Two New Cd(II) Coordination Polymers Based on Triazolyl Derivative and Different Carboxylate Ligands, Their Crystal Structures and Properties
Two new mixed-ligand coordination polymers of Cd(II), namely, [Cd(H 2 L)(ip)H 2 O] n ( 1 ) and [Cd(H 2 L)(Hbtc)] n ( 2 ) [H 2 L = 3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1,2,4-triazole, H 2 ip = isophthalic acid, H 3 btc = 1,3,5-benzenetricarboxylic acid], have been hydrothermally synthesized and chara...
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| Veröffentlicht in: | Russian journal of general chemistry 2021-08, Vol.91 (8), p.1566-1571 |
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| container_title | Russian journal of general chemistry |
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| creator | Wang, Y. F. Zhang, S. Q. Feng, Y. X. Wang, L. Y. |
| description | Two new mixed-ligand coordination polymers of Cd(II), namely, [Cd(H
2
L)(ip)H
2
O]
n
(
1
) and [Cd(H
2
L)(Hbtc)]
n
(
2
) [H
2
L = 3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1,2,4-triazole, H
2
ip = isophthalic acid, H
3
btc = 1,3,5-benzenetricarboxylic acid], have been hydrothermally synthesized and characterized by elemental analysis, IR spectra, powder X-ray diffraction, and single-crystal X-ray diffraction. Compound
1
displays a one-dimensional chain structure, which upon hydrogen bonding generates 3D supramolecular framework. Compound
2
exhibits a one-dimensional double-chain structure connected by hydrogen bonds with formation of 2D supramolecular framework. Fluorescent properties of two compounds have been studied in the solid state at room temperature. |
| doi_str_mv | 10.1134/S1070363221080193 |
| format | Article |
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2
L)(ip)H
2
O]
n
(
1
) and [Cd(H
2
L)(Hbtc)]
n
(
2
) [H
2
L = 3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1,2,4-triazole, H
2
ip = isophthalic acid, H
3
btc = 1,3,5-benzenetricarboxylic acid], have been hydrothermally synthesized and characterized by elemental analysis, IR spectra, powder X-ray diffraction, and single-crystal X-ray diffraction. Compound
1
displays a one-dimensional chain structure, which upon hydrogen bonding generates 3D supramolecular framework. Compound
2
exhibits a one-dimensional double-chain structure connected by hydrogen bonds with formation of 2D supramolecular framework. Fluorescent properties of two compounds have been studied in the solid state at room temperature.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363221080193</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Analysis ; Chemical bonds ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Coordination polymers ; Crystal structure ; Crystals ; Fluorescence ; Hydrogen ; Hydrogen bonding ; Hydrogen bonds ; Infrared analysis ; Infrared spectroscopy ; Ligands ; Polymers ; Room temperature ; Single crystals ; Structure ; Supramolecular frameworks ; X ray powder diffraction ; X-ray diffraction</subject><ispartof>Russian journal of general chemistry, 2021-08, Vol.91 (8), p.1566-1571</ispartof><rights>Pleiades Publishing, Ltd. 2021</rights><rights>COPYRIGHT 2021 Springer</rights><rights>Pleiades Publishing, Ltd. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c285t-ff97e97c7dac0d99ec3d32554fb6c5d04a4bff839112b7301f02535a6ee1b2153</citedby><cites>FETCH-LOGICAL-c285t-ff97e97c7dac0d99ec3d32554fb6c5d04a4bff839112b7301f02535a6ee1b2153</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070363221080193$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070363221080193$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Wang, Y. F.</creatorcontrib><creatorcontrib>Zhang, S. Q.</creatorcontrib><creatorcontrib>Feng, Y. X.</creatorcontrib><creatorcontrib>Wang, L. Y.</creatorcontrib><title>Two New Cd(II) Coordination Polymers Based on Triazolyl Derivative and Different Carboxylate Ligands, Their Crystal Structures and Properties</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>Two new mixed-ligand coordination polymers of Cd(II), namely, [Cd(H
2
L)(ip)H
2
O]
n
(
1
) and [Cd(H
2
L)(Hbtc)]
n
(
2
) [H
2
L = 3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1,2,4-triazole, H
2
ip = isophthalic acid, H
3
btc = 1,3,5-benzenetricarboxylic acid], have been hydrothermally synthesized and characterized by elemental analysis, IR spectra, powder X-ray diffraction, and single-crystal X-ray diffraction. Compound
1
displays a one-dimensional chain structure, which upon hydrogen bonding generates 3D supramolecular framework. Compound
2
exhibits a one-dimensional double-chain structure connected by hydrogen bonds with formation of 2D supramolecular framework. Fluorescent properties of two compounds have been studied in the solid state at room temperature.</description><subject>Analysis</subject><subject>Chemical bonds</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Coordination polymers</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Fluorescence</subject><subject>Hydrogen</subject><subject>Hydrogen bonding</subject><subject>Hydrogen bonds</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Ligands</subject><subject>Polymers</subject><subject>Room temperature</subject><subject>Single crystals</subject><subject>Structure</subject><subject>Supramolecular frameworks</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kd1uEzEQhVcIJErhAbizxA1IbBnb6_25LFt-IkVtpYbrldceB1ebdRg7LeEd-s51CBIXCPlirHPONzPSFMVrDmecy-rDDYcGZC2F4NAC7-ST4oTX0JZSKnia_9kuD_7z4kWMtwAcoBYnxcPqPrBLvGe9fbtYvGN9CGT9rJMPM7sO036DFNlHHdGyrKzI619ZndgFkr_LsTtkerbswjuHhHNivaYx_NxPOiFb-nU243u2-o6eWE_7mPTEbhLtTNoRxt_sNYUtUvIYXxbPnJ4ivvpTT4tvnz-t-q_l8urLoj9flka0KpXOdQ12jWmsNmC7Do20UihVubE2ykKlq9G5Vnaci7GRwB0IJZWuEfkouJKnxZtj3y2FHzuMabgNO5rzyEGoBnjVtV2VU2fH1FpPOPjZhUTa5Gdx402Y0fmsnzf8MKluDgA_AoZCjIRu2JLfaNoPHIbDmYZ_zpQZcWRizs5rpL-r_B96BNyDlMY</recordid><startdate>20210801</startdate><enddate>20210801</enddate><creator>Wang, Y. F.</creator><creator>Zhang, S. Q.</creator><creator>Feng, Y. X.</creator><creator>Wang, L. Y.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210801</creationdate><title>Two New Cd(II) Coordination Polymers Based on Triazolyl Derivative and Different Carboxylate Ligands, Their Crystal Structures and Properties</title><author>Wang, Y. F. ; Zhang, S. Q. ; Feng, Y. X. ; Wang, L. Y.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c285t-ff97e97c7dac0d99ec3d32554fb6c5d04a4bff839112b7301f02535a6ee1b2153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Analysis</topic><topic>Chemical bonds</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Coordination polymers</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Fluorescence</topic><topic>Hydrogen</topic><topic>Hydrogen bonding</topic><topic>Hydrogen bonds</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Ligands</topic><topic>Polymers</topic><topic>Room temperature</topic><topic>Single crystals</topic><topic>Structure</topic><topic>Supramolecular frameworks</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Y. F.</creatorcontrib><creatorcontrib>Zhang, S. Q.</creatorcontrib><creatorcontrib>Feng, Y. X.</creatorcontrib><creatorcontrib>Wang, L. Y.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Y. F.</au><au>Zhang, S. Q.</au><au>Feng, Y. X.</au><au>Wang, L. Y.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Two New Cd(II) Coordination Polymers Based on Triazolyl Derivative and Different Carboxylate Ligands, Their Crystal Structures and Properties</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2021-08-01</date><risdate>2021</risdate><volume>91</volume><issue>8</issue><spage>1566</spage><epage>1571</epage><pages>1566-1571</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>Two new mixed-ligand coordination polymers of Cd(II), namely, [Cd(H
2
L)(ip)H
2
O]
n
(
1
) and [Cd(H
2
L)(Hbtc)]
n
(
2
) [H
2
L = 3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1,2,4-triazole, H
2
ip = isophthalic acid, H
3
btc = 1,3,5-benzenetricarboxylic acid], have been hydrothermally synthesized and characterized by elemental analysis, IR spectra, powder X-ray diffraction, and single-crystal X-ray diffraction. Compound
1
displays a one-dimensional chain structure, which upon hydrogen bonding generates 3D supramolecular framework. Compound
2
exhibits a one-dimensional double-chain structure connected by hydrogen bonds with formation of 2D supramolecular framework. Fluorescent properties of two compounds have been studied in the solid state at room temperature.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070363221080193</doi><tpages>6</tpages></addata></record> |
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| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Analysis Chemical bonds Chemistry Chemistry and Materials Science Chemistry/Food Science Coordination polymers Crystal structure Crystals Fluorescence Hydrogen Hydrogen bonding Hydrogen bonds Infrared analysis Infrared spectroscopy Ligands Polymers Room temperature Single crystals Structure Supramolecular frameworks X ray powder diffraction X-ray diffraction |
| title | Two New Cd(II) Coordination Polymers Based on Triazolyl Derivative and Different Carboxylate Ligands, Their Crystal Structures and Properties |
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