A novel cellulose membrane from cattail fibers as separator for Li-ion batteries
Cattail is widely abounding in wetlands and marshes and is usually considered as an abundant and inexpensive biomass lignocellulose resource due to its rapid growth. In this paper, a novel cellulose (named as TOCF) separator for Li-ion batteries (LIBs) is successfully fabricated from cattail fibers...
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| Veröffentlicht in: | Cellulose (London) 2021-09, Vol.28 (14), p.9309-9321 |
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| container_title | Cellulose (London) |
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| creator | Zhao, Xiaobin Wang, Wenbo Huang, Chenghao Luo, Lei Deng, Zhongmin Guo, Wei Xu, Jie Meng, Zhenghua |
| description | Cattail is widely abounding in wetlands and marshes and is usually considered as an abundant and inexpensive biomass lignocellulose resource due to its rapid growth. In this paper, a novel cellulose (named as TOCF) separator for Li-ion batteries (LIBs) is successfully fabricated from cattail fibers by 2, 2, 6, 6-tetramethylpiperidine-1-oxyl (TEMPO) oxidation and vacuum filtration. The proposed TOCF membrane shows good tensile strength (75 MPa), superior thermal dimensional stability, sufficient porosity (64.8%), outstanding liquid electrolyte uptake (323%) as well as large ionic conductivity (2.83 mS cm
−1
). Moreover, the Li/LiFePO
4
cell assembled using the TOCF separator demonstrates better discharge capacity and cycling stability than the cell with a commercial Celgard separator. Thus, the TOCF separator is a promising and low-cost candidate used in high-performance LIBs. |
| doi_str_mv | 10.1007/s10570-021-04110-3 |
| format | Article |
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−1
). Moreover, the Li/LiFePO
4
cell assembled using the TOCF separator demonstrates better discharge capacity and cycling stability than the cell with a commercial Celgard separator. Thus, the TOCF separator is a promising and low-cost candidate used in high-performance LIBs.</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-021-04110-3</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Bioorganic Chemistry ; Cellulose ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composites ; Dimensional stability ; Glass ; Ion currents ; Lignocellulose ; Lithium-ion batteries ; Membranes ; Natural Materials ; Organic Chemistry ; Original Research ; Oxidation ; Physical Chemistry ; Polymer Sciences ; Rechargeable batteries ; Separators ; Sustainable Development ; Tensile strength ; Vacuum filtration</subject><ispartof>Cellulose (London), 2021-09, Vol.28 (14), p.9309-9321</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-5d8681d62752619af6dbaa9bab76c8852e9c273e8999a61f7df5216824d3f7013</citedby><cites>FETCH-LOGICAL-c319t-5d8681d62752619af6dbaa9bab76c8852e9c273e8999a61f7df5216824d3f7013</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-021-04110-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-021-04110-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Zhao, Xiaobin</creatorcontrib><creatorcontrib>Wang, Wenbo</creatorcontrib><creatorcontrib>Huang, Chenghao</creatorcontrib><creatorcontrib>Luo, Lei</creatorcontrib><creatorcontrib>Deng, Zhongmin</creatorcontrib><creatorcontrib>Guo, Wei</creatorcontrib><creatorcontrib>Xu, Jie</creatorcontrib><creatorcontrib>Meng, Zhenghua</creatorcontrib><title>A novel cellulose membrane from cattail fibers as separator for Li-ion batteries</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>Cattail is widely abounding in wetlands and marshes and is usually considered as an abundant and inexpensive biomass lignocellulose resource due to its rapid growth. In this paper, a novel cellulose (named as TOCF) separator for Li-ion batteries (LIBs) is successfully fabricated from cattail fibers by 2, 2, 6, 6-tetramethylpiperidine-1-oxyl (TEMPO) oxidation and vacuum filtration. The proposed TOCF membrane shows good tensile strength (75 MPa), superior thermal dimensional stability, sufficient porosity (64.8%), outstanding liquid electrolyte uptake (323%) as well as large ionic conductivity (2.83 mS cm
−1
). Moreover, the Li/LiFePO
4
cell assembled using the TOCF separator demonstrates better discharge capacity and cycling stability than the cell with a commercial Celgard separator. Thus, the TOCF separator is a promising and low-cost candidate used in high-performance LIBs.</description><subject>Bioorganic Chemistry</subject><subject>Cellulose</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Dimensional stability</subject><subject>Glass</subject><subject>Ion currents</subject><subject>Lignocellulose</subject><subject>Lithium-ion batteries</subject><subject>Membranes</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Oxidation</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Rechargeable batteries</subject><subject>Separators</subject><subject>Sustainable Development</subject><subject>Tensile strength</subject><subject>Vacuum filtration</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE1LxDAQhoMouH78AU8Bz9FMss3HcVn8ggU9KHgLaTuRLm2zJl3Bf2-0gjcPwxzmed-Bh5AL4FfAub7OwCvNGRfA-BKAM3lAFlBpwYwRr4dkwa2y5SztMTnJecs5t1rAgjyt6Bg_sKcN9v2-jxnpgEOd_Ig0pDjQxk-T73oauhpTpj7TjDuf_BQTDWU2HeviSOuCYeown5Gj4PuM57_7lLzc3jyv79nm8e5hvdqwRoKdWNUaZaBVQldCgfVBtbX3tva1Vo0xlUDbCC3RWGu9gqDbUAlQRixbGTQHeUou595diu97zJPbxn0ay0snKqVNQZQtlJipJsWcEwa3S93g06cD7r7NudmcK-bcjzknS0jOoVzg8Q3TX_U_qS-f6nA4</recordid><startdate>20210901</startdate><enddate>20210901</enddate><creator>Zhao, Xiaobin</creator><creator>Wang, Wenbo</creator><creator>Huang, Chenghao</creator><creator>Luo, Lei</creator><creator>Deng, Zhongmin</creator><creator>Guo, Wei</creator><creator>Xu, Jie</creator><creator>Meng, Zhenghua</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20210901</creationdate><title>A novel cellulose membrane from cattail fibers as separator for Li-ion batteries</title><author>Zhao, Xiaobin ; 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In this paper, a novel cellulose (named as TOCF) separator for Li-ion batteries (LIBs) is successfully fabricated from cattail fibers by 2, 2, 6, 6-tetramethylpiperidine-1-oxyl (TEMPO) oxidation and vacuum filtration. The proposed TOCF membrane shows good tensile strength (75 MPa), superior thermal dimensional stability, sufficient porosity (64.8%), outstanding liquid electrolyte uptake (323%) as well as large ionic conductivity (2.83 mS cm
−1
). Moreover, the Li/LiFePO
4
cell assembled using the TOCF separator demonstrates better discharge capacity and cycling stability than the cell with a commercial Celgard separator. Thus, the TOCF separator is a promising and low-cost candidate used in high-performance LIBs.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-021-04110-3</doi><tpages>13</tpages></addata></record> |
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| subjects | Bioorganic Chemistry Cellulose Ceramics Chemistry Chemistry and Materials Science Composites Dimensional stability Glass Ion currents Lignocellulose Lithium-ion batteries Membranes Natural Materials Organic Chemistry Original Research Oxidation Physical Chemistry Polymer Sciences Rechargeable batteries Separators Sustainable Development Tensile strength Vacuum filtration |
| title | A novel cellulose membrane from cattail fibers as separator for Li-ion batteries |
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