1H NMR STUDY OF MIXED-LIGAND LANTHANIDE COMPLEXES. STOICHIOMETRY AND TEMPERATURE SENSITIVITY OF PARAMAGNETIC CHEMICAL SHIFTS OF PRASEODYMIUM β-DIKETONATES AND THEIR COMPOUNDS WITH 18-CROWN-6
Complexes [(Pr(DPM) 3 ) 2 ], [Pr(DPM) 3 (18-crown-6)], [(Pr(DPM) 3 ) 2 (18-crown-6)], [Pr(DPM)(PTA)(18-crown-6)] + and the temperature sensitivity of paramagnetic lanthanidine-induced shifts of these complexes in CDCl 3 solution are characterized by 1 H NMR. The NMR methods are used to estimate the...
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| Veröffentlicht in: | Journal of structural chemistry 2021, Vol.62 (8), p.1184-1190 |
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| creator | Babailov, S. P. Stabnikov, P. A. Tkachev, S. V. Kruppa, A. I. |
| description | Complexes [(Pr(DPM)
3
)
2
], [Pr(DPM)
3
(18-crown-6)], [(Pr(DPM)
3
)
2
(18-crown-6)], [Pr(DPM)(PTA)(18-crown-6)]
+
and the temperature sensitivity of paramagnetic lanthanidine-induced shifts of these complexes in CDCl
3
solution are characterized by
1
H NMR. The NMR methods are used to estimate the possibility of forming inclusive complexes in CDCl
3
solution upon the interaction of lanthanide tris-β-diketonates with 18-crown-6 in the case of a more branched ligand than PTA (e.g., DPM). Upon the interaction of [(Pr(DPM)
3
)
2
] and 18-crown-6, the [Pr(DPM)
3
(18-crown-6)] forms prevail in solution. The obtained results indicate that the studied coordination compounds can be considered as
1
H NMR paramagnetic lanthanide probes for local temperature control in organic solutions using the analysis of paramagnetic lanthanidine-induced shifts. |
| doi_str_mv | 10.1134/S0022476621080035 |
| format | Article |
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3
)
2
], [Pr(DPM)
3
(18-crown-6)], [(Pr(DPM)
3
)
2
(18-crown-6)], [Pr(DPM)(PTA)(18-crown-6)]
+
and the temperature sensitivity of paramagnetic lanthanidine-induced shifts of these complexes in CDCl
3
solution are characterized by
1
H NMR. The NMR methods are used to estimate the possibility of forming inclusive complexes in CDCl
3
solution upon the interaction of lanthanide tris-β-diketonates with 18-crown-6 in the case of a more branched ligand than PTA (e.g., DPM). Upon the interaction of [(Pr(DPM)
3
)
2
] and 18-crown-6, the [Pr(DPM)
3
(18-crown-6)] forms prevail in solution. The obtained results indicate that the studied coordination compounds can be considered as
1
H NMR paramagnetic lanthanide probes for local temperature control in organic solutions using the analysis of paramagnetic lanthanidine-induced shifts.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476621080035</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Coordination compounds ; Inorganic Chemistry ; Ligands ; Molecular ; NMR ; Nuclear magnetic resonance ; Optical and Plasma Physics ; Physical Chemistry ; Praseodymium ; Sensitivity ; Solid State Physics ; Stoichiometry ; Temperature control</subject><ispartof>Journal of structural chemistry, 2021, Vol.62 (8), p.1184-1190</ispartof><rights>Pleiades Publishing, Ltd. 2021</rights><rights>Pleiades Publishing, Ltd. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1615-4cff9a575c69f2de3ba6a8c305f28fa9cbc729f687a915fa6fd40a16fdc6516b3</citedby><cites>FETCH-LOGICAL-c1615-4cff9a575c69f2de3ba6a8c305f28fa9cbc729f687a915fa6fd40a16fdc6516b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476621080035$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476621080035$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Babailov, S. P.</creatorcontrib><creatorcontrib>Stabnikov, P. A.</creatorcontrib><creatorcontrib>Tkachev, S. V.</creatorcontrib><creatorcontrib>Kruppa, A. I.</creatorcontrib><title>1H NMR STUDY OF MIXED-LIGAND LANTHANIDE COMPLEXES. STOICHIOMETRY AND TEMPERATURE SENSITIVITY OF PARAMAGNETIC CHEMICAL SHIFTS OF PRASEODYMIUM β-DIKETONATES AND THEIR COMPOUNDS WITH 18-CROWN-6</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>Complexes [(Pr(DPM)
3
)
2
], [Pr(DPM)
3
(18-crown-6)], [(Pr(DPM)
3
)
2
(18-crown-6)], [Pr(DPM)(PTA)(18-crown-6)]
+
and the temperature sensitivity of paramagnetic lanthanidine-induced shifts of these complexes in CDCl
3
solution are characterized by
1
H NMR. The NMR methods are used to estimate the possibility of forming inclusive complexes in CDCl
3
solution upon the interaction of lanthanide tris-β-diketonates with 18-crown-6 in the case of a more branched ligand than PTA (e.g., DPM). Upon the interaction of [(Pr(DPM)
3
)
2
] and 18-crown-6, the [Pr(DPM)
3
(18-crown-6)] forms prevail in solution. The obtained results indicate that the studied coordination compounds can be considered as
1
H NMR paramagnetic lanthanide probes for local temperature control in organic solutions using the analysis of paramagnetic lanthanidine-induced shifts.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination compounds</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Molecular</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Praseodymium</subject><subject>Sensitivity</subject><subject>Solid State Physics</subject><subject>Stoichiometry</subject><subject>Temperature control</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kU9u1DAYxS0EUofCAbqzxNrFzh_HWVqJZ2I1tkexQzuryJPGiAo6bUIXXIsL9AaciWQGiUXV1bd4v_ee9D0ALgi-JCROPluMoyjJKI0IZhjH6RuwImkWI5Zl-VuwWmS06Gfg_TTdYYxzltMVeCYV1KqB1rXlDpo1VPJGlKiWG65LWHPtKq5lKWBh1LYWN8JezqyRRSWNEq7ZwYVzQm1Fw13bCGiFttLJL9Id87a84YpvtHCygEUllCx4DW0l184e9YZbYcqdkq2Cf36jUl4JZzR3wp6iKyGbY7tpdWnhtXQVJAwVjbnWiH4A74L_Pg0f_91z0K6FKypUm83ShHpCSYqSPoTcp1na0zxEt0O899SzPsZpiFjweb_vsygPlGU-J2nwNNwm2JP59DQldB-fg0-n3Ifx8Pg0TD-7u8PTeD9XdtH8ZkZZnJCZIieqHw_TNA6hexi__fDjr47gbtmpe7HT7IlOnmlm778O4__k101_ARpghwM</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Babailov, S. P.</creator><creator>Stabnikov, P. A.</creator><creator>Tkachev, S. V.</creator><creator>Kruppa, A. I.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2021</creationdate><title>1H NMR STUDY OF MIXED-LIGAND LANTHANIDE COMPLEXES. STOICHIOMETRY AND TEMPERATURE SENSITIVITY OF PARAMAGNETIC CHEMICAL SHIFTS OF PRASEODYMIUM β-DIKETONATES AND THEIR COMPOUNDS WITH 18-CROWN-6</title><author>Babailov, S. P. ; Stabnikov, P. A. ; Tkachev, S. V. ; Kruppa, A. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1615-4cff9a575c69f2de3ba6a8c305f28fa9cbc729f687a915fa6fd40a16fdc6516b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination compounds</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Molecular</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Praseodymium</topic><topic>Sensitivity</topic><topic>Solid State Physics</topic><topic>Stoichiometry</topic><topic>Temperature control</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Babailov, S. P.</creatorcontrib><creatorcontrib>Stabnikov, P. A.</creatorcontrib><creatorcontrib>Tkachev, S. V.</creatorcontrib><creatorcontrib>Kruppa, A. I.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Babailov, S. P.</au><au>Stabnikov, P. A.</au><au>Tkachev, S. V.</au><au>Kruppa, A. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>1H NMR STUDY OF MIXED-LIGAND LANTHANIDE COMPLEXES. STOICHIOMETRY AND TEMPERATURE SENSITIVITY OF PARAMAGNETIC CHEMICAL SHIFTS OF PRASEODYMIUM β-DIKETONATES AND THEIR COMPOUNDS WITH 18-CROWN-6</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2021</date><risdate>2021</risdate><volume>62</volume><issue>8</issue><spage>1184</spage><epage>1190</epage><pages>1184-1190</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>Complexes [(Pr(DPM)
3
)
2
], [Pr(DPM)
3
(18-crown-6)], [(Pr(DPM)
3
)
2
(18-crown-6)], [Pr(DPM)(PTA)(18-crown-6)]
+
and the temperature sensitivity of paramagnetic lanthanidine-induced shifts of these complexes in CDCl
3
solution are characterized by
1
H NMR. The NMR methods are used to estimate the possibility of forming inclusive complexes in CDCl
3
solution upon the interaction of lanthanide tris-β-diketonates with 18-crown-6 in the case of a more branched ligand than PTA (e.g., DPM). Upon the interaction of [(Pr(DPM)
3
)
2
] and 18-crown-6, the [Pr(DPM)
3
(18-crown-6)] forms prevail in solution. The obtained results indicate that the studied coordination compounds can be considered as
1
H NMR paramagnetic lanthanide probes for local temperature control in organic solutions using the analysis of paramagnetic lanthanidine-induced shifts.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476621080035</doi><tpages>7</tpages></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Coordination compounds Inorganic Chemistry Ligands Molecular NMR Nuclear magnetic resonance Optical and Plasma Physics Physical Chemistry Praseodymium Sensitivity Solid State Physics Stoichiometry Temperature control |
| title | 1H NMR STUDY OF MIXED-LIGAND LANTHANIDE COMPLEXES. STOICHIOMETRY AND TEMPERATURE SENSITIVITY OF PARAMAGNETIC CHEMICAL SHIFTS OF PRASEODYMIUM β-DIKETONATES AND THEIR COMPOUNDS WITH 18-CROWN-6 |
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