondary alkyl bromides catalyzed by nickel/spiro-bidentate-pyox ligands with lithium chloride as the additive for the Csp 2 -Csp 3 bond formation was reported. The reaction could tolerate functional groups such as sulfonamide, ester, alde...
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| Veröffentlicht in: | New journal of chemistry 2021-09, Vol.45 (36), p.16477-16481 |
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| container_issue | 36 |
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| container_title | New journal of chemistry |
| container_volume | 45 |
| creator | Gao, Nanxing Li, Yanshun Cao, Guorui Teng, Dawei |
| description | The cross-electrophile coupling of aryl bromides and cyclic secondary alkyl bromides catalyzed by nickel/spiro-bidentate-pyox ligands with lithium chloride as the additive for the Csp
2
-Csp
3
bond formation was reported. The reaction could tolerate functional groups such as sulfonamide, ester, aldehyde, ketone, protected indolyl, tert-butoxycarbonyl, aryl nitriles and aryl chloride. Various aryl-cyclic secondary alkyl Csp
2
-Csp
3
bond products were synthesized under optimal reaction conditions (19 examples).
The cross-electrophile coupling catalyzed by nickel/spiro-bidentate-pyox ligands with lithium chloride as the additive was reported, which has good functional group tolerance (19 examples). |
| doi_str_mv | 10.1039/d1nj02677a |
| format | Article |
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2
-Csp
3
bond formation was reported. The reaction could tolerate functional groups such as sulfonamide, ester, aldehyde, ketone, protected indolyl, tert-butoxycarbonyl, aryl nitriles and aryl chloride. Various aryl-cyclic secondary alkyl Csp
2
-Csp
3
bond products were synthesized under optimal reaction conditions (19 examples).
The cross-electrophile coupling catalyzed by nickel/spiro-bidentate-pyox ligands with lithium chloride as the additive was reported, which has good functional group tolerance (19 examples).</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/d1nj02677a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Aldehydes ; Aromatic compounds ; Bromides ; Chemical synthesis ; Coupling ; Functional groups ; Ligands ; Lithium ; Lithium chloride ; Nickel ; Nitriles ; Sulfonamides</subject><ispartof>New journal of chemistry, 2021-09, Vol.45 (36), p.16477-16481</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-57c053ea8dcae0b0610e9ff5cdf3a1367c8be451cc8379905eddaf61cc1342dc3</citedby><cites>FETCH-LOGICAL-c281t-57c053ea8dcae0b0610e9ff5cdf3a1367c8be451cc8379905eddaf61cc1342dc3</cites><orcidid>0000-0003-1629-3787</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Gao, Nanxing</creatorcontrib><creatorcontrib>Li, Yanshun</creatorcontrib><creatorcontrib>Cao, Guorui</creatorcontrib><creatorcontrib>Teng, Dawei</creatorcontrib><title>Nickel-catalyzed cross-electrophile coupling of aryl bromides and cyclic secondary alkyl bromides with spiro-bidentate-pyox ligands</title><title>New journal of chemistry</title><description>The cross-electrophile coupling of aryl bromides and cyclic secondary alkyl bromides catalyzed by nickel/spiro-bidentate-pyox ligands with lithium chloride as the additive for the Csp
2
-Csp
3
bond formation was reported. The reaction could tolerate functional groups such as sulfonamide, ester, aldehyde, ketone, protected indolyl, tert-butoxycarbonyl, aryl nitriles and aryl chloride. Various aryl-cyclic secondary alkyl Csp
2
-Csp
3
bond products were synthesized under optimal reaction conditions (19 examples).
The cross-electrophile coupling catalyzed by nickel/spiro-bidentate-pyox ligands with lithium chloride as the additive was reported, which has good functional group tolerance (19 examples).</description><subject>Aldehydes</subject><subject>Aromatic compounds</subject><subject>Bromides</subject><subject>Chemical synthesis</subject><subject>Coupling</subject><subject>Functional groups</subject><subject>Ligands</subject><subject>Lithium</subject><subject>Lithium chloride</subject><subject>Nickel</subject><subject>Nitriles</subject><subject>Sulfonamides</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpNkTtPwzAQxy0EEqWwsCNZYkMy2HGcx1iVt6qywBy5Z6d168bBTgVh5YtjWgRM9_rdne5_CJ0yeskoL68Ua5Y0yfJc7qEB41lJyiRj-9FnaUqoSLNDdBTCklLG8owN0OfUwEpbArKTtv_QCoN3IRBtNXTetQtjNQa3aa1p5tjVWPre4pl3a6N0wLKJDT1YAzhocI2KZSzt6j_zZroFDq3xjsxioulkp0nbu3dszTwOCMfooJY26JMfO0QvtzfP43syebp7GI8mBJKCdUTkQAXXslAgNZ3RjFFd1rUAVXMZb82hmOlUMICC52VJhVZK1lmMGU8TBXyIzndzW-9eNzp01dJtfBNXVonI04yKgrNIXeyorRBe11XrzTreVTFafYtcXbPp41bkUYTPdrAP8Mv9PYF_ASShfPI</recordid><startdate>20210928</startdate><enddate>20210928</enddate><creator>Gao, Nanxing</creator><creator>Li, Yanshun</creator><creator>Cao, Guorui</creator><creator>Teng, Dawei</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H9R</scope><scope>JG9</scope><scope>KA0</scope><orcidid>https://orcid.org/0000-0003-1629-3787</orcidid></search><sort><creationdate>20210928</creationdate><title>Nickel-catalyzed cross-electrophile coupling of aryl bromides and cyclic secondary alkyl bromides with spiro-bidentate-pyox ligands</title><author>Gao, Nanxing ; Li, Yanshun ; Cao, Guorui ; Teng, Dawei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-57c053ea8dcae0b0610e9ff5cdf3a1367c8be451cc8379905eddaf61cc1342dc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aldehydes</topic><topic>Aromatic compounds</topic><topic>Bromides</topic><topic>Chemical synthesis</topic><topic>Coupling</topic><topic>Functional groups</topic><topic>Ligands</topic><topic>Lithium</topic><topic>Lithium chloride</topic><topic>Nickel</topic><topic>Nitriles</topic><topic>Sulfonamides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gao, Nanxing</creatorcontrib><creatorcontrib>Li, Yanshun</creatorcontrib><creatorcontrib>Cao, Guorui</creatorcontrib><creatorcontrib>Teng, Dawei</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Illustrata: Natural Sciences</collection><collection>Materials Research Database</collection><collection>ProQuest Illustrata: Technology Collection</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gao, Nanxing</au><au>Li, Yanshun</au><au>Cao, Guorui</au><au>Teng, Dawei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nickel-catalyzed cross-electrophile coupling of aryl bromides and cyclic secondary alkyl bromides with spiro-bidentate-pyox ligands</atitle><jtitle>New journal of chemistry</jtitle><date>2021-09-28</date><risdate>2021</risdate><volume>45</volume><issue>36</issue><spage>16477</spage><epage>16481</epage><pages>16477-16481</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>The cross-electrophile coupling of aryl bromides and cyclic secondary alkyl bromides catalyzed by nickel/spiro-bidentate-pyox ligands with lithium chloride as the additive for the Csp
2
-Csp
3
bond formation was reported. The reaction could tolerate functional groups such as sulfonamide, ester, aldehyde, ketone, protected indolyl, tert-butoxycarbonyl, aryl nitriles and aryl chloride. Various aryl-cyclic secondary alkyl Csp
2
-Csp
3
bond products were synthesized under optimal reaction conditions (19 examples).
The cross-electrophile coupling catalyzed by nickel/spiro-bidentate-pyox ligands with lithium chloride as the additive was reported, which has good functional group tolerance (19 examples).</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1nj02677a</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-1629-3787</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1144-0546 |
| ispartof | New journal of chemistry, 2021-09, Vol.45 (36), p.16477-16481 |
| issn | 1144-0546 1369-9261 |
| language | eng |
| recordid | cdi_proquest_journals_2574605831 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Aldehydes Aromatic compounds Bromides Chemical synthesis Coupling Functional groups Ligands Lithium Lithium chloride Nickel Nitriles Sulfonamides |
| title | Nickel-catalyzed cross-electrophile coupling of aryl bromides and cyclic secondary alkyl bromides with spiro-bidentate-pyox ligands |
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