Methylamine Derivatives with 1,2-Azole Fragments: Synthesis, Palladium Complexes, Catalysis of the Suzuki Reaction

Methylamine Derivatives with 1,2-Azole Fragments: Synthesis, Palladium Complexes, Catalysis of the Suzuki Reaction

New methylamine derivatives with 1,2-azole fragments (phenylisoxazole, p -tolylisoxazole, 2,5-dimethylphenylisoxazole and 4,5-dichloroisothiazole) and their palladium complexes were synthesized. It was shown that palladium complexes with the obtained N -methyl-1-(1,2-azol-3-yl)methylamine exhibit hi...

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Veröffentlicht in:Russian journal of general chemistry 2021-08, Vol.91 (8), p.1512-1518
Hauptverfasser: Akishina, E. A., Dikusar, Е. А., Petkevich, S. K., Alekseyev, R. S., Bumagin, N. A., Potkin, V. I.
Format: Artikel
Sprache:eng
Schlagworte:
Aqueous solutions
Catalysis
Catalytic activity
Chemical reactions
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Fragments
Palladium
Substitution reactions
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Zusammenfassung:New methylamine derivatives with 1,2-azole fragments (phenylisoxazole, p -tolylisoxazole, 2,5-dimethylphenylisoxazole and 4,5-dichloroisothiazole) and their palladium complexes were synthesized. It was shown that palladium complexes with the obtained N -methyl-1-(1,2-azol-3-yl)methylamine exhibit high catalytic activity in the Suzuki reaction in aqueous medium.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363221080120