Reactions of CF3-Haloenones with 1,3-Dicarbonyl Compounds: Chemo- and Stereoselective Assembly of Fluorinated Dihydrofurans

•A simple one-pot, atom and steps economic (PASE) synthesis of trifluoromethylated dihydrofurans has been elaborated.•The assembly of heterocycles from fluorinated α-haloenones and 1,3-dicarbonyls is initiated by aza-Michael reaction.•The different reaction pathways of CF3-haloenones and 1,3-N,N- or...

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Veröffentlicht in:	Journal of fluorine chemistry 2021-08, Vol.248, p.109819, Article 109819
Hauptverfasser:	Popov, Alexander V., Mareev, Alexander V., Kobelevskaya, Valentina A., Zinchenko, Sergei V., Vashchenko, Alexander V., Rulev, Alexander Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Assembly Carbonyl compounds Diketones Esters Fluorination Selectivity Stereoselectivity Substitution reactions
Online-Zugang:	Volltext
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