Volumetriс Properties of Butyronitrile–Dimethylsulfoxide and Butyronitrile–Diethylsulfoxide Binary Mixtures
Densities of binary mixtures of butyronitrile with dimethylsulfoxide and diethylsulfoxide are measured throughout the range of concentrations and in the temperature range of 298.15–323.15 K at ambient pressure. Volumetric parameters, the parameters of the Redlich–Kister equation, and the standard de...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2021-09, Vol.95 (9), p.1811-1820 |
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| container_issue | 9 |
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| container_title | Russian Journal of Physical Chemistry A |
| container_volume | 95 |
| creator | Ghazoyan, H. H. Markaryan, Sh. A. |
| description | Densities of binary mixtures of butyronitrile with dimethylsulfoxide and diethylsulfoxide are measured throughout the range of concentrations and in the temperature range of 298.15–323.15 K at ambient pressure. Volumetric parameters, the parameters of the Redlich–Kister equation, and the standard deviations of the excess molar volumes are calculated. Deviation of the behavior of these solutions from ideal is explained by the presence of competing homo- and hetero-molecular interactions, and by the effect the length of the hydrocarbon chain of sulfoxides has on the values of volumetric parameters. |
| doi_str_mv | 10.1134/S0036024421090089 |
| format | Article |
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Deviation of the behavior of these solutions from ideal is explained by the presence of competing homo- and hetero-molecular interactions, and by the effect the length of the hydrocarbon chain of sulfoxides has on the values of volumetric parameters.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024421090089</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Binary mixtures ; Chemistry ; Chemistry and Materials Science ; Mathematical analysis ; Molar volume ; Molecular chains ; Molecular interactions ; Parameters ; Physical Chemistry ; Physical Chemistry of Solutions ; Pressure</subject><ispartof>Russian Journal of Physical Chemistry A, 2021-09, Vol.95 (9), p.1811-1820</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 0036-0244, Russian Journal of Physical Chemistry A, 2021, Vol. 95, No. 9, pp. 1811–1820. © Pleiades Publishing, Ltd., 2021. 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A.</creatorcontrib><title>Volumetriс Properties of Butyronitrile–Dimethylsulfoxide and Butyronitrile–Diethylsulfoxide Binary Mixtures</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>Densities of binary mixtures of butyronitrile with dimethylsulfoxide and diethylsulfoxide are measured throughout the range of concentrations and in the temperature range of 298.15–323.15 K at ambient pressure. Volumetric parameters, the parameters of the Redlich–Kister equation, and the standard deviations of the excess molar volumes are calculated. Deviation of the behavior of these solutions from ideal is explained by the presence of competing homo- and hetero-molecular interactions, and by the effect the length of the hydrocarbon chain of sulfoxides has on the values of volumetric parameters.</description><subject>Binary mixtures</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Mathematical analysis</subject><subject>Molar volume</subject><subject>Molecular chains</subject><subject>Molecular interactions</subject><subject>Parameters</subject><subject>Physical Chemistry</subject><subject>Physical Chemistry of Solutions</subject><subject>Pressure</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kMtKxDAUhoMoOI4-gLuC6-pJk6bJ0vEOIwpecFc6uWiGTlOTFmZ2-gw-ma_gk5hhBMHL6nD4v_8_hx-hXQz7GBN6cANAGGSUZhgEABdraIBzglPOyMM6GizldKlvoq0QpgCUUkwHqL13dT_Tnbfvr8m1d632ndUhcSYZ9d3Cu8ZGrdYfL2_HNnJPizr0tXFzq3RSNeoP6gc0sk3lF8mlnXe912EbbZiqDnrnaw7R3enJ7dF5Or46uzg6HKcyI1ikjBdMYj0RcQhOmSBGVprmAFIBlbyaKFJAJnOqGVMcFC04V8pwyI2OOxmivVVu691zr0NXTl3vm3iyzPICC8IJzSOFV5T0LgSvTdl6O4v_lhjKZbHlr2KjJ1t5QmSbR-2_k_83fQLWZX-a</recordid><startdate>20210901</startdate><enddate>20210901</enddate><creator>Ghazoyan, H. 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A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2319-6876c1eb976c984693fcae4500cd04c8abd3702c54e66d80d4788ddf805fed803</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Binary mixtures</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Mathematical analysis</topic><topic>Molar volume</topic><topic>Molecular chains</topic><topic>Molecular interactions</topic><topic>Parameters</topic><topic>Physical Chemistry</topic><topic>Physical Chemistry of Solutions</topic><topic>Pressure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ghazoyan, H. H.</creatorcontrib><creatorcontrib>Markaryan, Sh. 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Volumetric parameters, the parameters of the Redlich–Kister equation, and the standard deviations of the excess molar volumes are calculated. Deviation of the behavior of these solutions from ideal is explained by the presence of competing homo- and hetero-molecular interactions, and by the effect the length of the hydrocarbon chain of sulfoxides has on the values of volumetric parameters.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036024421090089</doi><tpages>10</tpages></addata></record> |
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| identifier | ISSN: 0036-0244 |
| ispartof | Russian Journal of Physical Chemistry A, 2021-09, Vol.95 (9), p.1811-1820 |
| issn | 0036-0244 1531-863X |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Binary mixtures Chemistry Chemistry and Materials Science Mathematical analysis Molar volume Molecular chains Molecular interactions Parameters Physical Chemistry Physical Chemistry of Solutions Pressure |
| title | Volumetriс Properties of Butyronitrile–Dimethylsulfoxide and Butyronitrile–Diethylsulfoxide Binary Mixtures |
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