SrxTi1–xCoO3±δ Perovskite‐like Catalysts with Enhanced Activity for Hydrogen Production
Autothermal reforming (ATR) of acetic acid (HOAc) is a promising and alternative route for hydrogen production from renewable resources, but catalyst deactivation caused by cobalt metal sintering and coking is a major concern in ATR. In this work, perovskite‐like catalysts of the formula SrxTi1–xCoO...
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| Veröffentlicht in: | Chemical engineering & technology 2021-10, Vol.44 (10), p.1870-1876 |
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| creator | Liu, Yan Li, Huigu Huang, Jia Hu, Xiaomin Zhang, Yu Huang, Lihong |
| description | Autothermal reforming (ATR) of acetic acid (HOAc) is a promising and alternative route for hydrogen production from renewable resources, but catalyst deactivation caused by cobalt metal sintering and coking is a major concern in ATR. In this work, perovskite‐like catalysts of the formula SrxTi1–xCoO3±δ (x = 0, 0.2, 0.5, and 0.8) were prepared by evaporation‐induced self‐assembly and then evaluated in ATR for hydrogen production. The SrxTi1–xCoO3±δ catalysts exhibited high activity and stability as well as 100 % conversion of HOAc. Additionally, the Co particles with strong metal‐support interaction of SrTi(Co)O3 inhibited coking and agglomeration, and showed potential for hydrogen production by the ATR process.
Autothermal reforming (ATR) of acetic acid (HOAc) from renewable resources such as bio‐oil is an alternative route for hydrogen production. Perovskite‐like ATR catalysts of the formula SrxTi1–xCoO3±δ were prepared by evaporation‐induced self‐assembly. The SrTi(Co)O3 catalyst showed high activity in the ATR of HOAc, and the strong metal‐support interaction suppressed carbon deposition and sintering. |
| doi_str_mv | 10.1002/ceat.202100285 |
| format | Article |
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Autothermal reforming (ATR) of acetic acid (HOAc) from renewable resources such as bio‐oil is an alternative route for hydrogen production. Perovskite‐like ATR catalysts of the formula SrxTi1–xCoO3±δ were prepared by evaporation‐induced self‐assembly. The SrTi(Co)O3 catalyst showed high activity in the ATR of HOAc, and the strong metal‐support interaction suppressed carbon deposition and sintering.</description><identifier>ISSN: 0930-7516</identifier><identifier>EISSN: 1521-4125</identifier><identifier>DOI: 10.1002/ceat.202100285</identifier><language>eng</language><publisher>Frankfurt: Wiley Subscription Services, Inc</publisher><subject>Acetic acid ; Autothermal reforming ; Catalysts ; Coking ; Hydrogen ; Hydrogen production ; Perovskites ; Reforming ; Renewable resources</subject><ispartof>Chemical engineering & technology, 2021-10, Vol.44 (10), p.1870-1876</ispartof><rights>2021 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fceat.202100285$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fceat.202100285$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Liu, Yan</creatorcontrib><creatorcontrib>Li, Huigu</creatorcontrib><creatorcontrib>Huang, Jia</creatorcontrib><creatorcontrib>Hu, Xiaomin</creatorcontrib><creatorcontrib>Zhang, Yu</creatorcontrib><creatorcontrib>Huang, Lihong</creatorcontrib><title>SrxTi1–xCoO3±δ Perovskite‐like Catalysts with Enhanced Activity for Hydrogen Production</title><title>Chemical engineering & technology</title><description>Autothermal reforming (ATR) of acetic acid (HOAc) is a promising and alternative route for hydrogen production from renewable resources, but catalyst deactivation caused by cobalt metal sintering and coking is a major concern in ATR. In this work, perovskite‐like catalysts of the formula SrxTi1–xCoO3±δ (x = 0, 0.2, 0.5, and 0.8) were prepared by evaporation‐induced self‐assembly and then evaluated in ATR for hydrogen production. The SrxTi1–xCoO3±δ catalysts exhibited high activity and stability as well as 100 % conversion of HOAc. Additionally, the Co particles with strong metal‐support interaction of SrTi(Co)O3 inhibited coking and agglomeration, and showed potential for hydrogen production by the ATR process.
Autothermal reforming (ATR) of acetic acid (HOAc) from renewable resources such as bio‐oil is an alternative route for hydrogen production. Perovskite‐like ATR catalysts of the formula SrxTi1–xCoO3±δ were prepared by evaporation‐induced self‐assembly. The SrTi(Co)O3 catalyst showed high activity in the ATR of HOAc, and the strong metal‐support interaction suppressed carbon deposition and sintering.</description><subject>Acetic acid</subject><subject>Autothermal reforming</subject><subject>Catalysts</subject><subject>Coking</subject><subject>Hydrogen</subject><subject>Hydrogen production</subject><subject>Perovskites</subject><subject>Reforming</subject><subject>Renewable resources</subject><issn>0930-7516</issn><issn>1521-4125</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNo9kM1Kw0AUhQdRsFa3rgdcR-fOZDLJsoRqhUIL1qUMk2Ri08ZMnUx_susjCD6J4BP4AD5En8SUSleXj3s4Bz6EroHcAiH0LtXK3VJC9xDyE9QBTsHzgfJT1CERI57gEJyji7qeEUKghQ56ebKbSQG77ecmNiP28_X7jcfamlU9L5zebT_KYq5xrJwqm9rVeF24Ke5XU1WlOsO91BWrwjU4NxYPmsyaV13hsTXZsv2Y6hKd5aqs9dX_7aLn-_4kHnjD0cNj3Bt6CyoY91ISpJRpERE_EABJkgckEaHIfT_QXAHnScAy0JCEYe5HoHxf5QkoJSBiXEesi24OvQtr3pe6dnJmlrZqJyXlwmcMwhDaVHRIrYtSN3JhizdlGwlE7pXJvT959Cfjfm9yJPYHMNtppA</recordid><startdate>202110</startdate><enddate>202110</enddate><creator>Liu, Yan</creator><creator>Li, Huigu</creator><creator>Huang, Jia</creator><creator>Hu, Xiaomin</creator><creator>Zhang, Yu</creator><creator>Huang, Lihong</creator><general>Wiley Subscription Services, Inc</general><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>202110</creationdate><title>SrxTi1–xCoO3±δ Perovskite‐like Catalysts with Enhanced Activity for Hydrogen Production</title><author>Liu, Yan ; Li, Huigu ; Huang, Jia ; Hu, Xiaomin ; Zhang, Yu ; Huang, Lihong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p2735-c06c23e79046711bbf60b787f446e5a155b63d1e1b88f491a44afb1aa71935e93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acetic acid</topic><topic>Autothermal reforming</topic><topic>Catalysts</topic><topic>Coking</topic><topic>Hydrogen</topic><topic>Hydrogen production</topic><topic>Perovskites</topic><topic>Reforming</topic><topic>Renewable resources</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Yan</creatorcontrib><creatorcontrib>Li, Huigu</creatorcontrib><creatorcontrib>Huang, Jia</creatorcontrib><creatorcontrib>Hu, Xiaomin</creatorcontrib><creatorcontrib>Zhang, Yu</creatorcontrib><creatorcontrib>Huang, Lihong</creatorcontrib><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical engineering & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Yan</au><au>Li, Huigu</au><au>Huang, Jia</au><au>Hu, Xiaomin</au><au>Zhang, Yu</au><au>Huang, Lihong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>SrxTi1–xCoO3±δ Perovskite‐like Catalysts with Enhanced Activity for Hydrogen Production</atitle><jtitle>Chemical engineering & technology</jtitle><date>2021-10</date><risdate>2021</risdate><volume>44</volume><issue>10</issue><spage>1870</spage><epage>1876</epage><pages>1870-1876</pages><issn>0930-7516</issn><eissn>1521-4125</eissn><abstract>Autothermal reforming (ATR) of acetic acid (HOAc) is a promising and alternative route for hydrogen production from renewable resources, but catalyst deactivation caused by cobalt metal sintering and coking is a major concern in ATR. In this work, perovskite‐like catalysts of the formula SrxTi1–xCoO3±δ (x = 0, 0.2, 0.5, and 0.8) were prepared by evaporation‐induced self‐assembly and then evaluated in ATR for hydrogen production. The SrxTi1–xCoO3±δ catalysts exhibited high activity and stability as well as 100 % conversion of HOAc. Additionally, the Co particles with strong metal‐support interaction of SrTi(Co)O3 inhibited coking and agglomeration, and showed potential for hydrogen production by the ATR process.
Autothermal reforming (ATR) of acetic acid (HOAc) from renewable resources such as bio‐oil is an alternative route for hydrogen production. Perovskite‐like ATR catalysts of the formula SrxTi1–xCoO3±δ were prepared by evaporation‐induced self‐assembly. The SrTi(Co)O3 catalyst showed high activity in the ATR of HOAc, and the strong metal‐support interaction suppressed carbon deposition and sintering.</abstract><cop>Frankfurt</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ceat.202100285</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Acetic acid Autothermal reforming Catalysts Coking Hydrogen Hydrogen production Perovskites Reforming Renewable resources |
| title | SrxTi1–xCoO3±δ Perovskite‐like Catalysts with Enhanced Activity for Hydrogen Production |
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