Conversion of biorenewably available acetone and butanol to liquid fuels using base catalysts
We studied acetone butylation over KF/Na-ZSM-5 and ZSM-5 impregnated with other K-compounds which impart basicity. These base catalysts have, so far, not been reported for ketone alkylation. These catalysts did not contain any metal any of metal which are conventionally used to affect dehydrogenatio...
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| Veröffentlicht in: | Biomass conversion and biorefinery 2021-10, Vol.11 (5), p.1921-1930 |
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| container_end_page | 1930 |
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| container_issue | 5 |
| container_start_page | 1921 |
| container_title | Biomass conversion and biorefinery |
| container_volume | 11 |
| creator | Jadon, Tarun Pratap Singh Jana, Arun Kumar Parikh, Parimal A. |
| description | We studied acetone butylation over KF/Na-ZSM-5 and ZSM-5 impregnated with other K-compounds which impart basicity. These base catalysts have, so far, not been reported for ketone alkylation. These catalysts did not contain any metal any of metal which are conventionally used to affect dehydrogenation-hydrogenation reactions which have been reported to be involved in mechanism of acetone alkylation. Absence of such metals reduces catalyst costs and eliminates metal sintering. Catalyst basicity was determined by FTIR of pyrrole-adsorbed samples and CO
2
adsorption method. Coke deposited after reaction for 20 h time-on-stream on promising catalyst, namely, 10 wt% KF/Na-ZSM-5, was characterized by TGA and GCMS. This confirmed stability of KF on Na-ZSM-5, without leaching of F. Acetone conversion (60%) and ketone plus alcohol selectivity (exceeding 90%) surpassed reported performance at comparable operating conditions. |
| doi_str_mv | 10.1007/s13399-019-00563-6 |
| format | Article |
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2
adsorption method. Coke deposited after reaction for 20 h time-on-stream on promising catalyst, namely, 10 wt% KF/Na-ZSM-5, was characterized by TGA and GCMS. This confirmed stability of KF on Na-ZSM-5, without leaching of F. Acetone conversion (60%) and ketone plus alcohol selectivity (exceeding 90%) surpassed reported performance at comparable operating conditions.</description><identifier>ISSN: 2190-6815</identifier><identifier>EISSN: 2190-6823</identifier><identifier>DOI: 10.1007/s13399-019-00563-6</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Acetone ; Alkylation ; Basicity ; Biotechnology ; Butanol ; Catalysts ; Conversion ; Dehydrogenation ; Energy ; Leaching ; Liquid fuels ; Original Article ; Renewable and Green Energy ; Selectivity</subject><ispartof>Biomass conversion and biorefinery, 2021-10, Vol.11 (5), p.1921-1930</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-5163778ce5014cbace13f5b89c5305387476e3a13b4898005e424c9a0ed5c0653</citedby><cites>FETCH-LOGICAL-c319t-5163778ce5014cbace13f5b89c5305387476e3a13b4898005e424c9a0ed5c0653</cites><orcidid>0000-0002-1873-6310</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13399-019-00563-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13399-019-00563-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Jadon, Tarun Pratap Singh</creatorcontrib><creatorcontrib>Jana, Arun Kumar</creatorcontrib><creatorcontrib>Parikh, Parimal A.</creatorcontrib><title>Conversion of biorenewably available acetone and butanol to liquid fuels using base catalysts</title><title>Biomass conversion and biorefinery</title><addtitle>Biomass Conv. Bioref</addtitle><description>We studied acetone butylation over KF/Na-ZSM-5 and ZSM-5 impregnated with other K-compounds which impart basicity. These base catalysts have, so far, not been reported for ketone alkylation. These catalysts did not contain any metal any of metal which are conventionally used to affect dehydrogenation-hydrogenation reactions which have been reported to be involved in mechanism of acetone alkylation. Absence of such metals reduces catalyst costs and eliminates metal sintering. Catalyst basicity was determined by FTIR of pyrrole-adsorbed samples and CO
2
adsorption method. Coke deposited after reaction for 20 h time-on-stream on promising catalyst, namely, 10 wt% KF/Na-ZSM-5, was characterized by TGA and GCMS. This confirmed stability of KF on Na-ZSM-5, without leaching of F. Acetone conversion (60%) and ketone plus alcohol selectivity (exceeding 90%) surpassed reported performance at comparable operating conditions.</description><subject>Acetone</subject><subject>Alkylation</subject><subject>Basicity</subject><subject>Biotechnology</subject><subject>Butanol</subject><subject>Catalysts</subject><subject>Conversion</subject><subject>Dehydrogenation</subject><subject>Energy</subject><subject>Leaching</subject><subject>Liquid fuels</subject><subject>Original Article</subject><subject>Renewable and Green Energy</subject><subject>Selectivity</subject><issn>2190-6815</issn><issn>2190-6823</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9UMtKAzEUDaJg0f6Aq4Dr0WTuJJMspfiCghtdSsikd8qUMWmTmUr_3tQR3bm4nLM4D-4h5IqzG85YfZs4gNYF4_mYkFDIEzIruWaFVCWc_nIuzsk8pQ1jrIQaFLAZeV8Ev8eYuuBpaGnThYgeP23TH6jd267PDKl1OASf0a9oMw7Wh54OgfbdbuxWtB2xT3RMnV_Txiakzg62P6QhXZKz1vYJ5z94Qd4e7l8XT8Xy5fF5cbcsHHA9FIJLqGvlUDBeuSa3cWhFo7QTwASouqolguXQVEqr_CNWZeW0ZbgSjkkBF-R6yt3GsBsxDWYTxuhzpSlFXWqpKnVUlZPKxZBSxNZsY_dh48FwZo5LmmlJk5c030samU0wmVIW-zXGv-h_XF8KiXYZ</recordid><startdate>20211001</startdate><enddate>20211001</enddate><creator>Jadon, Tarun Pratap Singh</creator><creator>Jana, Arun Kumar</creator><creator>Parikh, Parimal A.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-1873-6310</orcidid></search><sort><creationdate>20211001</creationdate><title>Conversion of biorenewably available acetone and butanol to liquid fuels using base catalysts</title><author>Jadon, Tarun Pratap Singh ; Jana, Arun Kumar ; Parikh, Parimal A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-5163778ce5014cbace13f5b89c5305387476e3a13b4898005e424c9a0ed5c0653</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acetone</topic><topic>Alkylation</topic><topic>Basicity</topic><topic>Biotechnology</topic><topic>Butanol</topic><topic>Catalysts</topic><topic>Conversion</topic><topic>Dehydrogenation</topic><topic>Energy</topic><topic>Leaching</topic><topic>Liquid fuels</topic><topic>Original Article</topic><topic>Renewable and Green Energy</topic><topic>Selectivity</topic><toplevel>online_resources</toplevel><creatorcontrib>Jadon, Tarun Pratap Singh</creatorcontrib><creatorcontrib>Jana, Arun Kumar</creatorcontrib><creatorcontrib>Parikh, Parimal A.</creatorcontrib><collection>CrossRef</collection><jtitle>Biomass conversion and biorefinery</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jadon, Tarun Pratap Singh</au><au>Jana, Arun Kumar</au><au>Parikh, Parimal A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Conversion of biorenewably available acetone and butanol to liquid fuels using base catalysts</atitle><jtitle>Biomass conversion and biorefinery</jtitle><stitle>Biomass Conv. Bioref</stitle><date>2021-10-01</date><risdate>2021</risdate><volume>11</volume><issue>5</issue><spage>1921</spage><epage>1930</epage><pages>1921-1930</pages><issn>2190-6815</issn><eissn>2190-6823</eissn><abstract>We studied acetone butylation over KF/Na-ZSM-5 and ZSM-5 impregnated with other K-compounds which impart basicity. These base catalysts have, so far, not been reported for ketone alkylation. These catalysts did not contain any metal any of metal which are conventionally used to affect dehydrogenation-hydrogenation reactions which have been reported to be involved in mechanism of acetone alkylation. Absence of such metals reduces catalyst costs and eliminates metal sintering. Catalyst basicity was determined by FTIR of pyrrole-adsorbed samples and CO
2
adsorption method. Coke deposited after reaction for 20 h time-on-stream on promising catalyst, namely, 10 wt% KF/Na-ZSM-5, was characterized by TGA and GCMS. This confirmed stability of KF on Na-ZSM-5, without leaching of F. Acetone conversion (60%) and ketone plus alcohol selectivity (exceeding 90%) surpassed reported performance at comparable operating conditions.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13399-019-00563-6</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-1873-6310</orcidid></addata></record> |
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| identifier | ISSN: 2190-6815 |
| ispartof | Biomass conversion and biorefinery, 2021-10, Vol.11 (5), p.1921-1930 |
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| source | Springer Online Journals |
| subjects | Acetone Alkylation Basicity Biotechnology Butanol Catalysts Conversion Dehydrogenation Energy Leaching Liquid fuels Original Article Renewable and Green Energy Selectivity |
| title | Conversion of biorenewably available acetone and butanol to liquid fuels using base catalysts |
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