Synthesis of polymer hybrid latex poly(methyl methacrylate-co-butyl acrylate) with organo montmorillonite via miniemulsion polymerization method for barrier paper
Hybrid polymer latex based on combination of organic-inorganic materials, poly(methyl methacrylate-co-butyl acrylate) (PMMBA) and organo-montmorillonite (OMMT) were synthesized via miniemulsion polymerization technique. Modification of montmorillonite (MMT) through the incorporation of myristyltrime...
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description | Hybrid polymer latex based on combination of organic-inorganic materials, poly(methyl methacrylate-co-butyl acrylate) (PMMBA) and organo-montmorillonite (OMMT) were synthesized via miniemulsion polymerization technique. Modification of montmorillonite (MMT) through the incorporation of myristyltrimethylammonium bromide (MTAB) into the clay's interlayer spaces were investigated by Small-Angle X-ray Scattering (SAXS), Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA) and Transmission Electron Microscopy (TEM). Barrier property and thermal stability of polymer latex film sample were investigated through its Water Vapor Transmission Rate (WVTR) and Thermogravimetric Analysis (TGA). The results indicated that addition of OMMT as filler in PMMBA increased the barrier property and thermal stability of the latex film. Addition of 8.0% (wt) OMMT increased the barrier property and thermal stability. Miniemusion polymerization process with higher addition (>8.0 wt%) of OMMT resulting in high latex viscosity, particle size, and high amount of coagulum. The utilization of this hybrid polymer could benefits paper and board industries to produce high quality barrier paper for food packaging. |
doi_str_mv | 10.1088/1742-6596/985/1/012029 |
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Modification of montmorillonite (MMT) through the incorporation of myristyltrimethylammonium bromide (MTAB) into the clay's interlayer spaces were investigated by Small-Angle X-ray Scattering (SAXS), Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA) and Transmission Electron Microscopy (TEM). Barrier property and thermal stability of polymer latex film sample were investigated through its Water Vapor Transmission Rate (WVTR) and Thermogravimetric Analysis (TGA). The results indicated that addition of OMMT as filler in PMMBA increased the barrier property and thermal stability of the latex film. Addition of 8.0% (wt) OMMT increased the barrier property and thermal stability. Miniemusion polymerization process with higher addition (>8.0 wt%) of OMMT resulting in high latex viscosity, particle size, and high amount of coagulum. The utilization of this hybrid polymer could benefits paper and board industries to produce high quality barrier paper for food packaging.</description><identifier>ISSN: 1742-6588</identifier><identifier>EISSN: 1742-6596</identifier><identifier>DOI: 10.1088/1742-6596/985/1/012029</identifier><language>eng</language><publisher>Bristol: IOP Publishing</publisher><subject>Acrylics ; Addition polymerization ; Chemical synthesis ; Food packaging ; Food packaging industry ; Fourier transforms ; Infrared analysis ; Inorganic materials ; Interlayers ; Latex ; Montmorillonite ; Physics ; Polymer films ; Polymerization ; Polymers ; Polymethyl methacrylate ; Thermal stability ; Thermogravimetric analysis ; Water vapor ; X-ray scattering</subject><ispartof>Journal of physics. Conference series, 2018-03, Vol.985 (1), p.12029</ispartof><rights>Published under licence by IOP Publishing Ltd</rights><rights>2018. This work is published under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c408t-568d19c244df0385591a2126c4b27c22d134eec8e863a47daaa44f74089654b83</citedby><cites>FETCH-LOGICAL-c408t-568d19c244df0385591a2126c4b27c22d134eec8e863a47daaa44f74089654b83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.1088/1742-6596/985/1/012029/pdf$$EPDF$$P50$$Giop$$Hfree_for_read</linktopdf><link.rule.ids>314,777,781,27905,27906,38849,38871,53821,53848</link.rule.ids></links><search><creatorcontrib>Chanra, J</creatorcontrib><creatorcontrib>Budianto, E</creatorcontrib><creatorcontrib>Soegijono, B</creatorcontrib><title>Synthesis of polymer hybrid latex poly(methyl methacrylate-co-butyl acrylate) with organo montmorillonite via miniemulsion polymerization method for barrier paper</title><title>Journal of physics. Conference series</title><addtitle>J. Phys.: Conf. Ser</addtitle><description>Hybrid polymer latex based on combination of organic-inorganic materials, poly(methyl methacrylate-co-butyl acrylate) (PMMBA) and organo-montmorillonite (OMMT) were synthesized via miniemulsion polymerization technique. Modification of montmorillonite (MMT) through the incorporation of myristyltrimethylammonium bromide (MTAB) into the clay's interlayer spaces were investigated by Small-Angle X-ray Scattering (SAXS), Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA) and Transmission Electron Microscopy (TEM). Barrier property and thermal stability of polymer latex film sample were investigated through its Water Vapor Transmission Rate (WVTR) and Thermogravimetric Analysis (TGA). The results indicated that addition of OMMT as filler in PMMBA increased the barrier property and thermal stability of the latex film. Addition of 8.0% (wt) OMMT increased the barrier property and thermal stability. Miniemusion polymerization process with higher addition (>8.0 wt%) of OMMT resulting in high latex viscosity, particle size, and high amount of coagulum. The utilization of this hybrid polymer could benefits paper and board industries to produce high quality barrier paper for food packaging.</description><subject>Acrylics</subject><subject>Addition polymerization</subject><subject>Chemical synthesis</subject><subject>Food packaging</subject><subject>Food packaging industry</subject><subject>Fourier transforms</subject><subject>Infrared analysis</subject><subject>Inorganic materials</subject><subject>Interlayers</subject><subject>Latex</subject><subject>Montmorillonite</subject><subject>Physics</subject><subject>Polymer films</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Polymethyl methacrylate</subject><subject>Thermal stability</subject><subject>Thermogravimetric analysis</subject><subject>Water vapor</subject><subject>X-ray scattering</subject><issn>1742-6588</issn><issn>1742-6596</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>O3W</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqFUU1LxDAULKLguvoXJODFPdQmadqmR1n8ZEFh9RzSNrVZ2qYmWbX-HH-pqXVXBMFcXjJvZl5443nHCJ4hSGmAEoL9OErjIKVRgAKIMMTpjjfZNna3d0r3vQNjVhCG7iQT72PZt7YSRhqgStCpum-EBlWfaVmAmlvx9gWeNsJWfQ2GwnPdDx0_V362tg7dIDPwKm0FlH7irQKNam2jtKxr1UorwIvkoJGtFM26NlK1m2nyndvhOXirApRKg4xrLd0_Ot4Jfejtlbw24ui7Tr3Hy4uH-bW_uLu6mZ8v_JxAav0opgVKc0xIUcKQRlGKOEY4zkmGkxzjAoVEiJwKGoecJAXnnJAycdo0jkhGw6l3Mvp2Wj2vhbFspda6dSMZjhKMIKJJ5FjxyMq1MkaLknVaNlz3DEE25MGGVbNh7czlwRAb83BCPAql6n6c_xXN_hDd3s-Xv3isK8rwE97Inr4</recordid><startdate>20180301</startdate><enddate>20180301</enddate><creator>Chanra, J</creator><creator>Budianto, E</creator><creator>Soegijono, B</creator><general>IOP Publishing</general><scope>O3W</scope><scope>TSCCA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>H8D</scope><scope>HCIFZ</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20180301</creationdate><title>Synthesis of polymer hybrid latex poly(methyl methacrylate-co-butyl acrylate) with organo montmorillonite via miniemulsion polymerization method for barrier paper</title><author>Chanra, J ; Budianto, E ; Soegijono, B</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c408t-568d19c244df0385591a2126c4b27c22d134eec8e863a47daaa44f74089654b83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Acrylics</topic><topic>Addition polymerization</topic><topic>Chemical synthesis</topic><topic>Food packaging</topic><topic>Food packaging industry</topic><topic>Fourier transforms</topic><topic>Infrared analysis</topic><topic>Inorganic materials</topic><topic>Interlayers</topic><topic>Latex</topic><topic>Montmorillonite</topic><topic>Physics</topic><topic>Polymer films</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Polymethyl methacrylate</topic><topic>Thermal stability</topic><topic>Thermogravimetric analysis</topic><topic>Water vapor</topic><topic>X-ray scattering</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chanra, J</creatorcontrib><creatorcontrib>Budianto, E</creatorcontrib><creatorcontrib>Soegijono, B</creatorcontrib><collection>IOP Publishing Free Content</collection><collection>IOPscience (Open Access)</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Aerospace Database</collection><collection>SciTech Premium Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Journal of physics. Conference series</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chanra, J</au><au>Budianto, E</au><au>Soegijono, B</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of polymer hybrid latex poly(methyl methacrylate-co-butyl acrylate) with organo montmorillonite via miniemulsion polymerization method for barrier paper</atitle><jtitle>Journal of physics. Conference series</jtitle><addtitle>J. Phys.: Conf. Ser</addtitle><date>2018-03-01</date><risdate>2018</risdate><volume>985</volume><issue>1</issue><spage>12029</spage><pages>12029-</pages><issn>1742-6588</issn><eissn>1742-6596</eissn><abstract>Hybrid polymer latex based on combination of organic-inorganic materials, poly(methyl methacrylate-co-butyl acrylate) (PMMBA) and organo-montmorillonite (OMMT) were synthesized via miniemulsion polymerization technique. Modification of montmorillonite (MMT) through the incorporation of myristyltrimethylammonium bromide (MTAB) into the clay's interlayer spaces were investigated by Small-Angle X-ray Scattering (SAXS), Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA) and Transmission Electron Microscopy (TEM). Barrier property and thermal stability of polymer latex film sample were investigated through its Water Vapor Transmission Rate (WVTR) and Thermogravimetric Analysis (TGA). The results indicated that addition of OMMT as filler in PMMBA increased the barrier property and thermal stability of the latex film. Addition of 8.0% (wt) OMMT increased the barrier property and thermal stability. Miniemusion polymerization process with higher addition (>8.0 wt%) of OMMT resulting in high latex viscosity, particle size, and high amount of coagulum. The utilization of this hybrid polymer could benefits paper and board industries to produce high quality barrier paper for food packaging.</abstract><cop>Bristol</cop><pub>IOP Publishing</pub><doi>10.1088/1742-6596/985/1/012029</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Acrylics Addition polymerization Chemical synthesis Food packaging Food packaging industry Fourier transforms Infrared analysis Inorganic materials Interlayers Latex Montmorillonite Physics Polymer films Polymerization Polymers Polymethyl methacrylate Thermal stability Thermogravimetric analysis Water vapor X-ray scattering |
title | Synthesis of polymer hybrid latex poly(methyl methacrylate-co-butyl acrylate) with organo montmorillonite via miniemulsion polymerization method for barrier paper |
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