Anion-templated assembly of Co(II)-complexes based on the semirigid carboxylic acid ligand: synthesis, structure and magnetic property
Template-induced synthesis of coordination polymers (CPs) is of increasing interest. Herein, we report the synthesis of two Co(II)-complexes from 4-[(1-carboxynaphthalen-2-yl)oxy]phthalic acid (H 3 L) and 1,10-phenanthroline (phen) templates by two anions ( NO 3 − , CH 3 COO − ) under solvothermal c...
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| Veröffentlicht in: | Transition metal chemistry (Weinheim) 2021-10, Vol.46 (7), p.547-553 |
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| creator | Kang, Ya-Xin Hu, Dong-Cheng Zhang, Dan-Dan Zhao, Man-Na Zhang, Ji Liu, Jia-Cheng |
| description | Template-induced synthesis of coordination polymers (CPs) is of increasing interest. Herein, we report the synthesis of two Co(II)-complexes from 4-[(1-carboxynaphthalen-2-yl)oxy]phthalic acid (H
3
L) and 1,10-phenanthroline (phen) templates by two anions ( NO
3
−
, CH
3
COO
−
) under solvothermal conditions. The compounds were characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy, powder X-ray diffraction and thermogravimetry measurement, respectively. Compound
1
possesses an infinite 2D layer structure with a (
6
,
3
)-connected topology. Compound
2
exhibits 2D → 3D supermolecular frameworks by
π
⋯
π
stacking interactions among adjacent layers. Moreover, magnetization data for
2
with the {Co
2
} units showed the antiferromagnetic coupling in the {Co
2
} units.
Graphical abstract
Two novel Co(II) coordination polymers have been successfully synthesized by templating two different anions ( NO
3
−
, CH
3
COO
−
) under solvothermal conditions. Due to the templating role of the anions, the compounds showed different topological structure. Compound 1 possess an infinite 2D layer structure with a (6,3)-connected topology. Compound 2 exhibit 2D → 3D supermolecular frameworks by
π
⋯
π
stacking interactions among adjacent layers. |
| doi_str_mv | 10.1007/s11243-021-00472-6 |
| format | Article |
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3
L) and 1,10-phenanthroline (phen) templates by two anions ( NO
3
−
, CH
3
COO
−
) under solvothermal conditions. The compounds were characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy, powder X-ray diffraction and thermogravimetry measurement, respectively. Compound
1
possesses an infinite 2D layer structure with a (
6
,
3
)-connected topology. Compound
2
exhibits 2D → 3D supermolecular frameworks by
π
⋯
π
stacking interactions among adjacent layers. Moreover, magnetization data for
2
with the {Co
2
} units showed the antiferromagnetic coupling in the {Co
2
} units.
Graphical abstract
Two novel Co(II) coordination polymers have been successfully synthesized by templating two different anions ( NO
3
−
, CH
3
COO
−
) under solvothermal conditions. Due to the templating role of the anions, the compounds showed different topological structure. Compound 1 possess an infinite 2D layer structure with a (6,3)-connected topology. Compound 2 exhibit 2D → 3D supermolecular frameworks by
π
⋯
π
stacking interactions among adjacent layers.</description><identifier>ISSN: 0340-4285</identifier><identifier>EISSN: 1572-901X</identifier><identifier>DOI: 10.1007/s11243-021-00472-6</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Anions ; Antiferromagnetism ; Carboxylic acids ; Catalysis ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Coordination polymers ; Crystals ; Infrared analysis ; Inorganic Chemistry ; Magnetic properties ; Organometallic Chemistry ; Physical Chemistry ; Single crystals ; Stacking ; Thermogravimetry ; Topology ; X ray powder diffraction ; X-ray diffraction</subject><ispartof>Transition metal chemistry (Weinheim), 2021-10, Vol.46 (7), p.547-553</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-2b81b223d0cf48f55d6a4ef809ab6311c1c1c988ad3e3f6215ba83ab4570dc643</citedby><cites>FETCH-LOGICAL-c249t-2b81b223d0cf48f55d6a4ef809ab6311c1c1c988ad3e3f6215ba83ab4570dc643</cites><orcidid>0000-0002-9336-2283</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11243-021-00472-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11243-021-00472-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Kang, Ya-Xin</creatorcontrib><creatorcontrib>Hu, Dong-Cheng</creatorcontrib><creatorcontrib>Zhang, Dan-Dan</creatorcontrib><creatorcontrib>Zhao, Man-Na</creatorcontrib><creatorcontrib>Zhang, Ji</creatorcontrib><creatorcontrib>Liu, Jia-Cheng</creatorcontrib><title>Anion-templated assembly of Co(II)-complexes based on the semirigid carboxylic acid ligand: synthesis, structure and magnetic property</title><title>Transition metal chemistry (Weinheim)</title><addtitle>Transit Met Chem</addtitle><description>Template-induced synthesis of coordination polymers (CPs) is of increasing interest. Herein, we report the synthesis of two Co(II)-complexes from 4-[(1-carboxynaphthalen-2-yl)oxy]phthalic acid (H
3
L) and 1,10-phenanthroline (phen) templates by two anions ( NO
3
−
, CH
3
COO
−
) under solvothermal conditions. The compounds were characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy, powder X-ray diffraction and thermogravimetry measurement, respectively. Compound
1
possesses an infinite 2D layer structure with a (
6
,
3
)-connected topology. Compound
2
exhibits 2D → 3D supermolecular frameworks by
π
⋯
π
stacking interactions among adjacent layers. Moreover, magnetization data for
2
with the {Co
2
} units showed the antiferromagnetic coupling in the {Co
2
} units.
Graphical abstract
Two novel Co(II) coordination polymers have been successfully synthesized by templating two different anions ( NO
3
−
, CH
3
COO
−
) under solvothermal conditions. Due to the templating role of the anions, the compounds showed different topological structure. Compound 1 possess an infinite 2D layer structure with a (6,3)-connected topology. Compound 2 exhibit 2D → 3D supermolecular frameworks by
π
⋯
π
stacking interactions among adjacent layers.</description><subject>Anions</subject><subject>Antiferromagnetism</subject><subject>Carboxylic acids</subject><subject>Catalysis</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination polymers</subject><subject>Crystals</subject><subject>Infrared analysis</subject><subject>Inorganic Chemistry</subject><subject>Magnetic properties</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Single crystals</subject><subject>Stacking</subject><subject>Thermogravimetry</subject><subject>Topology</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><issn>0340-4285</issn><issn>1572-901X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KxDAUhYMoOI6-gKuAGwWj-WubupPBn4EBNwruQpqmtUPb1CSF6Qv43Gas4E7u4t7L_c65cAA4J_iGYJzdekIoZwhTgjDmGUXpAViQJA45Ju-HYIEZx4hTkRyDE--3GOOEZnwBvu77xvYomG5oVTAlVN6brmgnaCu4spfr9RXSNh7NznhYKB8R28PwYWDkGtfUTQm1coXdTW2jodJxb5ta9eUd9FMfQd_4a-iDG3UYnYHxAjtV9yZEfHB2MC5Mp-CoUq03Z799Cd4eH15Xz2jz8rRe3W-QpjwPiBaCFJSyEuuKiypJylRxUwmcqyJlhOh95UKokhlWpZQkhRJMFTzJcKlTzpbgYvaNjz9H44Pc2tH18aWkScZEKnhOIkVnSjvrvTOVHFzTKTdJguU-bznnLWPe8idvmUYRm0U-wn1t3J_1P6pvpT2FGg</recordid><startdate>20211001</startdate><enddate>20211001</enddate><creator>Kang, Ya-Xin</creator><creator>Hu, Dong-Cheng</creator><creator>Zhang, Dan-Dan</creator><creator>Zhao, Man-Na</creator><creator>Zhang, Ji</creator><creator>Liu, Jia-Cheng</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-9336-2283</orcidid></search><sort><creationdate>20211001</creationdate><title>Anion-templated assembly of Co(II)-complexes based on the semirigid carboxylic acid ligand: synthesis, structure and magnetic property</title><author>Kang, Ya-Xin ; Hu, Dong-Cheng ; Zhang, Dan-Dan ; Zhao, Man-Na ; Zhang, Ji ; Liu, Jia-Cheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-2b81b223d0cf48f55d6a4ef809ab6311c1c1c988ad3e3f6215ba83ab4570dc643</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Anions</topic><topic>Antiferromagnetism</topic><topic>Carboxylic acids</topic><topic>Catalysis</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination polymers</topic><topic>Crystals</topic><topic>Infrared analysis</topic><topic>Inorganic Chemistry</topic><topic>Magnetic properties</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Single crystals</topic><topic>Stacking</topic><topic>Thermogravimetry</topic><topic>Topology</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kang, Ya-Xin</creatorcontrib><creatorcontrib>Hu, Dong-Cheng</creatorcontrib><creatorcontrib>Zhang, Dan-Dan</creatorcontrib><creatorcontrib>Zhao, Man-Na</creatorcontrib><creatorcontrib>Zhang, Ji</creatorcontrib><creatorcontrib>Liu, Jia-Cheng</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Transition metal chemistry (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kang, Ya-Xin</au><au>Hu, Dong-Cheng</au><au>Zhang, Dan-Dan</au><au>Zhao, Man-Na</au><au>Zhang, Ji</au><au>Liu, Jia-Cheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Anion-templated assembly of Co(II)-complexes based on the semirigid carboxylic acid ligand: synthesis, structure and magnetic property</atitle><jtitle>Transition metal chemistry (Weinheim)</jtitle><stitle>Transit Met Chem</stitle><date>2021-10-01</date><risdate>2021</risdate><volume>46</volume><issue>7</issue><spage>547</spage><epage>553</epage><pages>547-553</pages><issn>0340-4285</issn><eissn>1572-901X</eissn><abstract>Template-induced synthesis of coordination polymers (CPs) is of increasing interest. Herein, we report the synthesis of two Co(II)-complexes from 4-[(1-carboxynaphthalen-2-yl)oxy]phthalic acid (H
3
L) and 1,10-phenanthroline (phen) templates by two anions ( NO
3
−
, CH
3
COO
−
) under solvothermal conditions. The compounds were characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy, powder X-ray diffraction and thermogravimetry measurement, respectively. Compound
1
possesses an infinite 2D layer structure with a (
6
,
3
)-connected topology. Compound
2
exhibits 2D → 3D supermolecular frameworks by
π
⋯
π
stacking interactions among adjacent layers. Moreover, magnetization data for
2
with the {Co
2
} units showed the antiferromagnetic coupling in the {Co
2
} units.
Graphical abstract
Two novel Co(II) coordination polymers have been successfully synthesized by templating two different anions ( NO
3
−
, CH
3
COO
−
) under solvothermal conditions. Due to the templating role of the anions, the compounds showed different topological structure. Compound 1 possess an infinite 2D layer structure with a (6,3)-connected topology. Compound 2 exhibit 2D → 3D supermolecular frameworks by
π
⋯
π
stacking interactions among adjacent layers.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11243-021-00472-6</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-9336-2283</orcidid></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Anions Antiferromagnetism Carboxylic acids Catalysis Chemical synthesis Chemistry Chemistry and Materials Science Coordination polymers Crystals Infrared analysis Inorganic Chemistry Magnetic properties Organometallic Chemistry Physical Chemistry Single crystals Stacking Thermogravimetry Topology X ray powder diffraction X-ray diffraction |
| title | Anion-templated assembly of Co(II)-complexes based on the semirigid carboxylic acid ligand: synthesis, structure and magnetic property |
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