Correlation between chemical composition, electrical, magnetic and microwave properties in Dy-substituted Ni-Cu-Zn ferrites

•Nanostructured Dy-substituted Ni-Cu-Zn spinel ferrites were produced via sol-gel method.•Strong correlation between Dy concentration, magnetic and microwave properties was observed.•Control of the microwave properties can be used for functional radio electronics. Dy3+ ion-substituted nanoferrites N...

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Veröffentlicht in:Materials science & engineering. B, Solid-state materials for advanced technology Solid-state materials for advanced technology, 2021-08, Vol.270, p.115202, Article 115202
Hauptverfasser: Almessiere, M.A., Slimani, Y., Güngüneş, H., Demir Korkmaz, A., Trukhanov, S.V., Guner, S., Alahmari, F., Trukhanov, A.V., Baykal, A.
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container_title Materials science & engineering. B, Solid-state materials for advanced technology
container_volume 270
creator Almessiere, M.A.
Slimani, Y.
Güngüneş, H.
Demir Korkmaz, A.
Trukhanov, S.V.
Guner, S.
Alahmari, F.
Trukhanov, A.V.
Baykal, A.
description •Nanostructured Dy-substituted Ni-Cu-Zn spinel ferrites were produced via sol-gel method.•Strong correlation between Dy concentration, magnetic and microwave properties was observed.•Control of the microwave properties can be used for functional radio electronics. Dy3+ ion-substituted nanoferrites Ni0.4Cu0.2Zn0.4Fe2−xDyxO4 (x ≤ 0.04) were produced via sol-gel method. Correlation between chemical composition, crystal structure, electrical, magnetic and microwave properties was investigated. All samples were characterized by single-phase state. It was observed that the increase of the Dy content leads to a decrease in the average crystallite size. The bandgap (Eg) was deduced to be between 1.83 and 1.86 eV. The measurements of magnetization versus applied magnetic field (M-H) and magnetization versus temperature (M-T) were investigated by vibrating sample magnetometer (VSM). Magnetic measurements revealed superparamagnetic character at room temperature. The magnetization was increased initially with doping Dy3+ in the ratio of x = 0.01 compering to the un-doped sample and thereafter dropped as Dy3+ ions content further increases. Microwave properties were discussed in terms of electromagnetic absorption in the frequency range 1–20 GHz. The occurrences of the intensive electromagnetic absorption in the frequency ranged from 1.6 to 2.7 GHz were observed. The changes in the amplitude-frequency characteristics correlated well with the level of chemical substitution (x) with Dy ions concentration.
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Dy3+ ion-substituted nanoferrites Ni0.4Cu0.2Zn0.4Fe2−xDyxO4 (x ≤ 0.04) were produced via sol-gel method. Correlation between chemical composition, crystal structure, electrical, magnetic and microwave properties was investigated. All samples were characterized by single-phase state. It was observed that the increase of the Dy content leads to a decrease in the average crystallite size. The bandgap (Eg) was deduced to be between 1.83 and 1.86 eV. The measurements of magnetization versus applied magnetic field (M-H) and magnetization versus temperature (M-T) were investigated by vibrating sample magnetometer (VSM). Magnetic measurements revealed superparamagnetic character at room temperature. The magnetization was increased initially with doping Dy3+ in the ratio of x = 0.01 compering to the un-doped sample and thereafter dropped as Dy3+ ions content further increases. Microwave properties were discussed in terms of electromagnetic absorption in the frequency range 1–20 GHz. The occurrences of the intensive electromagnetic absorption in the frequency ranged from 1.6 to 2.7 GHz were observed. The changes in the amplitude-frequency characteristics correlated well with the level of chemical substitution (x) with Dy ions concentration.</description><identifier>ISSN: 0921-5107</identifier><identifier>EISSN: 1873-4944</identifier><identifier>DOI: 10.1016/j.mseb.2021.115202</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Chemical composition ; Correlation ; Crystal structure ; Crystallites ; Domain boundaries resonance ; Dysprosium ; Electromagnetic absorption ; Frequency ranges ; Magnetic measurement ; Magnetic properties ; Magnetization ; Magnetometers ; Microwave properties ; Nanoparticles ; Room temperature ; Sol-gel processes ; Spinel ferrites ; Substitutes</subject><ispartof>Materials science &amp; engineering. 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Magnetic measurements revealed superparamagnetic character at room temperature. The magnetization was increased initially with doping Dy3+ in the ratio of x = 0.01 compering to the un-doped sample and thereafter dropped as Dy3+ ions content further increases. Microwave properties were discussed in terms of electromagnetic absorption in the frequency range 1–20 GHz. The occurrences of the intensive electromagnetic absorption in the frequency ranged from 1.6 to 2.7 GHz were observed. 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subjects Chemical composition
Correlation
Crystal structure
Crystallites
Domain boundaries resonance
Dysprosium
Electromagnetic absorption
Frequency ranges
Magnetic measurement
Magnetic properties
Magnetization
Magnetometers
Microwave properties
Nanoparticles
Room temperature
Sol-gel processes
Spinel ferrites
Substitutes
title Correlation between chemical composition, electrical, magnetic and microwave properties in Dy-substituted Ni-Cu-Zn ferrites
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