Temperature-Induced Structural Phase Transitions in Self-Assembled Hydrogen Bonded Networks at the Liquid/Solid Interface
The effect of temperature on the transformations of hydrogen-bonded structures of trimesic acid (TMA) and p -terphenyl-3,5,3'',5''-tetracarboxylic acid (TPTC) has been investigated at the nonanoic acid/highly oriented pyrolytic graphite (HOPG) interface by scanning tunneling micr...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2021-09, Vol.95 (9), p.1871-1876 |
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| container_issue | 9 |
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| container_title | Russian Journal of Physical Chemistry A |
| container_volume | 95 |
| creator | Qiu, Shenyu Li, Yudie Xu, Shilin Cai, Yuanqing Zhang, Yuxin Li, Wei |
| description | The effect of temperature on the transformations of hydrogen-bonded structures of trimesic acid (TMA) and
p
-terphenyl-3,5,3'',5''-tetracarboxylic acid (TPTC) has been investigated at the nonanoic acid/highly oriented pyrolytic graphite (HOPG) interface by scanning tunneling microscopy (STM). STM observations show that TMA assembly based on temperature modulations underwent phase transitions from a chicken-wire (25°C) to a flower (60°C) and further to a guest-host flower structure. Similarly, TPTC network with five kinds of pores underwent change of structural conformation after annealing to 85°C. This work provides a way toward controlled assembly directed by temperature and is beneficial for the understanding of both the assembling process and the underlying kinetics and thermodynamics for molecular nanostructures. |
| doi_str_mv | 10.1134/S0036024421090247 |
| format | Article |
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p
-terphenyl-3,5,3'',5''-tetracarboxylic acid (TPTC) has been investigated at the nonanoic acid/highly oriented pyrolytic graphite (HOPG) interface by scanning tunneling microscopy (STM). STM observations show that TMA assembly based on temperature modulations underwent phase transitions from a chicken-wire (25°C) to a flower (60°C) and further to a guest-host flower structure. Similarly, TPTC network with five kinds of pores underwent change of structural conformation after annealing to 85°C. This work provides a way toward controlled assembly directed by temperature and is beneficial for the understanding of both the assembling process and the underlying kinetics and thermodynamics for molecular nanostructures.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024421090247</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Hydrogen bonding ; Liquid-solid interfaces ; Phase transitions ; Physical Chemistry ; Pyrolytic graphite ; Scanning tunneling microscopy ; Self-assembly ; Structure of Matter and Quantum Chemistry ; Temperature effects ; Trimesic acid</subject><ispartof>Russian Journal of Physical Chemistry A, 2021-09, Vol.95 (9), p.1871-1876</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 0036-0244, Russian Journal of Physical Chemistry A, 2021, Vol. 95, No. 9, pp. 1871–1876. © Pleiades Publishing, Ltd., 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c246t-788555f5d9574e1281dd05d8be9ca05563339bb856f1c14be9d2ac0900abccc43</citedby><cites>FETCH-LOGICAL-c246t-788555f5d9574e1281dd05d8be9ca05563339bb856f1c14be9d2ac0900abccc43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036024421090247$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036024421090247$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Qiu, Shenyu</creatorcontrib><creatorcontrib>Li, Yudie</creatorcontrib><creatorcontrib>Xu, Shilin</creatorcontrib><creatorcontrib>Cai, Yuanqing</creatorcontrib><creatorcontrib>Zhang, Yuxin</creatorcontrib><creatorcontrib>Li, Wei</creatorcontrib><title>Temperature-Induced Structural Phase Transitions in Self-Assembled Hydrogen Bonded Networks at the Liquid/Solid Interface</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>The effect of temperature on the transformations of hydrogen-bonded structures of trimesic acid (TMA) and
p
-terphenyl-3,5,3'',5''-tetracarboxylic acid (TPTC) has been investigated at the nonanoic acid/highly oriented pyrolytic graphite (HOPG) interface by scanning tunneling microscopy (STM). STM observations show that TMA assembly based on temperature modulations underwent phase transitions from a chicken-wire (25°C) to a flower (60°C) and further to a guest-host flower structure. Similarly, TPTC network with five kinds of pores underwent change of structural conformation after annealing to 85°C. This work provides a way toward controlled assembly directed by temperature and is beneficial for the understanding of both the assembling process and the underlying kinetics and thermodynamics for molecular nanostructures.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Hydrogen bonding</subject><subject>Liquid-solid interfaces</subject><subject>Phase transitions</subject><subject>Physical Chemistry</subject><subject>Pyrolytic graphite</subject><subject>Scanning tunneling microscopy</subject><subject>Self-assembly</subject><subject>Structure of Matter and Quantum Chemistry</subject><subject>Temperature effects</subject><subject>Trimesic acid</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1UMtKAzEUDaJgrX6Au4DrsckkmceyFrWFokIruBsyyZ126jRpkwzSvzelggtxdbjndeEgdEvJPaWMjxaEsIyknKeUlBHzMzSggtGkyNjHORoc5eSoX6Ir7zeEcM4pH6DDErY7cDL0DpKZ0b0CjRfB9SoyssNva-kBL500vg2tNR63Bi-ga5Kx97Ctu2ifHrSzKzD4wRod7xcIX9Z9eiwDDmvA83bft3q0sF2r8cwEcI1UcI0uGtl5uPnBIXp_elxOpsn89Xk2Gc8TlfIsJHlRCCEaoUuRc6BpQbUmQhc1lEoSITLGWFnXhcgaqiiPtE6lihsQWSulOBuiu1Pvztl9Dz5UG9s7E19WqchpyfKCi-iiJ5dy1nsHTbVz7Va6Q0VJdVy4-rNwzKSnjI9eswL32_x_6BtcSn4y</recordid><startdate>20210901</startdate><enddate>20210901</enddate><creator>Qiu, Shenyu</creator><creator>Li, Yudie</creator><creator>Xu, Shilin</creator><creator>Cai, Yuanqing</creator><creator>Zhang, Yuxin</creator><creator>Li, Wei</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210901</creationdate><title>Temperature-Induced Structural Phase Transitions in Self-Assembled Hydrogen Bonded Networks at the Liquid/Solid Interface</title><author>Qiu, Shenyu ; Li, Yudie ; Xu, Shilin ; Cai, Yuanqing ; Zhang, Yuxin ; Li, Wei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c246t-788555f5d9574e1281dd05d8be9ca05563339bb856f1c14be9d2ac0900abccc43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Hydrogen bonding</topic><topic>Liquid-solid interfaces</topic><topic>Phase transitions</topic><topic>Physical Chemistry</topic><topic>Pyrolytic graphite</topic><topic>Scanning tunneling microscopy</topic><topic>Self-assembly</topic><topic>Structure of Matter and Quantum Chemistry</topic><topic>Temperature effects</topic><topic>Trimesic acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qiu, Shenyu</creatorcontrib><creatorcontrib>Li, Yudie</creatorcontrib><creatorcontrib>Xu, Shilin</creatorcontrib><creatorcontrib>Cai, Yuanqing</creatorcontrib><creatorcontrib>Zhang, Yuxin</creatorcontrib><creatorcontrib>Li, Wei</creatorcontrib><collection>CrossRef</collection><jtitle>Russian Journal of Physical Chemistry A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Qiu, Shenyu</au><au>Li, Yudie</au><au>Xu, Shilin</au><au>Cai, Yuanqing</au><au>Zhang, Yuxin</au><au>Li, Wei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Temperature-Induced Structural Phase Transitions in Self-Assembled Hydrogen Bonded Networks at the Liquid/Solid Interface</atitle><jtitle>Russian Journal of Physical Chemistry A</jtitle><stitle>Russ. J. Phys. Chem</stitle><date>2021-09-01</date><risdate>2021</risdate><volume>95</volume><issue>9</issue><spage>1871</spage><epage>1876</epage><pages>1871-1876</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>The effect of temperature on the transformations of hydrogen-bonded structures of trimesic acid (TMA) and
p
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| subjects | Chemistry Chemistry and Materials Science Hydrogen bonding Liquid-solid interfaces Phase transitions Physical Chemistry Pyrolytic graphite Scanning tunneling microscopy Self-assembly Structure of Matter and Quantum Chemistry Temperature effects Trimesic acid |
| title | Temperature-Induced Structural Phase Transitions in Self-Assembled Hydrogen Bonded Networks at the Liquid/Solid Interface |
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