Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides

Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides were converted to the corresponding carbonyl or imine compounds without any trace of the activators. This bond scission reaction through 1,2-migration of C-H and C-C bonds was accessible to the one...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2021-09, Vol.57 (7), p.8738-8741
Hauptverfasser:	Ardiansah, Bayu, Tanimoto, Hiroki, Tomohiro, Takenori, Morimoto, Tsumoru, Kakiuchi, Kiyomi
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbonyls Cleavage Covalent bonds Crystallography NMR Nuclear magnetic resonance Substitution reactions
Online-Zugang:	Volltext
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